• 폴리머
• /
• 제34권2호
• /
• pp.97-103
• /
• 2010

6FDA를 포함한 다양한 폴리이미드/MWCNT의 전도성 복합 필름을 제조하기 위하여 MWCNT 표면에 PMMA를 도입하여 복합필름을 제조하였으며 전기 전도성의 변화를 PMMA-g-MWCNT의 농도 변화에 따라 관찰하였다. 6FDA계 폴리이미드계 복합 필름 내의 MWCNT 분산성은 PMMA-g-MWCNT의 경우 분자간의 상호 인력으로 인하여 분산도가 표면 처리하지 않은 MWCNT에 비하여 매우 높음을 확인하였다. 전기 전도도의 거동은 percolation threshold를 통하여 해석하였으며 그 결과 높은 임계 지수와 낮은 임계 농도를 가지는 6FDA-6FpDA/ PMMA-g-MWCNT 복합체가 DABA(diamino benzoic acid)를 포함한 폴리이미드 복합체에 비하여 높은 분산도를 가짐을 확인하였다.

• E2M - 전기 전자와 첨단 소재
• /
• 제9권3호
• /
• pp.291-297
• /
• 1996

The surface properties of AI(Si, Cu) alloy film after plasma etching using the chemistries of chlorinated and fluorinated gases with varying the etching time have been investigated using X-ray Photoelectron Spectroscopy. Impurities of C, Cl, F and O etc are observed on the etched AI(Si, Cu) films. After 95% etching, aluminum and silicon show metallic states and oxidized (partially chlorinated) states, copper shows Cu metallic states and Cu-Cl$_{x}$(x$_{x}$ (x$_{x}$ (1

• 한국수소및신에너지학회논문집
• /
• 제26권1호
• /
• pp.45-53
• /
• 2015

The objective of this study is to develop a gas pro-treatment system for DME synthesis, wherein this system separates $CO_2$ from Flaring gas as Membrane, in order to save raw material ($CH_4$) cost of DME. In this study, hollow fiber membrane is developed, which is able to separate high-pressure gas, supported by polysulfone and coated with amorphous fluorinated polymer. Throughout the evaluation of the membrane's separation characteristics, the membrane is applied to this system. The membrane is designed by 2 stages for over 90% removal rate of $CO_2$ and over 90% recovery rate of $CH_4$. The bench scale of pro-treatment system is developed as $25Nm^3/hr$.

• E2M - 전기 전자와 첨단 소재
• /
• 제9권6호
• /
• pp.578-583
• /
• 1996

The magnetic properties have been investigated for the system of $Y_{1-x}$Yb$_{x}$Ba$_{2}$Cu$_{3}$F$_{y}$O$_{y}$ with x=0.0, 0.1, 0.2, 0.3, 0.4 and 0.5. In the magnetic hysteresis measurements, the values of the magnetic critical current densities are in the range of 10$^{4}$-10$^{5}$ A/cm$^{2}$ at the maximum external field 1.4 T. The upper critical field is over 100 T. The critical current density is estimated by the magnetization width .DELTA.M through the Bean critical state model. As the field strength is increased, the .DELTA.M diminishes slowly. The .DELTA.M for the fluorinated sample also decreases slowly with increasing field. It is considered that the large J, value results from this type is due to enhanced pinning center in grain boundary.y.ary.y.

• 한국전기전자재료학회논문지
• /
• 제30권10호
• /
• pp.665-671
• /
• 2017

Herein, we report the fabrication of low-voltage N-type organic field-effect transistors by using high capacitance fluorinated polymer gate dielectrics such as P(VDF-TrFE), P(VDF-TrFE-CTFE), and P(VDF-TrFE-CFE). Electron-withdrawing functional groups in PVDF-based polymers typically cause the depletion of negative charge carriers and a high contact resistance in N-channel organic semiconductors. Therefore, we incorporated intermediate layers of a low-k polymerto prevent the formation of a direct interface between PVDF-based gate insulators and the semiconducting active layer. Consequently, electron depletion is inhibited, and the high charge resistance between the semiconductor and source/drain electrodes is remarkably improved by the in corporation of solution-processed charge injection layers.

• 한국복합재료학회:학술대회논문집
• /
• 한국복합재료학회 2004년도 추계학술발표대회 논문집
• /
• pp.100-103
• /
• 2004

In this work, the effects of oxy-fluorination on surface characteristics of carbon fibers were investigated in mechanical interfacial properties of carbon fibers-reinforced composites. The surface properties of the carbon fibers were determined by X-ray photoelectron spectroscopy (XPS), FT-IR. and contact angle measurements. And their mechanical interfacial properties of the composites were studied in interlaminar shear strength (ILSS) and critical stress intensity factor $(K_{IC})$. As experimental results, the $F_{1S}/C_{1S}$ ratio of carbon fiber surfaces was increased by oxy-fluorination, due to the development of the oxygen containing functional groups. The mechanical interfacial properties of the composites, including ILSS and $K_{IC}$, had been improved in the oxy-fluorination on fibers. These results could be explained that the oxy-fluorination was resulted in the increase of the adhesion between fibers and matrix in a composite system.

• 한국환경보건학회지
• /
• 제38권6호
• /
• pp.451-459
• /
• 2012

Background: In Korea, a healthy 36-year-old man developed acute interstitial pneumonitis soon after inhaling a waterproofing spray which he had applied at home to his outdoor jacket. Objectives: The objectives of this study were to review cases of varying degrees of respiratory toxicity and poisoning in connection with the use of waterproofing spray and summarize major reasons for cases of poisoning. Methods: We searched articles reporting on a combination of a waterproofing agent and/or respiratory symptoms, including acute respiratory syndrome, lung injury, pneumonia, pulmonary toxicity, and respiratory disease. Results: We reviewed a number of cases of varying degrees of respiratory toxicity and poisoning resulting from inhalation of waterproofing spray containing fluorocarbon co-polymer, solvents and propellants reported in a variety of countries. The literature searches concluded that among the ingredients of waterproofing agents, fluorinated polymer may cause acute respiratory health effects. Conclusion: Environmental policy should be implemented in order to prevent consumers from using household and industrial products including waterproofing agents. In addition, a national surveillance system should be created to collect cases of poisoning caused by the use of consumer products.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
• /
• pp.26-29
• /
• 2004

High density plasma fluorinated silicate glass (HDP FSG) is used as a gap fill film for metal-to-metal space because of many advantages. However, FSG films can cause critical problems such as bonding issue of top metal at package, metal contamination, metal peel-off, and so on. It is known that these problems are caused by fluorine penetration out of FSG film. To prevent it, FSG capping layers such like SRO (Silicon Rich Oxide) are needed. In this study, their characteristics and a capability to block fluorine penetration for various FSG capping layers are investigated. Normal stress and High stress due to denser film. While heat treatment to PETEOS caused lower blocking against fluorine penetration, it had insignificant effect on SiN. Compared with other layers, SRO using ARC chamber and SiN were shown a better performance to block fluorine penetration.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1995년도 추계학술대회 논문집 학회본부
• /
• pp.338-341
• /
• 1995

The surface properties after plasma etching of Al(Si, Cu) solutions using the chemistries of chlorinated and fluorinated gases with varying the etching time have been investigated using X-ray Photoelectron Spectroscopy. Impurities of C, Cl, F and O etc are observed on the etched Al(Si, Cu) films. After 95% etching, aluminum and silicon show metallic states and oxized (partially chlorinated) states, copper shows Cu metallic states and Cu-Clx(x$CuCl_x$ (x$CuCl_x$ (1

• 한국기계가공학회지
• /
• 제18권12호
• /
• pp.45-51
• /
• 2019

As the separator becomes thinner, the role of thermal stability becomes more important in ensuring the high capacity of medium- and large-sized lithium-ion secondary batteries. In this study, we researched coating technology to improve the separator's thermal stability. We minimized the coating time by optimizing the design of a vertical two-stage coater that was thin, uniform, and capable of coating on both sides at the same time with a maximum 2㎛ thickness coating layer of fluorinated polymer (PVdF-HFP) on the bare polyethylene (PE) separator, which increased the thermal stability. In addition, during the coating process, a dual-jacket-roll method of drying was developed that increased the drying effectiveness without thermal damage to the separator. We also investigated the thermal stability of the separator manufactured from a coating machine, and studied the battery-applied performance by making a lithium-ion pouch battery.