• Title/Summary/Keyword: flammability

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Evaluation of the Burning Properties of Various Carpet Samples by using the Cone Calorimeter and Gas Toxicity Test (콘칼로리미터와 가스유해성 시험법을 이용한 카페트류의 연소특성 평가)

  • Lee, Bong-Woo;Kwon, Seong-Pil;Lee, Jang-Won;Lee, Byoung-Ho;Kim, Hee-Soo;Kim, Hyun-Joong
    • Fire Science and Engineering
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    • v.23 no.6
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    • pp.1-9
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    • 2009
  • In this study, the burning behaviours of five different kinds of carpet samples covered with nylon, PP (polypropylene), PTT (poly(trimethylene terephthalate)), wool fabric and NW (nylon and wool) were evaluated by using the cone calorimeter having a radiant flux of 50kW/$m^2$. And the combustion gas toxicity was evaluated according to KS F 2271 test method. As a result of the cone calorimeter test (KS F ISO 5660-1), nylon carpet samples were ignited most easily. In ignition ability or initial flammability, NW carpet samples showed the highest value. In heat release rate (HRR), fire intensity, PP carpet samples were larger than any other samples. Nylon carpet samples were the highest smoke production rate, while N/W carpet samples the lowest. The following were in mass loss rates: NW > wool > nylon > PP > PTT. CO (carbon monoxide) was one of the most toxic gases released from the combustion. PTT carpet samples gave rise to the highest CO concentration, while NW carpet samples the lowest. In addition, PP carpet samples caused the highest $CO_2$ (carbon dioxide) concentration, while NW carpet samples the lowest. Toxicity of the gas produced from carpet samples was determined by the mouse stop motion, and it resulted in the fact that the combustion gas of PTT carpet samples was more toxic than that of any other samples.

A numerical analysis study on the flammable volume by leakage of hydrogen fuel vehicles in parking lot (지하주차장 내 수소연료차의 수소 방출시 가연체적에 관한 수치해석적 연구)

  • Lee, Ho-Hyung;Kim, Hyo-Gyu;Yoo, Ji-Oh;Kim, Doo-Young
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.6
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    • pp.439-449
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    • 2021
  • The recent reduction in greenhouse gases, interest in environmental pollution such as low-carbon emission policies is increasing. Accordingly, the penetration rate of eco-friendly vehicles, including hydrogen battery vehicles capable of reducing carbon emission, is increasing, and thus it is required for disaster prevention and safety-related measures. In this study, the degree of risk for the concentration distribution of hydrogen when leaking hydrogen fuel vehicles according to ventilation conditions was analyzed through numerical analysis, limited to places in parking lots. As a result, when only one hydrogen tank was released, the combustible volume ratio of hydrogen in the underground parking lot was up to 8.6%, and as ventilation continued, the volume ratio of combustible hydrogen decreased to less than 1% after 150 seconds, indicating that mechanical ventilation is essential. In the case of simultaneous release or stage release of three hydrogen tanks, the final combustible volume ratio of hydrogen is similar, but the increase in the combustible volume ratio of hydrogen in the early stage of release is low, and further research is expected.

Recent Progress and Perspectives of Solid Electrolytes for Lithium Rechargeable Batteries (리튬이차전지용 고체 전해질의 최근 진전과 전망)

  • Kim, Jumi;Oh, Jimin;Kim, Ju Young;Lee, Young-Gi;Kim, Kwang Man
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.87-103
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    • 2019
  • Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

A Study on the Possibility of Using Fire-Retardant Working Cloth Made from Silicon Carbide (SiC) Composite Spun Yarns (Silicon Carbide (SiC) 복합방적사로부터 제조된 원단의 방화복 활용 가능성에 관한 연구)

  • Kang, Hyun-Ju;Kang, Gun-Woong;Kwon, Oh-Hoon;Kwon, Hyeon-Myoung;Hwang, Ye-Eun;Jeon, Hye-Ji;Joo, Jong-Hyun;Park, Yong-Wan
    • Science of Emotion and Sensibility
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    • v.24 no.4
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    • pp.149-156
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    • 2021
  • The mechanical properties of a woven fabric made of SiC (silicon carbide) fibers were determined in this study using the KES-FB system. The woven fabric is used in high heat settings above 1500℃. Composite spun yarns were used to create SiC fibers. By analyzing the wearing properties, we studied the prospect of using the textiles as fire-retardant work clothes. Mechanical properties determine the wearing attributes. Therefore, the tensile linearity (LT), tensile resilience (RT), and shear stiffness (G) values of the fabric varied according to the yarn type (filament or spun yarn). The thickness, weight per square meter, and density of the fabric were found to have an effect on the shear hysteresis (2HG) and compression resilience (RC) values. In terms of wearable clothing qualities, the fabric qualities of the SiC composite yarn demonstrated the highest ratio of compressive energy to thickness (WC/T), which indicates bulkiness. The fabric manufactured from SiC composite yarns passed the KFI criteria for carbonation length and cumulative flame time in the flame-retardant test. Therefore, we discovered that the material can be used as a fire-resistant work cloth.

Analysis of Damage Impact Range according to the NG/NH3 Mixing Ratio when applying Ammonia as Fuel for a Combined Cycle Power Plant using an ALOHA Program (ALOHA 프로그램을 활용한 복합화력발전소 내 암모니아 연료 적용 시 NG/NH3 혼소율에 따른 피해영향범위 분석)

  • Yoo Jeong Choi;Hee Kyung Park;Min Chul Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.73-84
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    • 2024
  • In this study, a quantitative risk impact assessment is performed using an ALOHA program to identify the risks when applying ammonia as fuel for combined cycle power plants as one of the solutions of climate change. The worst and the alternative accident scenarios are established for the Sejong combined cycle power plant and the effective ranges are calculated in terms of flammability, thermal radiation, overpressure and toxicity. The analysis results show that the toxic risk is the most critical and the effective distance is highly proportional to the mixing ratio of natural gas and ammonia by showing the Pearson's correlation coefficient over 98% as 0.991, 0.987 and 0.989 for the Level Of Concern(LOC)-1, LOC-2 and LOC-3, respectively. In addition, the coefficients of linearity for LOC-1, LOC-2 and LOC-3 are calculated to 133, 70 and 29, respectively so it can be confirmed that the effective distance increases as the criterion decreases.

Estimating the Area of Damage Caused by Gas Pipeline Leakage in Subway Construction Zones (지하철역 공사지역 도시가스 배관 누출로 인한 피해면적 산정)

  • Yang, Yong-Ho;Lee, Jae-Wook;Kong, Ha-Sung
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.2
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    • pp.419-427
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    • 2024
  • This study assessed the potential impact of gas leakage resulting from accidental damage to buried urban gas pipelines during perforating operation near subway construction sites. The risk of explosions due to ignition sources such as static electricity, arising from gas infiltrating the subway construction site through storm sewers and sewage pipes, was evaluated using the ALOHA program. The results of the threat zone calculation, which input various parameters of urban gas pipelines such as length, diameter, and pressure, indicated that the flammable area within the vapor cloud extended from 1.2 to 1.4 km (red zone), the blast area ranged from 0.8 to 1.0 km (yellow zone), and the jet fire extended from 45 to 61 m (red zone). This study demonstrates that within the flammable area of the vapor cloud, a specific combination of concentration and conditions can increase flammability. The blast area may experience explosions with a pressure of 1.0 psi, sufficient to break glass windows. In the event of a jet fire, high temperatures and intense radiant heat exposure lead to rapid fire propagation in densely populated areas, posing a high risk of casualties. The findings are presented in terms of the sphere of influence and threat zone ranges.

Preparation and physical properties of flame retardant high density polyethylene utilizing inorganic waste shell powder (재활용(再活用) 굴 껍질 분말(粉末)을 이용(利用)한 고밀도 폴리에틸렌계 난연 소재(素材)의 제조(製造)와 물성(物性))

  • Choi, Jae-Won;Cho, Tae-Keun;Ahn, Jun-Hyung;Lee, Sung-Ho;Chung, Yong-Chan;Jeon, Ho-Seok;Chun, Byoung-Chul
    • Resources Recycling
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    • v.17 no.4
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    • pp.21-29
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    • 2008
  • Waste shell powder was added to the high density polyethylene(HDPE), and resultant mechanical properties and flame retardancy were analyzed in terms of shell content. Compatibilizer(PE-g-MA) was used to enhance the mechanical properties of the prepared HDPE/shell composites, and several flame retardant agents($Al_2O_3$, $Sb_2O_3$) were utilized to improve flame retardancy. Addition of the compatibilizer resulted in an improved mechanical properties due to the increased interfacial bonding between HDPE matrix and shell powder. In the case of impact strength, it even reached to the impact strength of pure HDPE. Also the addition of the flame retardant agents did not exhibit mechanical property decrease. UL-94 flammability test on the prepared HDPE/shell composites indicated that at 40wt% of shell only inclusion, time to ignite the flame and the total time of flame duration increased. When flame retardant agents mixed with shell powder were added to the HDPE matrix, improved flame retardancy was observed. Generally, flame retardancy effect of $Al_2O_3$ was better than $Sb_2O_3$. UL-94 V-0 classification was observed for the specimens with $Al_2O_3$ and compatibilizer at more than 40wt% shell, and also for specimens with $Sb_2O_3$ and compatibilizer at all shell content.