• 제목/요약/키워드: fluorescent compound

검색결과 66건 처리시간 0.02초

Acid-Base and Spectroscopic Properties of 1,4-Benzodiazepines in Sodium Dodecyl Sulfate Micellar Solutions

  • Joon Woo Park;Hye Sung Cho
    • Bulletin of the Korean Chemical Society
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    • 제11권1호
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    • pp.54-58
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    • 1990
  • Acid-base equilibria and spectroscopic properties of diazepam and chlorodiazepoxide were investigated in sodium dodecyl sulfate (SDS) micellar solutions as functions of pH. The results were compared with the behaviors in homogeneous aqueous media. The presence of SDS increased the $pK_a$ of chlorodiazepoxide to 6.3 from 4.7, while it has little effect on the $pK_a$ of diazepam. The acidic protonated form of diazepam was moderately fluorescent when the solution was excited at 350 nm, and emissnion intensity of the species was enhanced about 5 fold by the presence of SDS. On the other hand, the acidic solution of chlorodiazepoxide was non-fluorescent, but the neutral solution of the compound was fluorescent upon excitation at 350 nm. The emission peak of the neutral chlorodiazepoxide shifted to shorter wavelength region without significant change in the emission intensity upon the addition of SDS. Procedures for assay of the individual drugs from their mixture by the use of SDS micelle were discussed.

인디고 염색제품에 대한 자외선흡수제의 응용효과 (An Aplication Effect of UV-Absorbent on The Indigo Dyed Products)

  • 차옥선;양진숙
    • 한국의류학회지
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    • 제23권6호
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    • pp.909-918
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    • 1999
  • The indigo-dyed blue denim garments are favored not only by young people but also by almost everyone of life, In the early years they were casually worn on most occasions but became universal recently. Such denim garments are treated with various process to give it optimal softness and color contrast of blue and white. The processess can generate photoyellowing and thus the yellowing may damage their appearance and quality. So this study is to find the solutions to reduce the photoyellowing problem. For this prupose sample denim were treated with cellulase fluorescent brightener UV absorbent etc. The results were as follows; The yellowing would be more accelerated by fluorescent brightening. Since the yellowing was reduced by 90% In particular the application of the UV absorbent before using of the fluorescent brightener was most effective. The optimal concentration was 0.5% (o.w.f) and the benzophenone compounds were found most effective for the indigo denim. And reduction effect of yellowing by UV absorbent was lowered with repeated laundering but metal compound treatment on fabric made a removal of UV absorbent by laundering prevented.

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벼논에서 벼멸구(Nilaparvata lugens Stal)약충 두부의 형광성 반점에 의한 식별법 (Discrimination Method of Brown Planthopper, Nilaparvata lugens(Stal) Nymphs by the Fluorescent Spots between Compound Eyes in Rice Paddies)

  • 조성래;이동운;추호렬;박정규;신현열;김형환
    • 한국응용곤충학회지
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    • 제42권4호
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    • pp.361-365
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    • 2003
  • 우리나라의 벼논에는 벼를 기주로 하는 여러 종류의 멸구, 즉, 벼멸구, 애멸구, 흰등멸구 들이 혼재하고 있지만 이들간의 구분은 쉽지 않다. 이들의 정확한 식별은 예찰과 방제 전략에서 필수적인 과정이다. 특히, 벼멸구는 가장 중요한 벼의 해충이기 때문에 비전문가에 있어 쉽고, 신뢰성 높은 식별 방법이 요구된다. 따라서 벼논에 분포하고 있는 벼멸구의 정확한 구분을 위하여 벼멸구, 애멸구, 흰등멸구의 약충을 조사한 결과. 두 종류의 해충에 비하여 벼멸구 약충은 다른 특징을 지니고 있었다. 측, 벼멸구 약충은 겹눈 아랫부분과 촉각 사이에 흰색형광성광택을 가지고 있었지만 애멸구나 흰등멸구의 약충에는 없었다. 그리고 형광성 반점은 부화직후 가장 선명하였고, 령기가 진행될수록 약해지다가 성충이 되어서는 없어졌다. 따라서 두부의 형광성반점은 벼멸구 약충의 판별에 활용하는데 있어 혁신적인 방법이라 할 수 있을 것이다.

Heptelidic Acid, a Sesquiterpene Lactone, Inhibits Etoposide-Induced Apoptosis in Human Leukemia U937 Cells

  • Kim, Jin-Hee;Lee, Choong-Hwan
    • Journal of Microbiology and Biotechnology
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    • 제19권8호
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    • pp.787-791
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    • 2009
  • In the course of screening for substances that inhibit etoposide (10 ${\mu}g$/ml)-induced apoptosis in human leukemia U937 cells, fungal strain F000120, which exhibits potent inhibitory activity, was selected. The active compound was purified from an ethyl acetate extract of the microorganism by Sep-pak $C_{18}$ column chromatography and HPLC, and was identified as heptelidic acid (koningic acid) by spectroscopic methods. This compound inhibited caspase-3 induction in U937 cells with an $IC_{50}$ value of 40 ${\mu}M$ after 8 h of etoposide treatment. Fluorescent dye staining with acridine orange and ethidium bromide showed that heptelidic acid inhibited apoptosis. Furthermore, it was found that DNA fragmentation and caspase-3 activation, the biological hallmarks of apoptosis, were inhibited by the compound in a dose-dependent manner, suggesting that heptelidic acid inhibits etoposide-induced apoptosis via downregulation of caspases.

실내에서 LED광질이 관엽식물의 생장에 미치는 영향 (The Effects of LED Light Quality on Foliage Plants Growths in Interior Environment)

  • 김명선;채수천;이명원;박갑순;안승원
    • 한국환경과학회지
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    • 제22권11호
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    • pp.1499-1508
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    • 2013
  • In the results of investigating the role of LED light quality in enhancing the ornamental value of indoor foliage plants, amber and red light increased plant height, leaf width, and leaf stalk, and the consequent tree shape decreased the ornamental value. The chlorophyll content increased significantly under white light and compound light. With regard to the effect of plant leaf color on ornamental value, the value of lightness was markedly enhanced by red light. As to the functionality of plants according to photosynthetic activity, plants such as Dieffenbachia, Clusia, and Dracaena were found favorable to those staying indoors for a longtime from morning to evening. Spathiphyllum, and Ficus were found to be recommendable for indoor spaces used actively during afternoon because their photosynthesis was activated in the afternoon. With regard to power consumption according to light quality, white light consumed 119 W/hour, around 45% lower than that of fluorescent lamps, so it is considered the optimal artificial light quality that can enhance energy efficiency. Red light consumed 72 W/hour, only 33% of that of fluorescent lamps, but it was not considered the optimal light quality because plant growth was poor under the light quality. White light and compound light were found to be the ideal light sources for improving the functionality and ornamental value of indoor plants and reducing the cost of maintenance, but because compound light hinders people from recognizing the original color of plants and makes their eyes easily tired, white light was considered the optimal light satisfying all of the ornamental value, economic efficiency and functionality resulting from plant growth.

Eastern Staining: A Simple Recombinant Protein Detection Technology Using a Small Peptide Tag and Its Counter Partner Which is a Fluorescent Compound

  • Lee, Jae-Jung;Kim, Jun-Young;Zhai, Duanting;Yun, Seong-Wook;Chang, Young-Tae
    • Interdisciplinary Bio Central
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    • 제4권2호
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    • pp.5.1-5.9
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    • 2012
  • Small peptide tags such as c-myc, HA, or FLAG tag have facilitated efficient Western-blotting of proteins of interest especially when specific antibodies for the proteins are not available. However, the conventional Western-blotting requires the multi-steps process taking at least several hours up to two days. With examples of various applications, here we show a convenient and time-saving method for protein detection which employs a fluorescent chemical BDED and its binding peptide RC-tag. And we propose "Estern staining", as a standard term for protein detection method using fluorescent chemicals and their binding small peptide tags. Eastern staining may substitutes for the time-consuming "immuno-staining" in many versatile applications.

Determination of Aloesin in Plasma by High-Performance Liquid Chromatography as Fluorescent 9-Anthroyl Derivative

  • Kim, Kyeong-Ho;Lee, Jin-Gyun;Park, Jeong-Hill;Shin, Young-Geun;Lee, Seung-Ki;Cho, Tae-Hyung
    • Archives of Pharmacal Research
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    • 제21권6호
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    • pp.651-656
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    • 1998
  • A sensitive high-performance liquid chromatographic (HPLC) method for the determination of aloesin in plasma was developed. After solid-phase extraction from plasma and derivatization of aloesin and compound AD-1, which was prepared from aloesin as a internal standard, with 9-anthroylnitrile in the presence of quinuclidine, the derivatives were separated on a Inertsil ODS-3 column using acetonitrile/methanol/water (3:1:6) as a mobile phase, and detected fluorimetrically at 460nm with excitation at 360nm. The detection limit of aloesin was 3.2ng/ml in plasma (S/N=3).

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뉴스초점 - LED산업 현황 및 육성의 필요성 (The Present Condition of LED Industry and Necessity of Promote it)

  • 하재찬
    • 기술사
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    • 제42권5호
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    • pp.41-45
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    • 2009
  • The last century of lighting has been dominated by incandescent, fluorescent and high-intensity discharge(HID)light sources. In the late 1970's, after green LEDs were invented, Dr. Ching Tang at Eastman Kodak discovered that sending an electrical impulse through carbon compound caused such material glow. Present day LED commercial packages have reached 100 lm/W, comparable to the efficacies of fluorescent and certain HID lamps. LED products available today are market as "Green-Industry" but actually low light output compared to typical light sources. The combination of high price and low light output make them a poor replacement for current technology. It is very important to compare new LED products to the most efficient conventional technology that could be used for any specific application. As LED technology advances, costs decrease, and efficiency improves, LEDs will build market share in the general illumination market.

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On-Off Type Mechanofluorochromism of a Novel Fluorescent Amorphous Molecular Material, N-{4-[Bis(4-methylphenyl)amino]benzylidene}aniline

  • Manabe, Satoshi;Nagata, Eisuke;Nakano, Hideyuki
    • Rapid Communication in Photoscience
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    • 제3권2호
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    • pp.38-41
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    • 2014
  • The title compound (BMBZA) was designed and synthesized as a novel fluorescent amorphous molecular material. BMBZA was found to exhibit solvatofluorochromism and to readily form an amorphous glass by cooling the melt on standing. In addition, the morphological change from crystalline state to amorphous one could be induced by mechanical grinding. Although fluorescence was scarcely observed for the crystalline sample of BMBZA, the grinding the sample was found to enhance the fluorescence emission, that is, BMBZA exhibited on-off type mechanofluorochromism.