• Title/Summary/Keyword: fire retardant materials

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Toxicity Evaluation of the Combustion Products from Synthetic Wood as Internal Finish (건축물 내부 마감재인 합성목재별 연소가스 독성평가)

  • Kim, Jong-Buk;Lee, Si-Young
    • Fire Science and Engineering
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    • v.30 no.2
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    • pp.7-18
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    • 2016
  • This study evaluated the toxicity of the burning gas from the synthetic wood products used in housings or warehouses. The combustion products of five materials, viz. impregnated laminated board, MDF, Douglas fir plywood, core plywood, and Lauan retardant, were analyzed using SEM, FTIR and a Cone Calorimeter. For the Lauan retardant, 256,965 ppm of carbon dioxide ($CO_2$) and 1,475 ppm of sulfur dioxide ($SO_2$) were measured, which are 2.5 times and 3.6 times as high as their lethal concentrations of 100,000 ppm and 400 ppm, respectively. For the impregnated laminated board, 1,569 ppm of nitrogen dioxide ($NO_2$) was measured, which is 6 times as high as its lethal concentration of 250 ppm. For MDF, 795 ppm of ammonia ($NH_3$) was measured, which is higher than its lethal concentration of 750 ppm. As a result, most internal-finishes generated toxic combustion products at levels higher than their lethal concentrations, which underlines the importance of the selection and manufacturing of internal-finish materials.

A Study on Characteristics of Interior design materials in Leisure Boats & Yachts (레저보트${\cdot}$요트의 인테리어재료 특징에 관한 연구)

  • Byun Lyang-Soun
    • Korean Institute of Interior Design Journal
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    • v.15 no.1 s.54
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    • pp.158-165
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    • 2006
  • The space of leisure boats & yachts is formed by interior design elements and shapes are formed by combination of those elements. By means of configuration of the design elements, space is made in a ship and patterns in an inside space are made through production. These space can be categorized as (1) cabin(common cabin, staterooms, one-cabin), (2) salon, (3) galleys & dinette, (4) heads(showers, toilets, bidets, sinks), (5) cockpit, (6) wheelhouses, navigation stations, (7) fore peaks, (8) engine room, (9) deck etc. Interior materials are classified into (1) walls(bulkheads & lining wall), (2) floors(sole), (3) ceilings(overheads), (4) doors & windows, (5) furniture, (6) lightings and (7) Hardware & decoration in large, medium and small sizes, which constitute interior design elements of a leisure boat & yacht. The materials used in leisure boats & yachts have properties of lightweight, noise and vibration resistance, fire & flame retardant, stability, strengths, lifespan, appearance and special operation in construction.

Analysis of the Maximum Heat Release Rate in Accordance with the Test Method of the Flame Retardant Performance for Pipe Insulation (배관용 보온재의 난연 성능 시험방법에 따른 최대 발열량 분석)

  • You, Woo Jun;Park, Jung Wook;Sin, Yeon Je;Park, Hyeong Gyu;Lim, Ohk Kun
    • Fire Science and Engineering
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    • v.34 no.1
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    • pp.18-25
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    • 2020
  • In this study, the heat release rate of pipe insulation is analyzed by considering the installation status in accordance with the standards ISO 20632 and NFPA 274. The flame retardation rate was evaluated for six types of test samples: polyethylene foam covered with beaten silver (PE(S)), PE foam tapped (PE(N)), elastomeric closed cell thermal insulation (rubber), Japanese PE foam (PE(J)), Japanese polyurethane foam (PU(J)), and Japanese styro form (ST(J)) by EN 13501-1 and fire growth curve. The results show that PU(J), PE(J), and PE(N) were Class E and ultra-fast, NFPA 274 test standards for Class D and Fast, and PE(S) by ISO 20632 were Class C and Slow, and Rubber and ST(J) were Classes and Low. However, the changes in the time-averaged maximum heat release rate for each test standard (ISO 20632 and NFPA 274) to evaluate the flame retardation rate differed among identical materials. This means that the fundamental study is necessary to analyze the more accurate reasons.

A Study on Fire Performance Evaluation of EIFS on Anti-Flaming Finish by Cone Calorimeter Test (콘칼로리미터에 의한 외단열시스템의 방염 화재성능평가를 위한 연구)

  • Min, Se-Hong;Sun, Ju-Seok;Kim, Sang-Chul;Choi, Yong-Mook;Lee, Seok-Ki
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.106-111
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    • 2012
  • In this study, EIFS (Exterior insulation finish system) of exterior cladding was applied Cone calorimeter test to confirm the effect of flame retardant. As a results, the initial ignition points in accordance with the coated form and concentration of the flame retardant was delayed. But flame resistant treatment of EIFS cladding to control the fire will not affect confirmed that. In addition, EIFS that uses high-density and low-density due to difference in the density of the impact of the fire was no difference. The exterior of the ignition experiment occurred before and after 40 seconds, heat release rate to 100 seconds appears to occur about 90 % compared with the other exterior wall materials, the initial fire spread very fast was confirmed. EIFS cladding in order to prevent the spread of fire in the application of EIFS legally use is limited by the use of the building. And flame spread can be prevented, such as a vertical outer wall compartment measures are urgently needed.

A Study on the Fire Risk Comparison of Building Flooring Materials by External Heat Flux (건축용 바닥재의 외부복사열에 의한 화재위험성 비교 연구)

  • Park, Youngju;Kim, Youngtak
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.20-24
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    • 2017
  • In this study, we have performed the Cone Calorimeter test in accordance with ISO 5660-1 to check the combustion characteristics of building flooring materials. The fire risk of these materials were evaluated by construction code, KFI criteria and standards of flame retardant performance. When samples exposed to external heat flux, all samples consumed a lot of Oxygen for a long time. So heat release from sample burning continued so long. And also all samples produced so much smoke. Even though a few samples were satisfied with only peak heat release rate criteria, all 8 samples were not satisfied with criteria of peak heat release rate and total heat released together. The results of 5 min total heat released were $15.9MJ/m^2{\sim}5.9MJ/m^2$. It menas the results are more than 2~6 times higher than the criteria. The results of 10 min total heat released were $30.1MJ/m^2{\sim}100.8MJ/m^2$. It means the results are more than 3~12 times higher than the criteria. 6 of 8 samples were not satisfied with Dm.corr.(corrected maximum smoke density) criteria. The building flooring materials which we used for this test ignited very fast and the burning continued so long. It means these samples are susceptible to fire.

Study on Property Modification with Polymer Compositions in the Manufacture of Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.220-224
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    • 2019
  • Herein, three polymer compounds were manufactured using three polymer combination methods, ethylene-vinyl acetate/ethylene-propylene-diene-copolymer (EPDM), ethylene-vinyl acetate (EVA)/polyethylene-A (PE-A; density: 0.870), and ethylene-vinyl acetate (EVA)/polyethylene-B (PE-B; density: 0.885), for making cable sheath for use in the shipping industry. In this study, EVA, EPDM, PE-A, and PE-B were used as matrix polymers, and EVA-grafted maleic anhydride was used as a coupling agent for compounding with various compounds such as a fire retardant, cross-linking agent, filler, and other additives, besides the plasticizer. ${\Delta}T$, Mooney viscosity, and tensile strength increased in order of EPDM < PE-A < PE-B, the probable reason is due to the different crosslinking effect. The three compounds showed similar results for fire resistance and aging resistance after compounding process, but they showed excellent cold resistance owing to the non-polarity of the polymers and sufficient plasticizer content.

A Study on Emission Properties of Green House Gas on Duration Combustion of Constructive Wood Materials (건축용 목재의 연소시 지구온난화 가스의 배출특성에 관한 연구)

  • An, Hyung-Hwan
    • Journal of the Korean Institute of Gas
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    • v.22 no.6
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    • pp.123-128
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    • 2018
  • MDF was treated on the surface of MDF with fire retardant lacquer, water-soluble flame retardant coat and water-soluble wood cover on the MDF wood, and the pyrolysis characteristics and the atmospheric noxious gas generation characteristics were investigated by using the large capacity thermal analyzer. As a result of investigating pyrolysis and combustion gas generation characteristics after treatment of 0.11 / 11.55 g in terms of mass ratio, it was found that combustion starting time was slightly longer than that of pure MDF in the case of treatment with fire retardant lacquer. The combustion temperature was increased from $340^{\circ}C$ to $450^{\circ}C$. The pyrolysis and combustion gas generation characteristics of the MDF wood treated with the aqueous flame retardant coat showed the changes in combustion starting time and temperature from $260^{\circ}C$ to $542^{\circ}C$ for about 26 minutes at the mass ratio of 0.13 / 11g. Also, when the commercially available waterproof wood cover was treated with 0.13 / 11.55 g of MDF, the sudden weight change tended to increase from $300^{\circ}C$ to $370^{\circ}C$ and showed a second change at approximately $500^{\circ}C$.

Experimental Study of Fire Characteristics by Isocyanate Functional Parameter (이소시아네이트 관능기 매개인자에 의한 화재 특성의 실험적 연구)

  • Lee, Jae-Geol;Han, Kyoung-Ho;Jo, Hyung-Won;Yoon, Do-Young
    • Journal of the Korean Institute of Gas
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    • v.26 no.3
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    • pp.27-37
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    • 2022
  • With the recent increase in the spread of ESS (Electric Storage System), the damage to human life and property is also rapidly increasing due to continuous fires caused by ESS. In the manufacture of urethane sandwich panels used in ESS, it is necessary to improve the flame retardant performance. In this study, in order to realize the flame retardant properties of flexible polyurethane foam, the effect of the tissue density of the product due to the change of the isocyanate functional group parameter that changes the physical properties of the product on the fire performance was studied. The product was manufactured by changing the density of the urethane structure, and combustion performance tests, gas toxicity tests, and smoke density tests were performed. As a result, it was confirmed that the total amount of heat released had excellent performance when the isocyanate functional group was high, and had no correlation with the maximum heat release rate. When the value of the isocyanate functional group was 2.7 or more, the collapse of the shape could be prevented. In the gas hazard test, the performance was increased when the isocyanate functional group was relatively high, so a flame retardant for the Char system, which had a dense structure and easy to form a carbonized film, was added. confirmed to be. Therefore, as a result of this study, it is thought that it will be possible to lay the foundation for the development of a flame retardant to replace the cheap urethane sandwich panel used in the past.

A Study on the Improvement of Flame Retardancy of Polylactide for Construction Materials (건축자재용 폴리락타이드의 난연성 향상에 관한 연구)

  • Cha, Sang-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.2
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    • pp.113-119
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    • 2021
  • Polymers are widely applied to construction materials due to their lightweight and excellent mechanical properties. However, owing to the combustible properties, polymers are one of the biggest reason of spreading large fires in fire accidents that occur frequently in the construction industry. Therefore, as a solution to this problem, many research has been conducted to impart flame retardancy by incorporating flame retardants to polymer matrix. Among these flame retardants, organic phosphorus-containing flame retardants have been attracting much attention because they have excellent compatibility with polymer matrix and low toxicity compared with halogen or inorganic-containing flame retardants. Accordingly, this study aims to design and synthesize an alkoxyamine-based organic phosphorus flame retardant to improve flame retardancy of polylactide which is an eco-friendly polymer used for construction materials.

The Flame Retardant and Mechanical Properties of Wood Flour-High Density Polyethylene Composites (목분-HDPE 복합체의 난연성 및 기계적 성질)

  • Shin, Baeg-Woo;Bang, Dae-Suk;Song, Young-Ho;Chung, Kook-Sam
    • Journal of the Korean Society of Safety
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    • v.27 no.1
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    • pp.26-31
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    • 2012
  • Wood-plastic composites represents a growing class of materials used by the residential construction industry and furniture industry. In this study, the effect of flame retardants on the flammability and mechanical properties of wood flour-high density polyethylene(HDPE) composites were studied. we were manufactured wood flour-HDPE composites by modular intermeshing co-rotating twin screw extruder with L/D ratio of 42. The flame retardant properties were used limiting oxygen index(LOI) and mechanical properties were measured by universal testing machine(UTM). The Morphological analysis of composites were analyzed by Scanning electron microscope(SEM). It was found that Ammonium polyphosphate can effectively reduce the flammability of the wood flour-HDPE composites. Marginal reduction in the mechanical properties of the composites was found with addition of flame retardants. SEM images showed that the coupling agent improved wood flour-HDPE interfacial bonding.