• Journal of the Korean Wood Science and Technology
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• v.12 no.2
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• pp.3-9
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• 1984

This study was carried out to examine the practicality of DAP[$(NH_4)_2HPO_4$] as fire retardant for plywood by static bending test the redried plywoods which had been soaked in 20% $(NH_4)_2HPO_4$ solution. Being hot/cold soaked in the solution for 3/3, 6/3, 9/3 and 12/3 hours and redried by cyclic press-drying method at the platen temp. of 130, 145, 100 and $175^{\circ}C$, the treated plywoods were tested to offer the mechanical data, that is, $S_{pl}$(stress at proportional limit), MOE(modulus of elasticity), MOR(modulus of rupture) and $W_{pl}$(work per unit volume to proportional limit ) in flexure. The results obtained were summarized as follows. 1. $S_{pl}$ of fire retardant treated plywoods ("FRP" would be used hereinafter) decreased as the platen temperature increased, but it was superior to that of non-treated plywoods(Control) at $160^{\circ}C$ or higher. 2. MOE of FRP decreased roughly with the increase of temperature, hut this tendency was not constant. And the value of FRP was higher than that of Control even at $175^{\circ}C$. 3. MOR of FRP showed same temperature-dependent tendency as MOE, but it was influenced more sensitively at the higher temperature. 4. $W_{pl}$ of FRP also decreased gradually with the increase of platen temperature and the value in DAP 9/3 treatment was Jess than 70% of control plywoods. 5. In view of redrying time and mechanical properties, the most reasonable platen temperature for DAP treated FRP was $160^{\circ}C$ in this study.

• Journal of the Korean Wood Science and Technology
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• v.14 no.4
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• pp.21-28
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• 1986

Plywood used for construction as a decorative inner material is inflammable and can fire accident, causing destruction of human life and property. In this study, 3.5mm Kapur plywoods were soaked in the 23% monoammonium phosphate solutions by cold soaking method 3, 6, 9hrs and hot-cold bath method for 3/3hrs, and redrying was carried out by press-drying at the platen temperature of 110, 130, 160, 180$^{\circ}C$, and then fire test was carried out to investigate burning point, flame exhausted length, frame spread length, back side carbonized area and weight loss. The results are as follows; 1. In cold soaking method for 3, 6, 9hrs. retentions of monoammonium phosphate were 0.377, 0.448, 0.498kg/(30cm)$^3$ respectively, and in hot-cold bath method for 3/3hrs, the retention was 1.331kg(30cm)$^3$ that exceeded the minimum retention 1.124kg/(30cm)$^3$. 2. Correlation coefficients among the variable were shown in table 2. From the table, it could be recognized that there were close negative correlations between the treatment and burning point, flame spread length, back side carbonized area, flame exhausted time and weight loss, and there was negative correlation between treating time and back side carbonized area, but there was positive correlation between platen temperature and burning point. 3. From table 3, it can be observed that there were highly significant differences for burning point, flame spread length, flame exhausted time, back side carhonized area, weight loss between treatments. And in 2-way interactions, there were also highly significant for burning point, flame spread length, flame exhausted time, weight loss between time x treatment. 4. It was observed that burning point, flame exhausted time, flame spread length, back side carbonized area, and weight loss in fire-retardant treated plywood were the best effects in fire-retardant treated plywood, water treated plywood and nontreated plywood. In conclusion, I can estimate that absorbed chemical contents by hot-cold bath method for 3/3hrs, have a lot of effects on fire-retardant factors such as burning point, flame spread length, flame exhausted time, backside carbonized area and weight loss, but platen temperatures have a little effects on the fire factors.

• Journal of the Korean Wood Science and Technology
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• v.39 no.3
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• pp.244-251
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• 2011

The combustion characteristics were evaluated for Japanese Red Pine (Pinus Densiflora) and Korean Pine (Pinus Koraensis). These two species are widely used as building member of Korea-style house and volume density of Japanese Red Pine is relatively higher than that of Korean Pine. The combustion characteristics are closely connected with volume density. The differences of two species in both total heat release (THR) and average heat release rate (HRR) seemed to be resulted from the volume density. Toxicity of smoke from the specimens was increased because of fire-retardant treatment.

• Journal of the Korean Society of Combustion
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• v.22 no.4
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• pp.1-8
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• 2017

This study was conducted to evaluate the fire retardant performance of exfoliated graphite nanoplatelets (xGnP) applied for particleboard. This work measured heat release rate(HRR), total heat release(THR) and smoke production rate(SPR) of xGnP added particleboard, using cone calorimeter to assess its fire characteristics according to the KS F ISO 5660-1 standard code. Heat release rates of all specimens treated by xGnP were less than the $200kW/m^2$ for a total experiment period of five minutes. Heat release rates of the specimens coated with xGnP were lower than those of the specimens made by mixing wood particles with xGnP directly. Meanwhile, the total heat release rates of xGnP coated specimen maintained quite lower level than the uncoated so the xGnP coating were effective in improving the fire retardant performance of particleboard. However, the smoke emission peaking problem at the initial combustion period, which was caused by adding base coating materials, should be resolved for further satisfaction as a fire retardant materials.

• Journal of the Korean Wood Science and Technology
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• v.27 no.3
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• pp.39-50
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• 1999

This research was carried out to investigate the development of fire-retardancy treatment technology and performance evaluation of fire-retardant treated plywoods. Radiata pine, keruing, dillenia, calophyllum and terminalia veneers were treated by normal(conventional) pressure soak(NPS) and vacuum-pressure-soak(VPS) using 20% water solution of diammonium phosphate. Then, 4.8mm thick, 3ply plywoods were fabricated with combination of fire-retardant treated, untreated or water-immersion types and several composition types of radiata pine and keruing veneers, i,e. the uniform and the mixed types in species composition, and the homogenious and the alternate layer types in veneer treatment. In composed species, the retention and the treatment effects of fire-retardant chemicals III radiata pine was still greater than those of keruing. The effect of VPS treatment was larger than that of NPS treatment, however, adhesive bonding strength and bending strength of plywoods treated by these two methods were not necessarily lowered, compared to those of untreated plywood. And also, fire endurance performance of the urea melamine resin-bonded plywood was greater than that of the phenol resin-bonded plywood. In result, the appropriate combination in veneer species and layer as well as alternate fire-retardant treatments would be more efficiently available in service.

• Fire Science and Engineering
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• v.15 no.3
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• pp.7-13
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• 2001

In this paper, we had analyzed comsbustion gases according to pyrolysis $600^{\circ}c$, $800^{\circ}c$ and $1000^{\circ}c$ for polymeric material using a GASTEC colorimetric gas detector tube in order to combustion gases toxicity evaluation for flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam of polymeric material. As a result, comsbustion gases producted from small specimens of polymeric material had reached fatal to man at a 30 minute exposure time that had possesed toxicity index. Toxicity index at pyrolysis $800^{\circ}c$ of flexible polyvinyl chloride was 31.74. Flexible polyvinyl chloride was the highest toxicity index of flame retardant untreated ply wood, flame retardant treated ply wood, flexible polyvinyl chloride and flexible polyurethane foam. The comsbustion gases producted commonly no concern with pyrolysis temperature had analyzed carbon dioxide($CO_2$) and carbon monoxide(CO). Toxicity index had investigated differently according to pyrolysis temperature even a similar materal.

• Journal of Korean Society of Forest Science
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• v.64 no.1
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• pp.26-32
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• 1984

This research was conducted to examine the effect of bonding on the bending and shear strength of COMPLY-board when used with meranti face veneer and fire retardant treated particle-board core. For ammonium sulfate, modulus of rupture (MOR) of COMPLY-board increased with increasing chemical concentration up to 10 percent and then decreased after that concentration. However, Minalith showed reverse effect to the result for ammonium sulfate. Modulus of elasticity (MOE) of COMPLY-hoard decreased with increasing chemical concentration and its differences were not significant between concentration. Shear strength was shown better when treated with ammonium sulfate than with Minalith. Wood failure of COMPLY increased with increasing chemical concentration up to 15 percent and then decreased after that concentration. The products of parallel and cross veneer laminated were better than those of COMPLY composed of fire retardant treated particle-board core. Non-treated particle-board was the least in strength. MOE of fire retardant treated COMPLY increased by 136 percent and its MOE by 170 percent as compared with non treated particle-board.

• Journal of the Korean Wood Science and Technology
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• v.15 no.3
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• pp.56-67
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• 1987

Plywoods used for construction as a decorative interior material are inflammable and can make fire accidents, causing destruction of human life and property. Therefore, it is indeed required to make fire-retardant treated plywood. In this study, 3.7mm yellow meranti plywoods were soaked in 18% boric acid solutions and tap water by hot-cold bath for 1/2, 2/2, 4/2, 6/2 hours and redrying of treated plywoods was carried out by press drying at the platen temperature of 110, 130, 160, $180^{\circ}C$ and then it was conducted to investigate solution absorption, drying rates, dynamic young's modulus. specific gravity and fire-retardant factors such as burning point, flame spread length. flame exhausted time, back side carbonized area and weight loss by treating time, treating solutions and platen temperature. The results are as follows; 1. When plywood was impregnated with the hot bath temperature of $70^{\circ}C$ for 1. 2, 4, 6 hours and the cold bath temperature of $15^{\circ}C$ for 2 hours respectively, retentions of boric acid were 1.565, l.597, 1.643, 1.709kg/$(30cm)^3$ and all of them exceeded the minimum retention [1.125kg/$(30cm)^3$] even in the shortest treatment. 2. In hot-cold bath method for 1/2 hours, the drying rates of treated plywood remarkably increased with the extension of platen temperature of 110, 130, 160, $180^{\circ}C$ and the values of boric acid treated plywood were 5.900, 10.196, 45.42, 54.958m.c%/min and the values of water treated plywood were 6.014, 12.373, 46.520, 55.730m.c%/min and drying rates of water treated plywood were faster than those of boric acid treated plywood. 3. The values of boric acid treated plywoods in dynamic young's modulus were widely higher than those of water treated plywoods. And it can be observed that there were highly significant differences for treating time between dynamic young's modulus, and the values of boric acid plywoods increased with the extension of treating time but on the contrary water treated plywoods were decreased values with prolonged time 4. It was observed that there were highly significant differences for platen temperature between dynamic young's modulus. When the values of water treated plywoods in dyna nic young's modulus were abruptly decreased according to the rise of platen temperature. boric acid treated plywoods showed rather increased values at $160^{\circ}C$ of platen temperature. And in 2- way interactions, there were also highly significant for dynamic young's modulus between treating time x treating solutions and platen temperature x treating solutions. 5. Correlation coefficients of fire-retardant factors were shown in table 5. It could be recognized that there were close correlations between the treating solutions and burning point, flame spread length, back side carbonized area, flame exhausted time and weight loss, but there was no correlation between fire-retardant factors and treating time and platen temperature. 6. From table 6, it can be observed that there were highly significant differences for burning point, flame spread length, flame exhausted time, back side carbonized area, weight loss between treating solutions. And in 2-way interactions, there were highly significant for burning point, flame spread length, weight loss between treating time $\times$ treating solutions.

• 한국문화재보존과학회:학술대회논문집
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• 2001.11a
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• pp.27-34
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• 2001

Following the recommendations made by the cultural authorities the wooden cultural properties (WCP) had been treated with fire-retardants for fire protection. However, visual inspections of some of the WCPs treated with fire-retardants showed microbial decay. The work was extended to examine the micromorphological characteristics of the WCPs in a Buddhist temple which had been treated with fire-retardant. Microscopic examination showed the presence of typical soft rot cavities along the length of microfibrils in the secondary wall. Bacterial attack was also observed by scanning and transmission electron microscopy. It is interesting that the decay patterns observed in the Buddhist temple were very similar to those observed in the waterlogged woods. Presumably chemicals in the fire-retardants used rendered the wood susceptible to attack by soft-rot and bacterial decay by causing an increase in the moisture content of wood. Further studies are needed to investigate the effect of fire-retardants used currently on the hygroscopicity and the strength of wood materials in the WCPs. Microbial attacks caused degradation of the secondary cell walls and in some cases also of the middle lamella. In addition, the cell walls in the outer parts of wood were also degraded due to weathering, and cell separation occurred from total disintegration of the middle lamella.

• Journal of the Korean Wood Science and Technology
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• v.11 no.3
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• pp.39-48
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• 1983

This research was performed to investigate the manufacturing possibility of the particleboard treated with commercial fire retardant chemicals. Laboratory test boards at this investigation were made from particles treated by soaking into 5, 10, 15, and 20 percent concentration solutions of ammonium sulfate and Minalith before resin was applied. According to the results, MOR (modulus of repture) and MOE (modulus of elasticity) in flexure exceeded type 100 (100 kgf/$cm^2$, $1.5{\times}10^4\;kgf/cm^2$) of the Korean Industrial Standard (KS F 3104). Except for 15 and 20 percent chemicals concentrations of Minalith, every internal bond stress values met type 100 (1.5 kgf/$cm^2$) of KS F 3104. However thickness swelling values of fire retardant treated particleboards were not reached in the Standard (12%).