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Effects of Oxygen Plasma-treated Graphene Oxide on Mechanical Properties of PMMA/Aluminum Hydroxide Composites  

Kim, Hyo-Chul (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Jeon, Son-Yeo (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Kim, Hyung-Il (Department of Fine Chemical Engineering Applied Chemistry, Chungnam National University)
Choi, Ho-Suk (Department of Chemical Engineering, Chungnam National University)
Hong, Min-Hyuk (Lion Chemtech Co., Ltd.)
Choi, Ki-Seop (Lion Chemtech Co., Ltd.)
Publication Information
Polymer(Korea) / v.35, no.6, 2011 , pp. 565-573 More about this Journal
Abstract
The nanocomposites containing graphene oxide (GO) were prepared in order to improve the mechanical properties of poly(methyl methacrylate)/aluminum hydroxide (PMMA/AH) composites. GO was prepared from graphite by oxidation of Hummers method followed by exfoliation with thermal treatment. The surface of GO was modified by oxygen plasma in various exposure times from 0 to 70 min to improve interfacial compatibility. Compared with PMMA/AH composites, the nanocomposites containing GO modified with oxygen plasma for the exposure time up to 50 min showed significant increases in flexural strength, flexural modulus, Rockwell hardness, Barcol hardness, and Izod impact strength. The morphology of fracture surface showed an improved interfacial adhesion between PMMA/AH composites and GO, which was properly treated with oxygen plasma. The mechanical properties of nanocomposites were deteriorated by increasing the content of GO above 0.07 phr due to the nonuniform dispersion of GO.
Keywords
PMMA; graphene oxide; aluminum hydroxide; oxygen plasma; mechanical properties;
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