• Title/Summary/Keyword: fire retardant materials

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Melting Characteristics of Asbestos Cement Slate on Basicity Control (염기도 조절에 의한 석면슬레이트 용융특성)

  • Yun, Jinhan;Keel, Sangin;Min, Taijin;Lee, Chungkyu;Jang, Duhun
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.159.2-159.2
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    • 2010
  • Asbestos is the collective name for a group of naturally occurring minerals in their fibrous form and hydrous silicates of magnesium and a mineral fiber that has been used commonly in a variety of building construction materials for insulation and as a fire-retardant. Asbestos has been used for a wide range of manufactured goods, because of its fiber strength and heat resistant properties. Nevertheless harmful of asbestos is quite serious. Exposure to airborne friable asbestos may result in a potential health risk because persons breathing the air may breathe in asbestos fibers. Continued exposure can increase the amount of fibers that remain in the lung. Fibers embedded in lung tissue over time may cause serious lung diseases including asbestosis, lung cancer. In this paper, we carried out as fundamental study for dispose of asbestos cement slate safely and perfectly. Melting Temperature of asbestos need to more than $1,520^{\circ}C$ and specially asbestos cement slate need more energy than that of pure asbestos. We need to decrease melting temperature of asbestos cement slate for economical efficiency. To the purpose, glass and bottom ash were chosen as additives for basicity control. we analyzed about properties of asbestos cements slate, melting characteristics on the additives ratio and temperature. We confirmed about harmlessness of melting slag through analysis of scanning electron microscope(SEM) and x-ray diffractometer(XRD).

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Housing Market and Opportunities for Wood Frame Housing in Korea (우리나라의 주택시장구조(住宅市長構造)와 목조주택개발(木造住宅開發))

  • Park, Moon-Jae;Kim, Wae-Jung;Han, Kap-Joon
    • Journal of the Korean Wood Science and Technology
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    • v.19 no.3
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    • pp.45-52
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    • 1991
  • To investigate opportunities for wood frame housing and to activate wood frame house construction, trends of construction activities. preference about housing, and building codes related to wood frame housing were discussed. And two models of wood frame house were developed and construction cost was analyzed to compare with comparative masonry houses. The results obtained were as follows: 1. While 77.8% of people prefer single-family houses, majority of people(74.9%), ironically, possess multi-family houses such as apartments Wood work cost was ratio of 4% of total building cost. while wood material cost accounted merely for 11 % out of total building material cost. 2. Building code was not major barrier to residential house at height under 13m. The building code regulated major structural member and family boder wall of multi-family house to be built with fire retardant material. 3. The proper wood frame house was analyzed of town house or villa type locating in suburban of big city with hot ondol system for the upper middle class. 4 There was no difference in construction cost between western style wood frame house and comparable masonry house, but construction cost for Korean style wood frame house is 27% higher than that of comparable masonry house. It was necessary to reduce materials and cost down by prefabrication technique for both style of wood frame house.

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Physical Properties of Cement Boards Mixed Pearlite and Expanded Graphite (펄라이트와 팽창흑연을 혼입한 시멘트 보드의 물리적 특성)

  • Lee, Ju-Won;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.65-66
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    • 2023
  • Recently, the importance of improving air quality has been greatly highlighted due to environmental problems such as indoor air pollution, and efforts are being made to improve indoor air quality not only in Korea but also around the world. In this situation, this study aims to study the physical properties of cement boards using pearlite with excellent physical adsorption performance due to micropores in materials, expanded graphite that is widely used as a flame retardant to prevent heat transfer in the event of a fire. The experimental items are bending fracture load and impact resistance. The bending destruction load at the fiber mixing rates 1, 2, 3, and 4 (%) did not meet the standard 140N, but the bending destruction load at 5% was 168.2N, and the impact resistance of the fiber mixing rates 1 and 2 (%) could not be measured due to cracks and damage, and the impact resistance at 3, 4, and 5 (%).

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Combustion-Retardation Properties of Pinus rigida Treated with Ammonium Salts (암모늄염으로 처리된 리기다 소나무의 난연성)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.627-631
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    • 2010
  • This study was performed to test the combustion-retardation properties of Pinus rigida-based materials by the treatment of ammonium salts. Pinus rigida plate was soaked by the treatment with three 20 wt% ammonium salt solutions consisting ammonium sulfate (AMSF), monoammonium phosphate (MAPP), and diammonium phosphate (DAPP), respectively, at the room temperature. After the drying specimen treated with chemicals, combustion properties were examined by the cone calorimeter (ISO 5660-1). When the ammonium salts were used as the retardant for Pinus rigida, the flame retardancy improved due to the treated ammonium salts in the virgin Pinus rigida. However the specimen shows increasing CO over virgin Pinus rigida and It is supposed that toxicities depend on extents. Also, the specimen with ammonium sulfate showed both the lower total smoke release (TSR) and lower total smoke production (TSP) than those of virgin plate. Among the specimens, the sample treated with diammonium phosphate showed a strong inhibitory effect of combustion.

Enhanced Flame Retardancy of Cotton Fabric by Functionalized Graphene Oxide and Ammonium Polyphosphate (기능성화 산화 그래핀과 폴리인산암모늄을 이용한 직물 난연성 향상)

  • Ka, Dongwon;Jang, Seongon;Jung, Hyunsook;Jin, Youngho
    • Composites Research
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    • v.33 no.4
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    • pp.177-184
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    • 2020
  • Flame retardant(FR) clothes prohibit additional fire diffusion and make the personnel do their tasks without a hitch in a flammable environment. The existing FR clothes, however, are heavy and give high thermal fatigue. Therefore, it is strongly demanded to develop a light, convenient, and eco-friendly clothes. Recently, many works have been reported to make FR fabrics with phosphorus compounds, but their performance could not satisfy the specified criteria in appraisal standards of domestic and American FR clothes or combat uniforms. In this paper, two kinds of phosphorus compounds were applied to cotton fabric. Graphene oxide functionalized with a phosphorus-rich deep eutectic solvent and ammonium polyphosphate were coated on cotton fabric by eco-friendly padding procedure. The coated fabrics were analyzed with thermogravimetric analysis, vertical flame resistance test(ASTM D6413), cone calorimeter test(ISO 5660-1), and method of test for limited flame spread(ISO 15025). It was revealed that the as-made cotton with those two materials simultaneously had better flame resistance than the cottons with each one. Furthermore, an additional coating for hydrophobicity on the FR cotton was tried for better washing fastness.

Combustion Characteristics of the Quercus variabilis and Zelkova Serrata Dried at Room Temperature (자연 건조된 굴참나무와 느티나무의 연소특성)

  • Chung, Yeong-Jin;Kwon, In-Kyu
    • Journal of Korean Society of Forest Science
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    • v.99 no.1
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    • pp.96-101
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    • 2010
  • One of the restriction of wood as building material is its combustibility. The purpose of this paper is to examine the combustion properties of the quercus variabilis and zelkova serrata which are dried at room temperature and meet the desirable characteristics for use of construction materials. The cone calorimeter (ISO 5660-1) was used to determine the heat release rate (HRR) and fire smoke index, as well as CO production and smoke obscuration. The $HRR_{mean}$ 77.94 kW/$m^2$ of the quercus variabilis at 50 kW/$m^2$ was high in comparison with $HRR_{mean}$ 13.06 kW/$m^2$ for the zelkova serrata. Furthermore, the quercus variabilis has high specific extinction area ($SEA_{mean}$), 41.11 $m^2$/kg compared with $SEA_{mean}$ 9.23 $m^2$/kg of zelkova serrata. Thease results are depend on the density of tested wood species. In addition, the quercus variabilis has high CO production rate compared with that of zelkova serrata. Also, zelkova serrata showed an increase of retardant properties attributed to char formation compared with that of quercus variabilis.

A Study on Improvement of Fire-resistant and Flame-retardant Properties of Silicone Rubber Composites Containing Perlite (펄라이트를 첨가한 실리콘 고무 복합체의 내화 및 난연 특성 향상에 관한 연구)

  • Lee, Byung-Gab;Lee, Jong-Hyeok;Bang, Dae-Suk;Won, Jong-Pil;Jang, Il-Young;Park, Woo-Young;Jhee, Kwang-Hwan
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.164-170
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    • 2011
  • In this study, silicone rubber filled with environmentally-friendly perlite was prepared by mechanical mixing in order to improve thermal properties, such as heat and fire resistances. We found that the properties of silicone rubber composites depended on perlite concentration by various characterization methods. Thermogravimetric analysis(TGA) indicated that the initial degradation temperature of silicone/perlite composite was higher than that of pristine silicone rubber. The gas torch test showed that the opposite side temperature of composite materials was remarkably low as compared to that of pristine silicone rubber. In addition, the composites containing 5 wt% and 10 wt% of perlite showed remarkable thermal stability at elevated temperatures according to the results of both fireproof furnace tests under the RABT condition and carbonization furnace tests. The images from a scanning electron microscope(SEM) showed the degree of dispersion of perlite in silicone rubber. Finally, it was confirmed that limited oxygen index(LOI) was increased with perlite concentration.

A Study on the Toxic Gases Released from Fire Retardant Finishing Materials (가스검지관법에 의한 방염시료의 연소가스 독성평가)

  • Lee, Hae Pyeong;Park, Young Ju;Lim, Suk Hwan;Kim, Jung In
    • 한국방재학회:학술대회논문집
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    • 2011.02a
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    • pp.195-195
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    • 2011
  • 본 연구는 방염성능시험에 의한 필름 및 도료처리 시료를 대상으로 화재 시 발생하는 연소가스 중의 독성에 대하여 NES 713 방법에 의해 분석하고, 독성지수를 확인함으로써 연소 시 인체에 미치는 영향을 간접적으로 확인해 보고자 하였다. 기존 방염제품 중 필름과 도료처리 그리고 도료처리 후 기간이 경과한 시료의 3가지로 실험군을 구분하였으며, NES 713 방법으로 연소가스를 분석하고 독성지수를 평가하였으며, 추가로 기존의 국내 노출기준과의 비교를 수행하였으며, 국내 NES 713 방법을 활용한 선행연구들을 참조하였다. 발암가능 추정물질인 아크릴로니트릴은 총 18개의 시료에서 검출되었으며, 포름알데히드는 9개의 시료에서 검출되었다. 염화수소와 브롬화수소는 각각 5개의 시료들에서 검출된 반면에 도료처리된 시료에서는 각각 1개만이 검출되었다. 그 외 일산화탄소와 이산화탄소 그리고 질소산화물은 모든 시료에서 공통적으로 검출되었다. 독성지수는 최소 3.5에서 최고 9.4의 값을 갖는 것으로 나타났다. 본 연구에서 수행한 NES 713 분석결과와 독성지수 산출 및 기존 국내 노출기준과의 비교를 수행해 본 결과는 다음과 같았다. 첫째, 현행 국내 기준 상 방염제품의 독성시험 등에 관한 기준이 없고, 둘째, 방염제품에 대한 연소가스 독성 등을 평가한 선행연구가 제한적이라는 점에서 의미가 있을 것으로 사료된다. 하지만 독성지수의 적용이 국내에서 이루어지고 있지 않은 현실에서 산출도나 독성지수의 위해정도를 평가하기 어렵고, 시료의 수량이 총 18개로서 많지 않았다는 점에서 전체 방염제품의 연소가스 독성의 잠재적인 위험성을 추정할 수는 있지만 대표성을 갖기에는 문제점이 있다는 한계성을 벗어날 수 없었다. 따라서 향후 후속 연구에서는 보다 많은 방염제품들을 대상으로 무작위 선정을 통한 연구 설계 및 실험 연구가 수행된다면 보다 객관적이고 대표성을 지닌 연구결과를 도출할 수 있을 것으로 기대한다.

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Effect of Flame Resistant Treatment on The Sound Absorption Capability of Sawdust-mandarin Peel Composite Particleboard (방염처리가 톱밥-귤박 혼합파티클보드의 흡음성능에 미치는 영향)

  • Kang, Chunwon;Jin, Taiquan;Kang, Ho-Yang
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.4
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    • pp.511-517
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    • 2015
  • Sound absorption capability of the flame resistant treated sawdust-mandarin peel composite particleboard was were estimated by two microphone transfer function methods. The weight of flame resistant treated board slightly increased by the treatment. The treatment improved fire retardant performance by decreasing the charred area of flame resistant treated board. Sound absorption capabilities of flame resistant treated sawdust-mandarin peel composite particleboard, in the entire estimated frequency range of 500-6,400 Hz was slightly lower than those of the control specimen. Sound absorption capability of both the control and flame resistant treated sawdust-mandarin peel composite particleboards were higher than that of commercial gypsum boards, being widely used as a sound absorber for ceiling at the estimated frequency.

Impact and Fire Retardant Properties of Flax Fiber Reinforced Nanoclay Composites by Taguchi Method (다구치 기법을 사용한 나노클레이가 첨가된 아마섬유 강화 복합재료의 충격 거동 및 연소 특성)

  • Won, Cheon;Kim, Jin-Woo;Lee, Dong-Woo;Kim, Byung-Sun;Song, Jung-Il
    • Composites Research
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    • v.26 no.3
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    • pp.189-194
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    • 2013
  • This paper deals with the study of mechanical properties and impact energy absorbed by composites, made by using thermoplastic and thermoset as matrix, flax fiber and nanoclay as reinforcements. The nanoclay was sprayed on the fiber laminate directly after mixing with ethanol. This experiment designed by Taguchi method and have variable factors, i.e three types of fiber direction(F), three different nanoclay wt%(N) and three spray gun hole shapes(S). According to these conditions, composites were made and the optimum conditions were found to be F1N3S1, F1N2S1, F1N2S1 and F3N2S1 for thermoplastic, and F1N3S2, F1N3S2, F1N2S2 and F3N2S1 for thermoset which were matched with tensile strength, modulus, total impact absorbed energy and heat release rate respectively.