DOI QR코드

DOI QR Code

Membrane distillation of power plant cooling tower blowdown water

  • Ince, Elif (Gebze Technical University, Department of Environmental Engineering) ;
  • Uslu, Yasin Abdullah (Gebze Technical University, Department of Environmental Engineering)
  • Received : 2018.10.06
  • Accepted : 2019.04.09
  • Published : 2019.09.25

Abstract

The objective of this study was to examine the recovery of the power plant cooling tower blowdown water (CTBD) by membrane distillation. The experiments were carried out using a flat plate poly vinylidene fluoride (PVDF) membrane with a pore diameter of $0.22{\mu}m$ by a direct contact membrane distillation unit (DCMD). The effects of operating parameters such as transmembrane temperature difference (${\Delta}T$), circulation rate and operating time on permeate flux and membrane fouling have been investigated. The results indicated that permeate flux increased with increasing ${\Delta}T$ and circulation rate. Whereas maximum permeate flux was determined as $47.4L/m^2{\cdot}h$ at ${\Delta}T$ of $50^{\circ}C$ for all short term experiments, minimum permeate flux was determined as $7.7L/m^2{\cdot}h$ at ${\Delta}T$ of $20^{\circ}C$. While $40^{\circ}C$ was determined as the optimum ${\Delta}T$ in long term experiments. Inorganic and non-volatile substances caused fouling in the membranes.

Keywords

References

  1. A.P.H.A. (2005), Standard Methods for the Examination of Water and Wastewater, (21st Edition), American Public Health Association, Washington, DC., USA.
  2. Borden, J., Gilron, J. and Hasson, D. (1987), "Analysis of RO flux decline due to membrane surface blockage", Desalination, 66, 257-269. https://doi.org/10.1016/0011-9164(87)90209-8.
  3. Boubakri, A., Hafiane, A. and Bouguecha, S.A.T. (2017), "Direct contact membrane distillation: Capability to desalt raw water", Arab. J. Chem., 10, S3475-S3481. https://doi.org/10.1016/j.arabjc.2014.02.010.
  4. Dehghan, N., Nezakati, R. and Marandi, R. (2010), "Performance Evaluation of Yazd Combined Cycle Power Plant wastewater treatment system and the reuse of wastewater in agriculture", The Second National Seminar on the Status of Recycled Waters in Water Resources Management, Mashhad, Iran.
  5. Di Filippo, M.N. (2004), Use of Produced Water in Recirculating Cooling Systems at Power Generating Facilities, National Energy Technology Laboratory, Palo Alto, CA, USA.
  6. El-Bourawi, M.S., Ding, Z., Ma, R. and Khayet, M. (2006), "Review - A framework for better understanding membrane distillation separation process", J. Membr. Sci., 285, 4-29. https://doi.org/10.1016/j.memsci.2006.08.002.
  7. Ge, J., Peng, Y., Li, Z., Chen, P. and Wang, P. (2014), "Membrane fouling and wetting in a DCMD process for RO brine concentration", Desalination, 344, 97-107. https://doi.org/10.1016/j.desal.2014.03.017.
  8. Greenlee, L.F., Lawler, D.F., Freeman, B.D., Marrot, B. and Moulin, P. (2009), "Reverse osmosis desalination: Water sources, technology, and today's challenges", Water Res., 43, 2317-2348. https://doi.org/10.1016/j.watres.2009.03.010.
  9. Gryta, M. (2009), "Calcium sulphate scaling in membrane distillation process", Chem. Pap., 63 (2), 146-151. https://doi.org/10.2478/s11696-008-0095-y.
  10. Gryta, M. (2010), "Application of membrane distillation process for tap water purification", Membr. Water Treat., 1(1), 1-12. https://doi.org/10.12989/mwt.2010.1.1.001.
  11. Gryta, M. (2012), "Effectiveness of water desalination by membrane distillation process", Membranes, 2, 415-429. https://doi.org/10.3390/membranes2030415.
  12. He, K., Hwang, H.J., Woo, M.W. and Moon, I.S. (2011), "Production of drinking water from saline water by direct contact membrane distillation (DCMD)", J. Ind. Eng. Chem., 17, 41-48. https://doi.org/10.1016/j.jiec.2010.10.007.
  13. Hou, D., Wang, J., Zhao, C., Wang, B., Luan, Z. and Sun, X. (2010), "Fluoride removal from brackish groundwater by direct contact membrane distillation", J. Environ. Sci., 22(12), 1860-1867. https://doi.org/10.1016/S1001-0742(09)60332-6.
  14. Ji, X., Curcio, E., Al-Obaidani, S., Di Profio, G., Fontananova, E. and Drioli, E. (2010), "Membrane distillation-crystallization of seawater reverse osmosis brines", Sep. Purif. Technol., 71, 76-82. https://doi.org/10.1016/j.seppur.2009.11.004.
  15. Kim, S., Park, K.Y. and Cho, J. (2017), "Evaluation of the efficiency of cleaning method in direct contact membrane distillation of digested livestock wastewater", Membr. Water Treat., 8(2), 113-123. https://doi.org/10.12989/mwt.2017.8.2.113.
  16. Koyuncu, I. and Wiesner, M.R. (2007), "Morphological variations of precipitated salts on NF and RO membranes", Environ. Eng. Sci., 24, 602-614. https://doi.org/10.1089/ees.2006.0114.
  17. Kujawa, J. and Kujawski, W. (2015), "Driving force and activation energy in air-gap membrane distillation process", Chem. Pap., 69(11), 1438-1444. https://doi.org/10.1515/chempap-2015-0155.
  18. Liu, Q., Song, L., Zhang, Z. and Liu, X. (2010), "Preparation and characterization of the PVDF-based composite membrane for direct methanol fuel cells", Int. J. Energy Environ., 1(4), 643-656.
  19. Loussif, N. and Orfi, J. (2016), "Comparative study of air gap, direct contact and sweeping gas membrane distillation configurations", Membr. Water Treat., 7(1), 71-86. https://doi.org/10.12989/mwt.2016.7.1.071.
  20. Manna, A.K., Sen, M., Martin, A.R. and Pal, P. (2010). "Removal of arsenic from contaminated groundwater by solar driven membrane distillation", Environ. Poll., 158, 805-811. https://doi.org/10.1016/j.envpol.2009.10.002.
  21. Martinez-Diez, L. and Vazquez-Gonzalez, M.I. (1999), "Temperature and concentration polarization in membrane distillation of aqueous salt solutions", J. Membrane Sci., 156, 265-273. https://doi.org/10.1016/S0376-7388(98)00349-4.
  22. Mattson, J.V. and Harris, T.G.I. (1979), "Zero discharge of cooling water by side stream softening", J. Water Pollut. Control Fed., 51, 2602-2614.
  23. Meng, S.W., Yea, Y., Mansouri, J. and Chen, V. (2015), "Crystallization behavior of salts during membrane distillation with hydrophobic and superhydrophobic capillary membranes", J. Membr. Sci., 473, 165-176. https://doi.org/10.1016/j.memsci.2014.09.024.
  24. Mohsen, M.S. (2004), "Treatment and reuse of industrial effluents: case study of a thermal power plant", Desalination, 167, 75-86. https://doi.org/10.1016/j.desal.2004.06.115.
  25. Music, S., Filipovic-Vincekovic, N. and Sekovanic, L. (2011), "Precipitation of amorphous SiO2 particles and their properties", Braz. J. Chem. Eng., 28(1), 89-94. http://dx.doi.org/10.1590/S0104-66322011000100011.
  26. Pal, P. and Manna, A.K. (2010), "Removal of arsenic from contaminated groundwater by solar-driven membrane distillation using three different commercial membranes", Wat. Res., 44, 5750-5760. https://doi.org/10.1016/j.watres.2010.05.031.
  27. Peng, P., Fane, A.G. and Li, X. (2005), "Desalination by membrane distillation adopting a hydrophilic membrane", Desalination, 173, 45-54. https://doi.org/10.1016/j.desal.2004.06.208.
  28. Plakas, K.V. and Karabelas, A.J. (2012), "Removal of pesticides from water by NF and RO membranes - A review", Desalination, 287, 255-265. https://doi.org/10.1016/j.desal.2011.08.003.
  29. Saffarini, R.B., Mansoor, B., Thomas, R. and Arafat, H.A. (2013), "Effect of temperature-dependent microstructure evolution on pore wetting in PTFE membranes under membrane distillation conditions", J. Membr. Sci. 429, 282-294. https://doi.org/10.1016/j.memsci.2012.11.049.
  30. Shintani, T., Matsuyama, H. and Kurata, N. (2009) "Effect of heat treatment on performance of chlorine-resistant polyamide reverse osmosis membranes", Desalination, 247, 370-377. https://doi.org/10.1016/j.desal.2008.09.003.
  31. Shirazi, M.M.A., Kargari, A. and Shirazi, M.J.A. (2012), "Direct contact membrane distillation for seawater desalination", Desalin. Water Treat., 49, 368-375. https://doi.org/10.1080/19443994.2012.719466.
  32. Shirazi, M.M.A. and Kargari, A. (2015), "A Review on applications of membrane distillation (MD) process for wastewater treatment". J. Membr. Sci. Res., 1, 101-112. https://dx.doi.org/10.22079/jmsr.2015.14472.
  33. Wang, Z., Fan, Z.F., Xie, L.X. and Wang, S.C. (2006), "Study of integrated membrane systems for the treatment of wastewater from cooling towers", Desalination, 191, 117-124. https://doi.org/10.1016/j.desal.2005.04.125.
  34. Yu, X., Yanga, H., Lei, H. and Shapiro, A. (2013), "Experimental evaluation on concentrating cooling tower blowdown water by direct contact membrane distillation", Desalination, 323, 134-141. https://doi.org/10.1016/j.desal.2013.01.029.
  35. Zhang, J.D., Chen, L., Zeng, H.M., Yan, X.X., Song, X.N., Yang, H. and Ye, C.S. (2007), "Pilot testing of outside-in MF and UF modules used for cooling tower blowdown pretreatment of power plants", Desalination, 214, 287-298. https://doi.org/10.1016/j.desal.2006.12.004.
  36. Zoungrana, A., Cakmakci, M., Zengin, I.H., Inoglu, O. and Elcik, H. (2016), "Treatment of metal-plating waste water by modified direct contact membrane distillation", Chem. Pap., 70(9), 1185-1195. https://doi.org/10.1515/chempap-2016-0066.