• Membrane and Water Treatment
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• v.12 no.1
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• pp.1-9
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• 2021

This study optimized the chemical cleaning process of discarded RO membranes for reuse in less demanding separation processes. The effect of physicochemical parameters, including the temperature, cleaning time, pH of the cleaning solution, and addition of additives, on the cleaning process was investigated. The membrane performance was evaluated by testing the flux recovery rate and salt rejection before and after the cleaning process. High temperatures (45-50 ℃) resulted in a better flux recovery rate of 71% with more than 80% salt rejection. Equal time for acid and base cleaning 3-3 h presented a 72.43% flux recovery rate with salt rejection above 85%. During acid and base cleaning, the best results were achieved at pH values of 3.0 and 12.0, respectively. Moreover, 0.05% concentration of ethylenediaminetetraacetic acid presented 72.3% flux recovery, while 69.2% flux was achieved using sodium dodecyl sulfate with a concentration of 0.5%; both showed >80% salt rejection, indicating no damage to the active layer of the membrane. Conversely, 0.5% concentration of sodium percarbonate showed 83.1% flux recovery and 0.005% concentration of sodium hypochlorite presented 85.2% flux recovery, while a high concentration of these chemicals resulted in oxidation of the membrane that caused a reduction in salt rejection.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.3
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• pp.229-236
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• 2017

In this study, a direct contact membrane module was manufactured to be used in a pilot scale membrane distillation process to treat $3m^3/day$ of the digestate produced from anaerobic digestion of livestock manure. In order to investigate the performance of the membrane module, permeate flux was measured with and without spacer inside the module under various condition of temperature difference and cross flow velocity (CFV) through the membrane surfaces. Flux recovery rate after chemical cleaning was also investigated by applying three different cleaning methods. Additionally, thermal energy consumption was theoretically simulated based on actual pilot plant operation conditions. As results, we observed flux of the module with spacer was almost similar to the theoretically predicted value because the installation of spacer reduced the channeling effect inside the module. Under the same operating condition, the permeate flux also increased with increasing temperature difference and CFV. As a result of chemical in-line cleaning using NaOCl and citric acid for the fouled membranes, the recovery rate was 83.7% compared to the initial flux when NaOCl was used alone, and 87% recovery rate was observed when only citric acid was used. However, in the case of using only citric acid, the permeate flux was decreased at a rapid rate. It seemed that a cleaning by NaOCl was more effective to recover the flux of membrane contaminated by the organic matter as compared to a cleaning by citric acid. The total heat energy consumption increased with increasing CFV and temperature difference across the membrane. Thus, further studies should be intensively conducted to obtain a high permeate flux while keeping the energy consumption to a minimum for a practical application of membrane distillation process to treat wastewater.

• Journal of Fisheries and Marine Sciences Education
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• v.26 no.3
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• pp.639-646
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• 2014

A heat exchanger using two-phase loop thermosyphons was developed as a waste heat recovery system. An experimental study was carried out on the heat transfer characteristics of two-phase loop thermosyphons heat exchanger and the results from the experiments were used to see the possibility which the two-phase loop thermosyphons could be an alternate solution for waste heat recovery system. In the present work, R134a has been used as the working fluid and the filling rate do working fluid and heat flux have been used as the experimental parameters. The results show that the filling rate of working fluid and heat flux are very important factors for the operation of two-phase loop thermosyphons. The experimental results showed the provisional results as a waste heat recovery system.

• Microbiology and Biotechnology Letters
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• v.27 no.4
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• pp.320-326
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• 1999

The effects of operating pressure, lactate concentration, impurities, and pH on solution flux and lactate rejection in nanofiltration were investigated with model sodium lactate solutions (lactate 10~200g/L) as a model system. In the tested range of pressure(80~140 psig), the solution flux was observed to be proportional to the operating pressure and the rejection of lactate increased only slightly with the pressure. Both of the flux and the rejection decreased with lactate concentration, while the recovery rate of lactate increased. The effects of glucose and yeast extract as impurities on lactate rejection were negligible, but the flux decreased significantly with the addition of yeast extract. At low lactate concentrations, the rejection of lactate increased with pH due to the increased repulsion (Donnan exclusion effect) between lactate ions and membrane surface. But, at high lactate concentrations, the donnan effect was observed to be overwhelmed by the effect of sodium ions added to adjust the pH, and the rejection of lactate decreased with pH. When fermentation broth containing about 89g/L of lactate was nanofiltered, the flux and the rejection of lactate were 2.8L/$m^2$h and 5%, respectively at 120psig. Both of them were slightly lower than those with model solutions. The recovery rate was 2.6mol/$m^2$h.

• Korean Journal of Food Science and Technology
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• v.24 no.3
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• pp.199-203
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• 1992

This study was aimed to optimize the required condition for recovering the low soluble taste component obtained from sea tangle extract using ultrafiltration, and to investigate effects of membrane type, temperature, transmembrane pressure and flow rate respectively. We also compared relationship between the profile of permeate flux and the recovery yield of taste component under the selected optimal condition using ultrafiltration and diafiltration. Hydrophobic GR 51 PP membrane kept higher average permeate flux than hydrophilic FS membrane, and average permeate flux also had increasing tendency in relation to rising flow rate but it showed limit value of 3.7 l/min. Average permeate flux decreased as transmembrane pressure increased but it showed little change with rising temperature. Investigation upon average permeate flux, total dissolved solid and recovery yield of taste components using ultrafiltration and diafiltration resulted in relatively higher recovery yield in ultrafiltration. Compared ultrafiltration and diafiltration, average permeate flux was lower in ultrafiltration.

• Journal of Korean Society of Water and Wastewater
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• v.31 no.6
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• pp.501-510
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• 2017

In this study, it is estimated that ceramic membrane process which can operate stably in harsh conditions replacing existing organic membrane connected with coagulation, sedimentation etc.. Jar-test was conducted by using artificial raw water containing kaolin and humic acid. It was observed that coagulant (A-PAC, 10.6%) 4mg/l is the optimal dose. As a results of evaluation of membrane single filtration process (A), coagulation-membrane filtration process (B) and coagulation-sedimentation-membrane filtration process (C), TMP variation is stable regardless of in Flux $2m^3/m^2{\cdot}day$. But in Flux $5m^3/m^2{\cdot}day$, it show change of 1-89.3 kpa by process. TMP of process (B) and (C) is increased 11.8, 0.6 kpa each. But, the (A) showed the greatest change of TMP. When evaluate (A) and (C) in Flux $10m^3/m^2{\cdot}day$, TMP of (A) stopped operation being exceeded 120 kpa in 20 minutes. On the other hand, TMP of (C) is increased only 3 kpa in 120 minutes. Through this, membrane filtration process can be operated stably by using the linkage between the pretreatment process and the ceramic membrane filtration process. Turbidity of treated water remained under 0.1 NTU regardless of flux condition and DOC and $UV_{254}$ showed a removal rate of 65-85%, 95% more each at process connected with pretreatment. Physical cleaning was carried out using water and air of 500kpa to show the recovery of pollutants formed on membrane surface by filtration. In (A) process, TMP has increased rapidly and decreased the recovery by physical cleaning as the flux rises. This means that contamination on membrane surface is irreversible fouling difficult to recover by using physical cleaning. Process (B) and (C) are observed high recovery rate of 60% more in high flux and especially recovery rate of process (B) is the highest at 95.8%. This can be judged that the coagulation flocs in the raw water formed cake layer with irreversible fouling and are favorable to physical cleaning. As a result of estimation, observe that ceramic membrane filtration connected with pretreatment improves efficiency of filtration and recovery rate of physical cleaning. And ceramic membrane which is possible to operate in the higher flux than organic membrane can be reduce the area of water purification facilities and secure a stable quantity of water by connecting the ceramic membrane with pretreatment process.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.1
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• pp.47-52
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• 2005

This study was conducted to evaluate the performance of submerged hollow fiber MF processes to treat secondary wastewater for water reuse. Specifically, membrane productivity and filtrate water quality were investigated under various operating conditions (i.e. flux, recovery, and backwash rate) at pilot-scale. Membrane fouling became more severe with increasing flux and recovery, suggesting that low flux operation (< 25 LMH) was desirable. At high flux operating(> 37.5 LMH), increasing backwash rate showed only limited success. The biofouling, quantified by PEPA and BFHPC, was also significant in wastewater reclamation, and biogrowth control by chlorine, were necessary to improve membrane productivity. Filtrate water qualities are in good compliance with water reuse regulations regardless of operating conditions (flux, recovery and backwash rate). Particle (e.g. turbidity) removal ranged from 89 to 98%, while only 11 to 21% of organics (e.g. NPDOC) were removed by MF membrane. Only small improvement in biostability (e.g. AOC) was achieved by MF system, and thus, without post disinfection, significant microorganisms might be present in the filtrate due to regrowth. Lastly, in order to further investigate pathogen removal, controlled microbial challenge tests were performed by monitoring Giardia, Cryptosporidium, bacteria and virus, and showed relatively good microbial removal.

• Membrane and Water Treatment
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• v.10 no.5
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• pp.321-330
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• 2019

The objective of this study was to examine the recovery of the power plant cooling tower blowdown water (CTBD) by membrane distillation. The experiments were carried out using a flat plate poly vinylidene fluoride (PVDF) membrane with a pore diameter of $0.22{\mu}m$ by a direct contact membrane distillation unit (DCMD). The effects of operating parameters such as transmembrane temperature difference (${\Delta}T$), circulation rate and operating time on permeate flux and membrane fouling have been investigated. The results indicated that permeate flux increased with increasing ${\Delta}T$ and circulation rate. Whereas maximum permeate flux was determined as $47.4L/m^2{\cdot}h$ at ${\Delta}T$ of $50^{\circ}C$ for all short term experiments, minimum permeate flux was determined as $7.7L/m^2{\cdot}h$ at ${\Delta}T$ of $20^{\circ}C$. While $40^{\circ}C$ was determined as the optimum ${\Delta}T$ in long term experiments. Inorganic and non-volatile substances caused fouling in the membranes.

• KSBB Journal
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• v.4 no.2
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• pp.177-184
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• 1989

In separating mycelia from antibiotic fermentation broths, high permeate flux was obtained by cross-flow filtration using modified regenerated cellulose membrane. The flux was increased most effectively by increasing the flow rate. There existed a critical mycelium density (about 20% PMV) at which the highest flux was observed. In a batchwise concentration of the fermentation broth, the system suffered from a severe fouling problem, which was relieved drastically by applying diafiltration technique, although it increased the permeate volume. A combined concentration/diafiltration process was ideal in keeping relatively high flux together with a high product recovery yield. The best result was obtained by starting diafiltration after concentrating the broth to 20% PMV. By doing so, a 98% product recovery yield was achieved in the shortest time while keeping the permeate volume at a minimum level.

• Journal of Environmental Science International
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• v.7 no.1
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• pp.74-80
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• 1998

Because permeate flux was very low as It has the suspension soled of higher concentration In the trafiltration membrane separation treatment of dyestuff wastewater, pre-treatment of Ponton reaction was carried out. In the case of pH 3, COD removal rate was the hi각erst of 58%. When PAC was added into the pre-treatment supernatant, the COD removal rate was found to be 53% , and when COD was 153mg/L, the removal rate was 92.3% in the trafiltration separation. In addition, the effect of the addition of PAC on the permeate flux was also investigated. The decrease of permeate flux In the presence of PAC was higher than In the abscence of PAC, but the recovery of permeability by cleaning was better In the case of PAC system.