• Membrane and Water Treatment
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• 제8권6호
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• pp.575-590
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• 2017

PolyHIPEs membrane prepared with styrene (St), divinylbenzene (DVB), and ethylhexyl acrylate (EHA) can yield a unique pore structure provided by large voids highly interconnected by many small window throats. With the advantageous pore structure, PolyHIPE presents a potential as a support for carrier facilitated transport membrane. Tricaprylmethylammonium chloride (Aliquat 336) can be efficiently incorporated into the PolyHIPE membrane by a two-step solvent-nonsolvent method to obtain an Aliquat 336-immobilized PolyHIPE membrane with good stability. The study of Cr (VI) transport through Aliquat 336-immobilized PolyHIPE membrane indicates that the membrane has high initial flux and maxima stripping flux ($J_f^o=15.01({\mu}mol/m^2s)$, $J_s^{max}=6.15({\mu}mol/m^2s)$). The reusability study shows that the Aliquat 336-immobilized PolyHIPE membrane can maintain high Cr(VI) recovery efficiency even after 15 cycles of operations. The developed membrane was also used in the separation of Cr (VI) from other anions (i.e., $SO_4{^{2-}}$ and $NO_3{^-}$) and other cations (i.e., Ni (II), Mg (II) and Cu (II)) with good selectivity.

• 한국물환경학회지
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• 제21권2호
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• pp.196-204
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• 2005

The objective of this study is to evaluate the possibility to apply pre-ozone and membrane system for drinking water. This system is improved in fouling control by pre-ozone system. It is composed of ultrafiltration hollow fiber type membrane and ozone reactor. The result of this study is that the flux is increased about 10.7% and decreased in TMP by the pre-ozone. Also, backwashing pressure decreased about 18%. The optimum concentration of residual ozone is 0.3~0.5 ppm. During the period, the recovery ratio of this system was turned out to be 90% as the flowrate of effluent is $67.1m^3/day$. When the TMP and backwashing pressure was $0.85kg/cm^2$ and $1.10kg/cm^2$, this system was stable without sudden fouling. Finally, the quality of effluent is satisfied the guidelines for potable water quality such as turbidity, color, E.coli, Mn, Al, Fe and so on.

• The Korean Journal of Ecology
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• 제21권1호
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• pp.89-96
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• 1998

The diurnal changes of the stomatal conductance, transpiration and leaf water potential were measured in order to assess the water relations characteristics of Pueraria thunbergiana in August of 1995 and 1996. The results showed two different responses depending on the duration of rainless days. The microclimatic conditions were highly stressful on 2 August. Daily maximum temperature reached to $39.0{\circ}C$ and vapor pressure deficit was 3.55 KPa. During this time the leaf water potential decreased to -1.02 MPa and a marked reduction of stomatal conductance was shown. However, on 15 August the stomatal conductance increased with increment of photon flux density, and transpiration was highly maintained during the day time. Minimum leaf water potential was only -0.47 MPa in spite of high transpiration rate. Furthermore, on 15 August reduced leaf water potential during the day time was recovered rapidly with decrease of photon flux density, whereas recovery of leaf water potential on 2 August was delayed. However, reduced leaf water potential on 2 August was recovered untile the next dawn. Osmotic potential at turgor loss point of Pueraria thunbergiana on 2, 3 and 15 August was -1.79, -1.70 and -1.60 MPa, respectively. The vapor pressure deficit is more contributive to the regulation of stomatal conductance than leaf water potential.

• Journal of Pharmaceutical Investigation
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• 제4권4호
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• pp.17-25
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• 1974

1. Neutron acivation analysis of arsenic contained in Korean human liver was studied in the view point of forensic chemistry, using 12 corpses. A sample of 1g was irradiated for 30 mins. in a neutron flux of $1.2{\times}10^{12}n/cm^2/sec$, followed by nitric-sulfuric acid digestion and then by Gutzeit separation. Radio activity was detected by it's scintillation counter. The arsenic content in the liver was found to be $0.01{\mu}g/g$ to $0.15{\mu}g/g$. 2. A rapid and convenient method for the radiochemical determination of minerals by neutron activation analysis was established. After neutron irradiation to the standard soln. of Cu and Mn in pneumatic tube (neutron flux : $1.2{\times}10^{12}n/cm^2/sec$), Cu and Mn were determined by estimating the ratio of the widths under energy peak area in ${\gamma}-ray-spectrogram$. When the standard soln. of Mn and Cu is irradiated for 15 mins. to 18 hrs., recovery test shows that the relative errors are 5.1% and 4.5% for copper and manganese, respectively.

• Membrane and Water Treatment
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• 제10권2호
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• pp.127-137
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• 2019

The D2EHPA/TBP co-extractants immobilized PolyHIPE membrane can be used for the selective separation of Mn (II) from Co (II). By solvent-nonsolvent method, D2EHPA/TBP co-extractants can be effectively immobilized into PolyHIPE membrane. The pore structure of PolyHIPE membrane and the presence of TBP enhance the stability of immobilized co-extractants. The optimal operating conditions for the separation of Mn (II) and Co (II) are feeding phase at pH 5.5, sulfuric acid concentration in the stripping phase of about 50 g/L and stirring speed at 400 rpm. The D2EHPA/TBP co-extractants ratio of 5:1 shows synergetic effect on Mn/Co separation factor about 22.74. The removal rate and recovery rate of Mn (II) is about 98.4 and 97.1%, respectively, while for Co (II) the transport efficiency is insignificant. The kinetic study of Mn (II) transport shows that high initial flux, $J_f^o=80.1({\mu}mol/m^2s)$, and maxima stripping flux, $J_s^{max}=20.8({\mu}mol/m^2s)$, can be achieved with D2EHPA/TBP co-extractants immobilized PolyHIPE membrane. The stability and reusability study shows that the membrane can maintain a long term performance with high efficiency. High purity of Co (II) and Mn (II) can be recovered from the feeding phase and stripping phase, respectively.

• 대한기계학회논문집B
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• 제37권2호
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• pp.197-204
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• 2013

본 연구에서는 덕트 버너를 추가적으로 사용하는 수직형 배열회수 보일러(HRSG)에서 발생하게 되는 화염에 의한 전열면으로의 화염 복사 열전달에 의한 영향을 살펴보기 위한 해석 기법을 마련하였다. 덕트 버너 화염과 전열면은 가상의 평면으로 가정하였고, 화염 온도, 면적 및 방사율 입력정보는 간략화 하였다. 덕트버너 설치 위치 및 연료를 달리한 3 가지 해석 case 가 고려되었으며 계산된 화염 복사 열전달률과 열유속은 삼원자 가스 복사 및 대류 열전달과 비교되었다. 모든 해석 case 에서 삼원자 가스복사 열전달에 의한 영향은 미미하였고, 전열면에서 대류 열전달 대비 화염 복사 열전달률은 8~41%인 것으로 나타났다. 이 연구에서 얻은 중요한 사실은 화염 복사가 집중되는 전열면의 중앙부분에서 국부적인 열유속은 화염 복사에 의해 완전히 지배된다는 것이다.

• 멤브레인
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• 제25권2호
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• pp.132-143
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• 2015

인구의 급속한 증가, 한정된 식수 자원의 오염 등으로 인하여 인류에게 필수적인 물이 점점 부족해지고 있다. 깨끗한 물을 얻기 위해 분리막 공정을 이용한 수처리 방식이 널리 사용되고 있으며, 분리막 공정 중 하나인 정삼투 공정은 고압펌프 없이 구동이 가능하다. 정삼투 공정이 높은 수투과도를 가지기 위해서는 내부 농도 분극 현상 및 Reverse salt flux를 적게 일으키는 유도 용질 개발이 필요하며, 희석된 유도 용액에 포함된 유도 용질의 경제적인 회수 방법 개발 또한 필요하다. 현재까지는 $60^{\circ}C$ 가량에서 회수가 가능한 $NaHCO_3$와 같은 무기 유도 용질, 음료수 생산이 가능한 sucrose와 같은 유기 유도 용질, 자기장을 이용해 회수가 가능한 magnetic nanoparticle과 같은 유도 용질들이 개발되어 보고되었다. 또한, 이러한 정삼투 원리를 이용하여 해수 담수, 폐수처리, 단백질 정제, 압력 지연 삼투 이용한 에너지 생산, 관개를 위한 농축된 비료 희석, 바이오 연료를 위해 폐수로부터 조류를 키우는 공정과 같은 분야에 적용될 수 있다. 본 논문에서는 정삼투 공정에 영향을 주는 유도용액의 특성과 이상적인 조건, 여러 가지 유도 용질 및 유도용질의 회수 방법, 정삼투 공정의 적용 분야를 여러 논문 내용들을 바탕으로 정리하였다.

• 대한기계학회논문집B
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• 제33권7호
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• pp.541-551
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• 2009

Configuration of the inlet transition square duct (hereinafter referred to as "transition duct") for heat recovery steam generator (hereinafter referred to as "HRSG") in combined cycle power plant is limited by the construction type of HRSG and plant site condition. The main purpose of the present study is to analyze the effect of a variation in turbulent flow pattern by roof slop angle change of transition duct for horizontal HRSG, which is influencing heat flux in heat transfer structure to the finned tube bank. In this study, a computational fluid dynamics(CFD) is applied to predict turbulent flow pattern and comparisons are made to 1/12th scale cold model test data for verification. Re-normalization group theory (RNG) based k-$\epsilon$ turbulent model, which improves the accuracy for rapidly strained flow and swirling flow in comparison with standard k-$\epsilon$ model, is used for the results cited in this study. To reduce the amount of computer resources required for modeling the finned tube bank, a porous media model is used.

• Journal of Welding and Joining
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• 제24권1호
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• pp.64-70
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• 2006

570MPa grade weldable steels were gas metal arc welded with various heat inputs and interpass temperatures using flux cored wires. Effects of heat input and interpass temperature on the strength and impact toughness of weld metal were investigated in terms of microstructural change, recovery of alloying elements, and the amount of reheated weld metal. Increase of heat input and interpass temperature resulted in decrease of weld metal strength. This is because of the small amount of acicular ferrite, large columnar size and low recovery of alloying elements such as manganese and silicon. In addition to the microstructural change, weld metal toughness was also influenced by the deposition sequence. It increased with an increase of the amount of reheated weld metal.

• 한국추진공학회지
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• 제6권2호
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• pp.65-74
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• 2002

전압력 회복율을 최대로 하기 위한 IRR형 램젯 공기 흡입구 초음속 확산부의 최적형상 설계를 수행하였다. 질량유량을 제약조건으로 고려하고 외부램프에서의 두 번째 경사충격파와 카울립 형상, 그리고 흡입구 목의 단면적을 설계변수로 선택하였다. 효율적인 최적화를 위해 설계변수 변환을 통한 개선된 반응면 기법을 사용하였으며 설계반복을 통해 높은 신뢰도의 반응면을 구성할 수 있었다. 최적화 기법으로 유전자 알고리즘을 사용하였으며, 이차원 Euler Code를 사용하여 공력해석을 수행하였다. 배압조건의 적용을 위해 흡입구 목 뒤로 가상의 노즐을 장착하였고 총 20회의 계산으로 종말충격파 이후의 전압력 회복율이 기준형상에 비하여 14% 향상된 초음속 확산부 최적형상을 설계할 수 있었다.