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http://dx.doi.org/10.5857/RCP.2014.3.2.38

On-Off Type Mechanofluorochromism of a Novel Fluorescent Amorphous Molecular Material, N-{4-[Bis(4-methylphenyl)amino]benzylidene}aniline  

Manabe, Satoshi (Department of Applied Chemistry, Muroran Institute of Technology)
Nagata, Eisuke (Department of Applied Chemistry, Muroran Institute of Technology)
Nakano, Hideyuki (Department of Applied Chemistry, Muroran Institute of Technology)
Publication Information
Rapid Communication in Photoscience / v.3, no.2, 2014 , pp. 38-41 More about this Journal
Abstract
The title compound (BMBZA) was designed and synthesized as a novel fluorescent amorphous molecular material. BMBZA was found to exhibit solvatofluorochromism and to readily form an amorphous glass by cooling the melt on standing. In addition, the morphological change from crystalline state to amorphous one could be induced by mechanical grinding. Although fluorescence was scarcely observed for the crystalline sample of BMBZA, the grinding the sample was found to enhance the fluorescence emission, that is, BMBZA exhibited on-off type mechanofluorochromism.
Keywords
mechanofluorochromism; fluorescence; amorphous molecular material; morphology;
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