• Title/Summary/Keyword: flat membrane

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Ultrafiltration of oil-in-water emulsion: Analysis of fouling mechanism

  • Chakrabarty, B.;Ghoshal, A.K.;Purkait, M.K.
    • Membrane and Water Treatment
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    • v.1 no.4
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    • pp.297-316
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    • 2010
  • Membrane fouling is one of the major operational concerns of membrane processes which results in loss of productivity. This paper investigates the ultrafiltration (UF) results of synthetic oil-in-water (o/w) emulsion using flat sheets of polysulfone (PSf) membrane synthesized with four different compositions. The aim is to identify the mechanisms responsible for the observed permeate flux reduction with time for different PSf membranes. The experiments were carried out at four transmembrane pressures i.e., 68.9 kPa, 103.4 kPa, 137.9 kPa and 172.4 kPa. Three initial oil concentrations i.e., 75 $mgL^{-1}$, 100 $mgL^{-1}$ and 200 $mgL^{-1}$ were considered. The resistance-in-series (RIS) model was applied to interpret the data and on that basis, the individual resistances were evaluated. The significances of these resistances were studied in relation to parameters, namely, transmembrane pressure and initial oil concentration. The total resistance to permeate flow is found to increase with increase in both transmembrane pressure and initial oil concentration while for higher oil concentration, resistance due to concentration polarization is found to be the prevailing resistance. The applicability of the constant pressure filtration models to the experimental data was also tested to explain the blocking process. The study shows that intermediate pore blocking is the dominant mechanism at the initial period of UF while in the later period, the fouling process is found to approach cake filtration like mechanism. However, the duration of pore blocking mechanism is different for different membranes depending on their morphological and permeation properties.

Review on Antifouling Membranes with Surface-Patterning for Water Purification (물 정화를 위한 표면패턴화된 내오염성 분리막에 대한 총설)

  • Aung, Hein Htet;Patel, Rajkumar;Kim, Jong Hak
    • Membrane Journal
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    • v.31 no.3
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    • pp.161-169
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    • 2021
  • As clean water continues to be a demand in this global water crisis, development of separation membrane technology for water purification becomes a necessity. The effectiveness of separation membranes is hindered in the water crisis due to fouling of membranes. To address this problem, the application of patterns on flat membranes via various methods have been recently studied and experimented. Patterned membranes have shown to not only reduce the fouling effects of membranes, but also increase the fluxes depending on the method and materials used. Each application has shown benefits that include, but not limited to, enhanced surface area, higher pure-water permeability, and increased number of filtration cycles. In this review, the effects of patterned membranes against antifouling is summarized and discussed.

Magnetic Orientations of Bull Sperm Treated by DTT or Heparin

  • Suga, D.;Shinjo, A.;Kumianto, E.;Nakada, T.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.1
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    • pp.10-18
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    • 2000
  • This paper describes the magnetic orientation of the intact and demembranated bull sperm treated by DTT or heparin in a 5,400 G static field. Semen samples collected from four bulls (Japanese Black) were mixed to the same sperm density. One percentage triton X-100 was used to extract the plasma membrane. The intact and demembranated sperm suspensions were treated with 20, 200, 2,000 mM DTT, 100, 1,000 or 10,000 units heparin solutions at $4{^{\circ}C}$ for 6 days. The decondensation of the sperm nuclei treated by DTT or heparin was examined by measuring the sperm head area at 1, 3, and 6 days. After measuring the area, each sperm sample was exposed to a 5,400 G static magnetic field generated by Nd-Fe-B permanent magnets for 24 hours at room temperature. Results showed that the decondensation of bull sperm nuclei was not induced by the heparin treatment, however, incomplete decondensation was induced by the DTT treatment. During the magnetic orientation, bull sperms treated by DTT or heparin had low percentages of long axis perpendicular to the magnetic lines of force. However, different aspects were obtained for long axis perpendicular orientations following treatment of DTT or heparin. Through the DTT treatment, the decline of long axis perpendicularly oriented percentages was due to the increase of long axis parallel orientation with the head of the flat plane perpendicular to the magnetic lines of force, whereas, using the heparin treatment, the decline of long axis perpendicular orientation was due to the increment of long axis parallel orientation with the head of the flat plane parallel to the magnetic lines of force. Also, percentages of the head of the flat plane perpendicular were decreased by the heparin treatment. These findings suggest that maintaining the structure of protamine in the chromatin is necessary for the sperm head to orient with its flat plane perpendicular, and maintaining the disulfide bond in the chromatin is necessary for the long axis of sperm to orient perpendicularly.

Low Actuation Voltage Capacitive Shunt RF-MEMS Switch Using a Corrugated Bridge with HRS MEMS Package

  • Song Yo-Tak;Lee Hai-Young;Esashi Masayoshi
    • Journal of electromagnetic engineering and science
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    • v.6 no.2
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    • pp.135-145
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    • 2006
  • This paper presents the theory, design, fabrication and characterization of the novel low actuation voltage capacitive shunt RF-MEMS switch using a corrugated membrane with HRS MEMS packaging. Analytical analyses and experimental results have been carried out to derive algebraic expressions for the mechanical actuation mechanics of corrugated membrane for a low residual stress. It is shown that the residual stress of both types of corrugated and flat membranes can be modeled with the help of a mechanics theory. The residual stress in corrugated membranes is calculated using a geometrical model and is confirmed by finite element method(FEM) analysis and experimental results. The corrugated electrostatic actuated bridge is suspended over a concave structure of CPW, with sputtered nickel(Ni) as the structural material for the bridge and gold for CPW line, fabricated on high-resistivity silicon(HRS) substrate. The corrugated switch on concave structure requires lower actuation voltage than the flat switch on planar structure in various thickness bridges. The residual stress is very low by corrugating both ends of the bridge on concave structure. The residual stress of the bridge material and structure is critical to lower the actuation voltage. The Self-alignment HRS MEMS package of the RF-MEMS switch with a $15{\Omega}{\cdot}cm$ lightly-doped Si chip carrier also shows no parasitic leakage resonances and is verified as an effective packaging solution for the low cost and high performance coplanar MMICs.

Effect of Polymer Structure on Membrane Morphology by Addition of 2-butoxyethanol (2-butoxyethanol 첨가에 따른 고분자 구조가 분리막 구조에 미치는 영향)

  • Son, Ye-Ji;Kim, No-Won
    • Membrane Journal
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    • v.21 no.4
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    • pp.377-388
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    • 2011
  • Flat sheet microfiltration membranes were prepared with polysulfone (PSF), polyethersulfone (PES), and polyphenylsulfone (PPS) by an immersion precipitation phase inversion method. In this method, dimethyl formamide (DMF) and polyvinylpyrrolidone (PVP) were used as a solvent and a wetting polymer additive, respectively. 2-butoxyethanol (BE) was used as a nonsolvent additive catalyst to form pore. The morphology of membranes was investigated by scanning electron microscopy and micropermporometer. The permeability of the membranes was evaluated with the flux of pure water. When the BE was added, the pore size of membranes became larger than blank membranes. The changes in the morphology of membrane due to the BE addition depend on polymer structure. All membranes have similar mean pore size and porosity. The mean pore sizes of PSF, PES, and PPS membranes were 0.282, 0.330 $0.308{\mu}m$, respectively. The porosities of PSF, PES and PPS membranes were 68.5, 66.1, 66.4%, respectively. However, the PPS membrane showed higher pore density on surface and narrower pore size distribution than PSF or PES membrane does. As a result, the pure water flux of PPS membrane ($357L/m^2\;hr$) was higher than that of PSF ($196L/m^2\;hr$) or PES membrane ($214L/m^2\;hr$).

Efficient removal of radioactive waste from solution by two-dimensional activated carbon/Nano hydroxyapatite composites

  • El Said, Nessem;Kassem, Amany T.
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.327-334
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    • 2018
  • The nano/micro composites with highly porous surface area have attracted of great interest, particularly the synthesis of porous and thin film sheets of high performance. In this paper, an easy method of cost-effective synthesis of thin film ceramic fiber membranes based on Hydroxyapatite, and activated carbon by turned into studied to be applied within the service-facilitated the transport of radioactive waste such as $^{90}Sr$, $^{137}Cs$ and $^{60}Co$) as activated product of radioisotopes from ETRR-2 research reactor and dissolved in 3M $HNO_3$, across a thin flat-sheet supported liquid membrane (TFSSLM). Radionuclides are transported from alkaline pH values. The presence of sodium salts in the aqueous media improves in $HNO_3$, the lowering of permeability because the initial $HNO_3$ concentration is improved. The study some parameters on the thin sheet ceramic supported liquid membrane. EDTA as stripping phase concentration, time of extraction and temperature were studied. The study of maximum permeability of radioisotopes for all parameters. The pertraction of a radioactive waste solution from nitrate medium were examined at the optimized conditions. Under the optimum experimental 98.6-99.9% of $^{90}Sr$, 79.65-80.3% of $^{137}Cs$ and $^{60}Co$ 45.5-55.5% in 90-110 min with were extracted in 10-30 min, respectively. The process of diffusion in liquid membranes is governed by the chemical diffusion process.

A Study on Application of Corrugated Invar Strake Edge in the Membrane Cargo Containment of LNG Carriers (LNG선 화물격납용기 Invar strake edge 이음부 형상 개선에 관한 연구)

  • Han, Jong-Man
    • Journal of Welding and Joining
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    • v.27 no.5
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    • pp.74-80
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    • 2009
  • The membrane of the LNG carriers consists of thin strips of INVAR(Fe-36%Ni) steel plates, and the junction between INVAR strips is fabricated by welding. Thousands of the raised edge joints, regularly spaced, are located around all the side of the tank corner near the transverse bulkhead, and TIG welding is manually made on the top of the raised edges. Since the thickness of all the laminated edge plies is extremely thin and the weld position is under a bad accessibility, highly skilled workers are required to perform welding relatively for a long welding time. An alternative scheme for the corner membrane fabrication is proposed in the study to improve the installation workability and thus productivity. The scheme replaces the welded edges with the preformed corrugation ones. A panel strip with regularly-spaced corrugations is installed at the corner instead of the individual flat strip of which edge is vertically raised to be welded with the adjacent strip. In the study, a series of the evaluation on the corrugated edge members was performed to assess the applicability to the real LNG carrier fabrication. Opening displacement at the raised edge was experimentally examined. Elastic stiffness regressed from the displacement was nearly same in both edge types. Edge displacement and local stresses were calculated under hydrostatic pressure and temperature change due to liquefied cargo. Fatigue test was performed on both corrugated and welded edge specimens consisting of two or five plies of invar strips. Fatigue strength of the corrugated specimens was not less than that of the welded specimens.

Preparation of Nanoporous Ceramic Membranes by Sol-gel Method and Characterization of Gas Permeation (졸-겔법에 의한 나노기공성 세라믹 막의 제조 및 기체투과 특성)

  • Lee, Yong-Taek;Choi, Ga-Young;Han, Hyuk-Hee
    • Membrane Journal
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    • v.18 no.2
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    • pp.176-184
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    • 2008
  • Nano-porous ceramic membranes was synthesized by the sol-gel method. Gas permeation of hydrogen and nitrogen was determined by single composition gas. Pore size $0.1{\mu}m$ and porosity 32% of flat type ${\alpha}-Al_2O_3$ substrate was manufactured. An intermediate ${\gamma}-Al_2O_3$ layer with pore size of 4 nm was formed by dip-coating. Polymeric silica sol was synthesized by acid catalyzed hydrolysis and condensation of tetra-ethyl-ortho-silicate. Supported membranes on alumina were prepared by dipping and calcining. He, $N_2$ permeation experiments with nanoporous sol-gel modified supported ceramic membranes were peformed to determine the gas transport characteristics. $He/N_2$ permselectivity around $100{\sim}160$ and helium permeation in the order of $10^{-7}mol/m^2{\cdot}s{\cdot}Pa$ were measured in the temperature range of $303{\sim}363K$.

Effect of the Shape and Size of Quorum-Quenching Media on Biofouling Control in Membrane Bioreactors for Wastewater TreatmentS

  • Lee, Seonki;Lee, Sang Hyun;Lee, Kibaek;Kwon, Hyeokpil;Nahm, Chang Hyun;Lee, Chung-Hak;Park, Pyung-Kyu;Choo, Kwang-Ho;Lee, Jung-Kee;Oh, Hyun-Suk
    • Journal of Microbiology and Biotechnology
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    • v.26 no.10
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    • pp.1746-1754
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    • 2016
  • Recently, spherical beads entrapping quorum quenching (QQ) bacteria have been reported as effective moving QQ-media for biofouling control in MBRs for wastewater treatment owing to their combined effects of biological (i.e., quorum quenching) and physical washing. Taking into account both the mass transfer of signal molecules through the QQ-medium and collision efficiencies of the QQ-medium against the filtration membranes in a bioreactor, a cylindrical medium (QQ-cylinder) was developed as a new shape of moving QQ-medium. The QQ-cylinders were compared with previous QQ-beads in terms of the QQ activity and the physical washing effect under identical loading volumes of each medium in batch tests. It was found that the QQ activity of a QQ-medium was highly dependent on its specific surface area, regardless of the shape of the medium. In contrast, the physical washing effect of a QQ-medium was greatly affected by its geometric structure. The enhanced anti-biofouling property of the QQ-cylinders relative to QQ-beads was confirmed in a continuous laboratory-scale MBR with a flat-sheet membrane module.

Effect of pH in Hybrid Water Treatment Process of PVdF Nanofibers Spiral Wound Microfiltration and Granular Activated Carbon (PVdF 나노섬유 나권형 정밀여과와 입상 활성탄의 혼성 수처리 공정에서 pH의 영향)

  • Kyung, Kyu Myung;Park, Jin Yong
    • Membrane Journal
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    • v.25 no.4
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    • pp.358-366
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    • 2015
  • Flat membrane with $0.4{\mu}m$ pore size was prepared with PVdF (polyvinylidene fluoride) nanofiber, which has the advantages such as excellent strength, chemical resistance, nontoxic, non-combustibility. After that, spiral wound module was manufactured with it including a woven paper. Effect of pH was studied by comparing permeate fluxes and rejection rates of the spiral wound module using simulation solution including kaolin and humic acid. The recovery rate and filtration resistance were calculated after water back-washing at the end of filtration experiment. In addition, after the water filtrated by the spiral wound module was passed through a column filled with GAC (granular activated carbon), adsorption effect of GAC was investigated by measuring the turbidity and $UV_{254}$ absorbance.