• 제목/요약/키워드: finishing agent

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Development of Cationic Dyeable Polyamide Substrates by Pretreatment with Synthetic Tanning Agent: Statistical Optimization and Analysis

  • Son, Young-A;Ravikumar, K.;Bae, Jin-Seok
    • 한국염색가공학회지
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    • 제21권5호
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    • pp.41-50
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    • 2009
  • Design of experiments (DoE) concept was successfully applied to determine the optimum processing conditions that yield maximum % exhaustion for berberine interaction with synthetic tanning agent pretreated polyamide substrates. The potential of synthetic tanning agent to provide anionic sites on the polyamide for berberine interaction which is cationic in nature was tested to increase the % exhaustion of berberine in this article. Experiments were designed according to Central Composite Rotatable Design (CCRD). The three factors for synthetic tanning agent pretreatment and two factors for berberine interaction each at five different levels, including central and axial points were considered. Experiments were conducted in a laboratory scale infra-red treatment instrument according to CCRD. For each response, second order polynomial models were developed using multiple linear regression analysis incorporating linear, interactions and squared effects of all variables and then optimized. The significance of the mathematical model developed was ascertained using Excel regression (solver) analysis module. Analysis of variance (ANOVA) was performed to check the adequacy and accuracy of the fitted models. The response surfaces and contour maps showing the interaction of process variables were constructed. Applying Monte Carlo simulation, response surface and contour plots, optimum operating conditions were found and at this optimum point, % exhaustion of 81% and 74% respectively for synthetic tanning agent pretreatment and berberine interaction were observed and subsequently the results were experimentally investigated.

카플링제를 도입한 탄소섬유/나일론 6 복합재료의 기계적 성질(II) -복합재료의 계면강도 증가- (Mechanical Properties of Carbon Fiber/Nylon 6 Composite Introducing Coupling Agent (II) -Increasing Interfacial Strength of Composite-)

  • Park, Chan Hun;Lee, Yang Hun;Shin, Eun Joo
    • 한국염색가공학회지
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    • 제9권4호
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    • pp.47-53
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    • 1997
  • To improve the interfacial bonding of carbon fiber-nylon 6 composite, carbon fiber(CF) were oxidized by nitric acid treatment, and two types of graft polymer(GP) of nylon 6-g-polyacrylamide (PAAm) -water dispersable GP(WDGP) and m-cresol solu ble GP(CSGP) were treated as coupling agents. Introduction of polar groups such as -COOH, -OH, etc, on the surface of the oxidized CF was confirmed by IR spectra. The stem polymer of nylon 6 in the coupling agent (GP) could be compatible with'matrix nylon 5, and the grafted branch of PAAm on GP could react to the polar groups on the oxidized CF in composite. The interfacial strength was measured by the transverse tensile test to the fiber direction for single CF embedded nylon 6 film especially prepared and by the pull-out test method. The interfacial strength of the composite reinforced with oxidized CF is greater than that reinforced with unoxidized CF. The interfacial strength of the composite was increased by treatment of coupling agents(GPs) considerably, and the increasing tendency by the WDGP is greater than that by the CSGP. The optimum conditions of coupling agent treatment are as follows: the concentration, adsorption tlme of GP, and curing temperature are 2%, 20 minutes, and $170^{\circ}$, respectively.

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표면도포제에 따른 수복용 글라스 아이오노머 세멘트의 표면조도 비교 (A COMPARATIVE STUDY ON SURFACE ROUGHNESS OF GLASS IONOMER CEMENT BY SURFACE COATING AGENT)

  • 최병재;황동환
    • 대한소아치과학회지
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    • 제23권4호
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    • pp.915-924
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    • 1996
  • The purpose of this paper is to investigate the surface roughness of glass ionomer cement during initial setting time followed by applying surface coating agent. No other finishing or polishing procedure is done and each surface coating agents (varnish, adhesive, gloss, sealant) are used after filling of glass ionomer cement. Surface roughness indices(Ra) are measured and surface contours are obtained electronically by Surfcorder SEF-30D(Kosaka laboratory Ltd., Japan). The results are as follows: 1. During initial setting time, surface roughness increases slightly regardless of surface coating agents. But it is statistically insignificant. (p>0.05) 2. Among surface coating agents used, Ra indices of group using varnish are high significantly compared to other groups regardless of elapsed time.(p<0.05) Among the groups which has used other surface coating agents except for the varnish group, similar Ra index all over the experiment is obtained, when compared to control group (no agent). 3. If no surface treatment is performed, tri-cure glass ionomer cement (Vitremer) has higher Ra Index than light cure glass ionomer cement (Fuji II LC) (t<0.05). But there is no difference between two groups in Ra index if any kinds of agents are applied except for sealant. (t>0.05)

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자외선 경화에 의한 PET 니트직물의 편면 발수발유 가공 (Preferential face coating of knitted PET fabrics via UV curing for water- and oil-repellent finish)

  • 정용균;정영진;장진호
    • 한국염색가공학회지
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    • 제17권6호
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    • pp.27-35
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    • 2005
  • Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

양모 방축가공에 따른 물리적 성질 변화 (A Study on Physical Properties of Wool with Shrink-resist treatment and Felting)

  • 정아현;김종준
    • 패션비즈니스
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    • 제19권2호
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    • pp.23-35
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    • 2015
  • In this study, the effect of shrink-resist treatment agent on the wool finishing, specifically anti-felting of wool product was studied. We aimed at providing preliminary data leading to the diversification of high-value added fashionable wool product. Two type of wool fabrics, dense and sheer, were employed. The fabric specimens were treated with solutions of shrink-resist treatment agent with wet pick-up rate 110%, 130%, and 150%, respectively, by using a padding mangle. The solution treated fabric specimens were then dried at room temperature first, at $90^{\circ}C$ for 15 minutes in a drying oven, and finally cured at $130^{\circ}C$ for 3 minutes. Cured wool fabric specimens were then subjected to a felting process. The physical and mechanical properties, including shrinkage rate along warp/filling direction, thickness at specified measurement pressure, drape stiffness, and air-permeability, were analyzed. After felting process, the shrinkage rates of wool fabric specimens, treated with shrink-resist treatment agent, were lower than those of control wool fabric specimens. The stiffness values of wool fabric specimens measured by using Flexometer were increased.

DGEBA에 대한 폴리트리아졸술폰의 강인화 효과 연구 (Effect of Polytriazolesulfone Addition on Fracture Toughness of DGEBA Epoxy Resin)

  • 권웅;이민규;한민우;정의경
    • 한국염색가공학회지
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    • 제31권2호
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    • pp.118-126
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    • 2019
  • This study aims to investigate the effect of polytriazolesulfone(PTS) addition on fracture toughness of diglycidyl ether of bisphenol A(DGEBA) and 4,4'-diaminodiphenylsulfone(DDS). Various amounts of PTS were added to DGEBA/4,4'-DDS in diazide and dialkyne monomer forms and polymerized during the epoxy curing process. Fracture toughness(K1C), tensile properties and thermal stability of the PTS added epoxy resin were evaluated and compared with those of PES, the conventional high Tg toughening agent, added epoxy resin. Fracture toughness of the PTS added epoxy resin was dramatically improved up to 133%, as the amount of PTS added increased, whereas that of the PES added epoxy resin was improved by only 67%. The tensile strength of PTS added DGEBA/4,4'-DDS was similar to the epoxy resin without PTS and tensile modulus was improved by 20%. And thermal stability of the PTS added epoxy resin was improved up to 14%. Therefore, PTS addition to DGEBA/4,4'-DDS, as a toughening agent, is very effective way to improve its fracture toughness without any lowering in other properties.

구아니딘화 폴리에틸렌이민이 처리된 폴리프로필렌 부직포의 군사용 화학 작용제 제독 특성 (Detoxification Properties of Guanidinylated Polyethyleneimine Treated Polypropylene Non-woven Fabric Against Chemical Warfare Agents)

  • 김지윤;권웅;김창규;정의경
    • 한국염색가공학회지
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    • 제33권1호
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    • pp.1-9
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    • 2021
  • This study aims to prepare the fabric with detoxification properties against chemical warfare agent by the simple treatment. For this purpose, polypropylene non-woven fabric(PP) was treated with polyethyleneimine(PEI) and guanidinylated PEI and detoxification properties of the guanidinylated PEI treated PP were evaluated using diisopropylfluorophosphate(DFP), as a chemical warfare agent simulant, and compared with the untreated and PEI treated PP. The half-lives of DFP on guanidinylated PEI treated PP and untreated PP were 334 min and 714 min, respectively. The half-life of DFP with guanidinylated PEI treated PP was 53.22% shorter than with untreated PP. This result shows that guanidine group in guanidinylated PEI treated PP was acted as a base catalyst for hydrolysis of DFP and decreased half-life of DFP. Therefore, it is expected that guanidinylated PEI treatment can be an simple pathway to prepare the detoxification fabric material for protective clothing against chemical warfare agents.

Human Tutoring vs. Teachable Agent Tutoring: The Effectiveness of "Learning by Teaching" in TA Program on Cognition and Motivation

  • Lim, Ka-Ram;So, Yeon-Hee;Han, Cheon-Woo;Hwang, Su-Young;Ryu, Ki-Gon;Shin, Mo-Ran;Kim, Sung-Il
    • 한국HCI학회:학술대회논문집
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    • 한국HCI학회 2006년도 학술대회 1부
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    • pp.945-953
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    • 2006
  • The researchers in the field of cognitive science and learning science suggest that the teaching activity induces the elaborative and meaningful learning. Actually, lots of research findings have shown the beneficial effect of learning by teaching such as peer tutoring. But peer tutoring has some limitations in the practical learning context. To overcome some limitations, the new concept of "learning by teaching" through the agent called Teachable Agent. The teachable agent is a modified version of traditional intelligent tutoring system that assigns a role of tutor to teach the agent. The teachable agent monitors individual difference and provides a student with a chance for deep learning and motivation to learn by allowing them to play an active role in the process of learning. That is, The teaching activity induces the elaborative and meaningful learning. This study compared the effects of our teachable agent, KORI, and peer tutoring on the cognition and motivation. The field experiment was conducted to examine whether learning by teaching the teachable agent would be more effective than peer tutoring and reading condition. In the experiment, all participants took 30 minutes lesson on rock and rock cycle together to acquire the base knowledge in the domain. After the lesson, participants were randomly assigned to one of the three experimental conditions; reading condition, peer tutoring condition, and teachable agent condition. Next, participants of each condition moved into separated place and performed their own learning activity. After finishing all of the learning activities in each condition, all participants were instructed to rate the interestingness using a 5-point scale on their own learning activity and leaning material, and were given the comprehension test. The results indicated that the teachable agent condition and the peer tutoring condition showed more interests in the learning than the reading condition. It is suggested that teachable agent has more advantages in overcoming the several practical limitations of peer tutoring such as restrictions in time and place, tutor's cognitive burden, unnecessary interaction during peer tutoring. The applicability and prospects of the teachable agent as an efficient substitute for peer tutoring and traditional intelligent tutoring system were also discussed.

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대나무숯 액상코팅제의 제조 및 특성 (Formulation of Liquid Coating Agent using Bamboo Charcoal and its Characteristics)

  • 박상범;이희영;이상민;박종영
    • Journal of the Korean Wood Science and Technology
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    • 제36권6호
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    • pp.113-120
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    • 2008
  • 본 연구는 포름알데히드와 같은 유해화학물질을 저감하고, 인체에 무해한 친환경 건축마감재를 개발하기 위하여 대나무숯분말, 편백추출수 및 바인더를 원료로 이용하여 실내 건축마감재용 액상코팅제를 제조하였다. 편백추출수의 함유량에 따른 액상코팅제의 유해화학물질에 대한 탈취율, 원적외선방사율, 음이온방출량, 항균성 및 실제 소요량을 조사하였다. 액상코팅제의 포름알데히드 탈취율은 60.0~98.6%, 암모니아 탈취율은 76.7~86.2%였다. 편백추출수의 혼합량이 증가함에 따라 탈취율도 증가하는 경향을 보였다. 액상코팅제의 원적외선방사율은 91.7%, 음이온 방출량은 77개/cc 였으며, 세균감소율은 99.4%로 항균력이 우수하였으나, 편백추출수의 혼합량 증가에 따른 이들 값에는 차이가 인정되지 않았다. 액상코팅제의 소요량은 스프레이건을 사용할 경우 $0.66kg/m^2$, 붓칠의 경우 $0.94kg/m^2$로 스프레이건을 이용할 경우가 더 효율적이었다.

모바일 아이피에서 개선된 캐싱 에이전트와 CoA 풀을 사용한 빠른 핸드오프 기법 (Fast Handoff Technique using Improved Cashing Agent and CoA Pool in Mobile IP)

  • 이장수;김성천
    • 대한전자공학회논문지TC
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    • 제45권2호
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    • pp.75-82
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    • 2008
  • 모바일 아이피는 무선 모바일 노드의 이동성에 따른 기존 아이피 주소 체계의 고유성 보장 문제를 해결하고자 제안되었다. 네트워크 레이어에서의 핸드오프는 모바일 광고 메시지를 수신하게 됨으로써 완료되는데, 메시지 광고 주기는 지연 시간과 밀접한 관련을 가지게 된다. 일반적으로 평균 500ms의 큰 지연시간을 발생시키게 되며 인터넷 전화나 멀티미디어 스트리밍 서비스와 같은 경우에 치명적인 문제로 작용할 수 있다. 기존의 기법에서는 최근의 모바일 광고 메시지를 저장하고 있는 캐싱 에이전트의 리플레잉 정책에 의하여 핸드오프 지연 시간을 감소시켰지만, 모바일 아이피 등록 과정 동안의 패킷 손실과 지연 시간 증가의 문제점을 가지고 있다. 본 논문에서는 위와 같은 문제를 해결하고자 캐싱 에이전트를 개선해 핸드오프 완료 전에 데이터 포워딩이 가능하도록 하였고, 또한 빠른 모바일 아이피 등록을 위해 CoA풀을 도입하여 핸드오프 지연 효과를 감소하는 기법을 제안하였다.