• Title/Summary/Keyword: fine dispersion

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Effects of Oxygen Plasma-treated Graphene Oxide on Mechanical Properties of PMMA/Aluminum Hydroxide Composites (산소 플라즈마 처리된 그래핀 산화물이 PMMA/수산화알루미늄 컴포지트의 기계적 물성에 미치는 영향)

  • Kim, Hyo-Chul;Jeon, Son-Yeo;Kim, Hyung-Il;Choi, Ho-Suk;Hong, Min-Hyuk;Choi, Ki-Seop
    • Polymer(Korea)
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    • v.35 no.6
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    • pp.565-573
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    • 2011
  • The nanocomposites containing graphene oxide (GO) were prepared in order to improve the mechanical properties of poly(methyl methacrylate)/aluminum hydroxide (PMMA/AH) composites. GO was prepared from graphite by oxidation of Hummers method followed by exfoliation with thermal treatment. The surface of GO was modified by oxygen plasma in various exposure times from 0 to 70 min to improve interfacial compatibility. Compared with PMMA/AH composites, the nanocomposites containing GO modified with oxygen plasma for the exposure time up to 50 min showed significant increases in flexural strength, flexural modulus, Rockwell hardness, Barcol hardness, and Izod impact strength. The morphology of fracture surface showed an improved interfacial adhesion between PMMA/AH composites and GO, which was properly treated with oxygen plasma. The mechanical properties of nanocomposites were deteriorated by increasing the content of GO above 0.07 phr due to the nonuniform dispersion of GO.

Process Study on Alumina-zirconia Nanocomposite via Ammonolysis Route

  • Naoya Enomoto;Tang, Jun-Mu;Masato Uehara;Hideaki Maeda;Junichi Hojo;Nakagawa, Zenbe-e
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 2000.06a
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    • pp.143-150
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    • 2000
  • Wet-chemical process using ammonia to precipitate aluminum ion dissolved in a zirconia sol solution is examined. Formation of crystalline bayerite is unfavorable for fine dispersion of zirconia nanoparticles in alumina matrix after heat treatment. To avoid the bayerite formation, it was preferred to make a precipitation with a diluted ammonia or with an ammonia gas flow at high temperature. By optimizing the precipitation process and the calcination temperature, we successfully prepared the uniform microstructure in which tetragonal zirconia particles of ∼30nm is finely dispersed within the alumina grains.

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Effect of Manufacturing Process Conditions on Characteristics of Metal Particle Tape (초미립 Metal Tape의 제특성에 미치는 제조공정의 영향)

  • 김주호;김기호
    • Journal of the Korean Magnetics Society
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    • v.6 no.1
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    • pp.21-27
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    • 1996
  • The effects of various manufacturing conditions on the characteristics of metal particle tape using ultra-fine metal powder were investigated. As functions of kneading conditions and milling solid contents. coating thickness, orientation, calender and curing conditions. various properties of the tapes were studied. By the consideration of physical and eletromagnetic properties of the tapes, optimum process conditions were determined. As a result of above investigations, we concluded that manufacturing processes were very important factor in addition to dispersion behavior of particles for achieving maximum properties of the metal particle tape.

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The Synthesis of High-purity Zirconia Powders and Its Properties (Compaction and Sintering Behaviro as a Function of Granulation Methods) (고순도 지르코니아 분말의 합성 및 그 특성 (조립방법에 따른 성형 및 소결 특성))

  • Kim, Hwan;Lee, Jong-Kook;Kim, Ju-Young;Hwang, Kyu-Hong
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.357-363
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    • 1988
  • Ccompaction and sintering behavior of highly pure PSZ powders were investigated by laying the stress on the granulation processes. The particle size of coprecipitated PSZ powder was so fine that the agglomeration was severely formed during drying and calcing step and by this agglomeration differential sinering was occurred. The methanol dispersion of precipitates was the good method of avoiding severe agglomeration formed during drying process because of small surface tension than water. But perfect deagglomeraton was not possible due to high surface area of powders. So homogenization by granulation was needed, and among the method spray granulation was the most desirable to obtain homogeneous compacts and subsequent flaw-free ceramics.

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A Development on the Non-Photomask Plate Making Technology for Screen Printing (포토 마스크가 필요없는 스크린 제판 기술 개발)

  • Koo, Yong-Hwan;Ahn, Suk-Chul;Kim, Sung-Bin;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.65-75
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    • 2010
  • Environmentally friendly, stencil and screen printing for cost-effective for maskless. In this study, UV -LED light source for the dispersion characteristics and high competence photoresist coating was prepared. Wavelength of 365nm UV-LED exposure device using the maskless lithography, 1.7kgf/$cm^2$ $2600mmH_2O$ the injection pressure and the suction pressure by using a dry photoconductor symptoms were dry emulsion on the market as a result, curing properties and adhesion, hardness, solvent resistance and excellent reproduction of fine patterns and ecological stencil technology was available and could be confirmed as a possibility.

Fabrication of Zirconium Phosphate Nanoparticles through Solution Technique (수용액법에 의한 인산 지르코늄 나노입자의 합성)

  • 정영근;최현규
    • Journal of Powder Materials
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    • v.9 no.5
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    • pp.336-340
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    • 2002
  • The $\alpha$-zirconium phosphate particles as fine as 20 nm were fabricated through solution technique using $ZrOCl_2{\cdot}8H_2O$ and $H_3PO_4$ as precursors. Stability of $\alpha$-Zirconium phosphate could be ensured by adding excess phosphoric acid to a stoichiometric composition Instead of using reflux route that resulted in coarsening of particles due to an inevitably long aging. The excess phosphorous incorporated in the crystal could be successfully eliminated afterwards through careful washing. Moreover, heavily agglomerated particles are observed before washing, but fairly dispersed state is found out after washing treatment. Thus, it is found that dispersed state as well as phase stability is ensured through proper washing treatment.

Hyper Functionalized Nanoparticle Technology and their Applications

  • Lee, Sun-Jong;Jung, Yeon-Jae;Lee, Jung-Min;Lee, Jun-Young;Kim, Jung-Hyun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.83-84
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    • 2006
  • In aqueous phase, we directly prepared conducting and photoluminescent nano-structured particles by oxidation polymerization. Thiophene(PT) was initiated by $FeCl_{3}/H_{2}O_{2}$ (catalyst/oxidant) combination system. And, polydispersed core-shell poly(styrene/thiophene) and polyaniline(PANI)-coated multi core-shell polystyrene latex particles were successfully prepared by oxidative and radical polymerization. The resulting latex particles have fine improved luminescence and conductive efficiency and dispersion state due to the PT and PANI shell. Hyper functionalized nanoparticle would be expected to increase the processibility in various electrical and electro-optical fields.

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Analysis of Debis Flow according to Change of Slope Angle (사면경사 변화에 따른 토석류의 거동 분석)

  • Park, Byung-Soo;Jun, Sang-Hyun;Yoo, Nam-Jae;Han, Kwang-Doo;Yoon, Young-Ho
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.1294-1301
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    • 2010
  • This study is an experimental research for the dispersion behavior and impact characteristics of debris flow according to change of slope. Large scale experimental setup for the debris flow was established to simulate the artificial rainfall and control the ground slope. Parameters such as materials of debris flow, slope, and length of slope were used for the experiments. After the experiments, it was found that the speed of ground material components was increased about 28~47%. It was found that speed can be increased by increasing the particle size. Furthermore, maximum/final loads for ground material components were increased 89% for the coarse aggregate and 68% for the fine aggregate comparing with sand.

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A Study on the Structure and Strength of Rapidly Solidified HSLA Steels (급냉응고한 HSLA강의 조직과 강도에 의한 연구)

  • Nam, Tea-Woon
    • Journal of Korea Foundry Society
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    • v.10 no.2
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    • pp.162-170
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    • 1990
  • The major effects of RSP sre 1) extension of solid solubilities, 2) formation of metastable phaeses, 3) microstructural refinement 4) segregationless. The main trust of this study was to investigate the effects of superimposing RSP on the structure and properties of HSLA steels. Powder was made by NGA (Nitrogen Gas Atomization) process, and consolidated by HIP. The high grain-coarsening resistance of NGA-HIP steels was attributed to a fine dispersion of oxide precipitates. The average grain size for the NGA-HIP steels was somewhat finer than that for the conventional HSLA steels, The impact properteis of NGA-HIP steels were improved over those of the conventional HSLA steels.

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Precipitation Behavior of α-Cr Particle in B2-type Intermetallic Compounds β-NiAl (B2형 금속간화합물 β-NiAl중에 α-Cr입자의 석출거동)

  • Han, Chang-Suck;Kim, Youn-Che
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.91-102
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    • 1996
  • Microstructural control to produce multiphase structure has received much attention to improve the high temperature strength as well as low temperature ductility of intermetallics. Transmission electron microscopic investigation has been carried out concerning the effect of Cr-precipitation on the mechanical properties of B2-ordered NiAl containing 4 to 8 mol% of Cr. By aging at temperatures around 973 K after solution annealing, fine spherical precipitates took place homogeneously in the NiAl matrix and the alloys hardened appreciably. Selected area electron diffraction (SAED) patterns have not revealed any additional extra-spots during aging, because the Cr-particles show cube-cube orientation relationship and keep a perfect coherency with the ordered matrix lattice. Dislocations were confirmed to bypass the particles during deformation. Although the dispersion of Cr-particles increased the yield strength of NiAl at intermediate temperature, the strength decreased appreciably at higher temperatures.

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