• Title/Summary/Keyword: filler size effect

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Water Absorption of Wood Flour-Polypropylene Composites: Effects of Wood Species, Filler Particle Size and Coupling Agent (목분-폴리프로필렌 복합재의 수분흡수율 : 목재수종, 충진제 입자크기 및 상용화제의 영향)

  • Kang, In-Aeh;Lee, Sun-Youn;Doh, Geum-Hyun;Chun, Sang-Jin;Yoon, Seung-Lak
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.4
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    • pp.298-305
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    • 2010
  • The effects of wood species, chemical components, filler loading level, filler particle size, and coupling agent on the water absorption property of the wood flour filled polypropylene (PP) composites were investigated in this study. After 500, 1,000, 1,500, 2,000, 2,500 and 3,000 hr water immersion, Quercus (Quercus accutisima Carr.) and Maackia (Maackia amuresis Rupr. et Maxim) showed significantly lower water absorption properties compared to Larix (Larix kaempferi Lamb.). As wood flour loading increases from 10 to 50 wt%, most wood species showed increased water absorption after a given immersion period. Particle size of wood flour proved to have very significant effects on water absorption of the composites. The effect of coupling agent was positive in terms of lowering water absorption of the composites. As the treatment level of coupling agent increases, the water absorption of the composites decreases. The lowest water absorption was obtained at the lower wood flour loading (Maackia), smaller particle size and by the addition of coupling agent. Thickness swelling of the composites shows close dependency on water absorption.

Rubber Composites with Piezoresistive Effects (고무 복합재료의 압저항 효과)

  • Jung, Joonhoo;Yun, Ju Ho;Kim, Il;Shim, Sang Eun
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.76-84
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    • 2013
  • The term 'Piezoresistive effect' describes a change in the electrical resistance of the material from deformed to its original shape by the external pressure, e.g., elongation, compression, etc. This phenomenon has various applications of sensors for monitoring pressure, vibration, and acceleration. Although there are many materials which have the piezoresistive effect, rubber (nano)composites with conductive fillers have attracted a great deal of attention because the piezoresistive effect appears at the various range of pressure by controlling the type of filler, particle size, particle shape, aspect ratio of particles, and filler content. Especially one can obtain the composites with elasticity and flexibility by using the rubber as a matrix. This paper aims to review the piezoresistive effect itself, their basic principles, and the various conductive rubber-composites with piezoresistive effect.

Effect of Ball Milling on Photosensitive Carbon Nanotube Pastes and Their Field Emission Properties (감광성 CNT paste에 대한 저에너지 Ball Milling 처리 효과)

  • Jang, Eun-Soo;Lee, Han-Sung;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.154-154
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    • 2008
  • Although the screen printing technology using photosensitive carbon nanotube (CNT) paste has many advantages such as low cost, simple process, uniform emission, and capability of mass production, the CNT paste needs to be improved further in CNT dispersion, printability, adhesion, electrical conductivity, population of CNT emitters, etc. Ball milling has been frequently employed to prepare the CNT paste as ball milling can mix its ingredients very well and easily cut the long, entangled CNTs. This study carried out a parametric approach to fabricating the CNT paste in terms of low-energy ball milling and a paste composition. Field emission properties of the CNT paste was characterized with CNT dispersion and electrical conductivity which were measured by a UV-Vis spectrophotometer and a 4-point probe method, respectively. Main variables in formulating the CNT paste include a length of milling time, and amounts of CNTs and conductive inorganic fillers. In particular, we varied not only the contents of conductive fillers but also used two different sizes of filler particles of ${\mu}m$ and nm ranges. Among many variations of conductive fillers, the best field emission characteristics occurred at the 5 wt% fillers with the mixing ratio of 3:1 for ${\mu}m$-and nm-sizes. The amount and size of fillers has a great effect on the morphology, processing stability, and field emission characteristics of CNT emitter dots. The addition a small amount of nm-size fillers considerably improved the field emission characteristics of the photosensitive CNT paste.

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Effect of cement as mineral filler on the performance development of emulsified asphalt concrete

  • Liu, Baoju;Wu, Xiang;Shi, Jinyan;Wu, Xiaolong;Jiang, Junyi;Qin, Jiali
    • Advances in concrete construction
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    • v.10 no.6
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    • pp.515-526
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    • 2020
  • Cold-mixed asphalt mixture is a widely recommended asphalt pavement materials with potentially economic and environmental benefits. Due to the reduction of natural non-renewable mineral resources, powder minerals with similar properties are considered as new mineral fillers in asphalt mixtures. This study explored the feasibility of using cement to replace natural limestone powder (LP) in emulsified asphalt concrete modified by styrene-butadiene styrene copolymer. The experimental tests, including compressive strength, Marshall stability as well as moisture susceptibility test, were used to investigate the mechanical properties, the Marshall stability, flow value, as well as the moisture damage. In addition, the influence of material composition on the performance of asphalt concrete is explained by the microstructure evolution of the pore structure, the interface transition zone (ITZ), and the micromorphology. Due to mineralogical reactivity of cement, its replacement part of LP improved the mechanical properties, Marshall stability, but it will reduce the moisture susceptibility and flow value. This is because with the increase of the cement substitution rate, the pore structure of the asphalt concrete is refined, the width of ITZ becomes smaller, and the microstructure is more compact. In addition, asphalt concrete with a larger nominal particle size (AC-16) has relatively better performance.

Electrostatic Electrification Properties due to Square of Silicone Rubber (실리콘 고무의 면적 변화에 따른 정전기 대전 특성)

  • Lee, Sung-Ill
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.9
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    • pp.732-737
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    • 2012
  • This study made a specimen (contact surface size: $45\;mm{\times}0.02\;mm{\times}45{\sim}55\;mm$) with silicon rubber for low voltage cable with 50 phr silica filler. The electrification voltage of electrostatics were measured for different sizes of contact surface with the applied voltage of 10kV and the environmental settings of temperature ($25{\sim}40^{\circ}C$) and humidity (40~80%). The following conclusions were made. The electrification voltage of electrostatics decreased as the humidity increased. The electrification voltage of electrostatics increased as the temperature increased. The larger the surface size, the higher the electrification voltage of electrostatics. The property of the material had more effect on the relaxation time than the humidity.

Effect of steel fibres and nano silica on fracture properties of medium strength concrete

  • Murthy, A. Ramachandra;Ganesh, P.
    • Advances in concrete construction
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    • v.7 no.3
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    • pp.143-150
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    • 2019
  • This study presents the fracture properties of nano modified medium strength concrete (MSC). The nano particle used in this study is nano silica which replaces cement about 1 and 2% by weight, and the micro steel fibers are added about 0.4% volume of concrete. In addition to fracture properties, mechanical properties, namely, compressive strength, split tensile strength, and flexural strength of nano modified MSC are studied. To ensure the durability of the MSC, durability studies such as rapid chloride penetration test, sorptivity test, and water absorption test have been carried out for the nano modified MSC. From the study, it is observed that significant performance improvement in nano modified MSC in terms of strength and durability which could be attributed due to the addition pozzolanic reaction and the filler effect of nano silica. The incorporation of nano silica increases the fracture energy about 30% for mix without nano silica. Also, size independent fracture energy is arrived using two popular methods, namely, RILEM work of fracture method with $P-{\delta}$ tail correction and boundary effect method. Both the methods resulted in nearly the same size-independent $G_F$ irrespective of the notch to depth ratio of the same specimen. This shows evidence that either of the two procedures could be used in practice for analysis of cracked concrete structures.

Fundamental Study on Developing Lignocellulosic Fillers for Papermaking(II) - Effect of lignocellulosic fillers on paper properties - (목질계 제지용 충전제 개발을 위한 기초연구(II) - 목질계 충전제가 종이 물성에 미치는 영향 연구 -)

  • Kim, Chul-Hwan;Lee, Ji-Young;Lee, Young-Rok;Chung, Ho-Kyung;Back, Kyung-Kil;Lee, Hui-Jin;Gwak, Hye-Joeng;Gang, Ha-Ryun;Kim, Sung-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.1-6
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    • 2009
  • The purpose of this study was to investigate effects of lignocellulosic fillers made of wood powder and inorganic fillers, such as GCC and PCC, on physical properties of papers. Mechanical treatment and chemical treatment were carried out subsequently for generating lignocellulosic fillers, and then inorganic filler and wood powder were mixed together, and then mechanically treated for making lignocellulosic fillers covered with inorganic fillers. Consequently the particle size of lignocellulosic fillers was higher than that of inorganic fillers, which led to lumen loading and simultaneously surface coverage of fine inorganic fillers. Lignocellulosic fillers contributed to the increase of both bulk and opacity of handsheets dramatically, but some of properties including tensile strength, brightness and roughness decreased compared to inorganic fillers.

Extraction of Micro Filler from Bio-waste Material (Bio waste 소재로부터의 마이크로 필러 추출)

  • Nam, Gibeop;Song, Jung-Il
    • Composites Research
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    • v.31 no.5
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    • pp.209-214
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    • 2018
  • This paper explain about the development of environmental friendly, low cost and stable supply material i.e., rice husk and shell were used as micro incorporating bio waste filler. Those were processed by ball mill and analyzed through micro observation by FE-SEM, EDS and particle size distribution. The obtained filler was mixed with epoxy resin for the manufacturing of CFRP composite and study tensile properties. In EDS analysis main contents of rice husk and rice husk ash are C, O and Si. When rice husk was burned C and Si ration were increased. Shell powder has C, O and Ca. It caused $CaCO_3$ from shell. Surface weighted mean of rice husk powder is $6.19{\mu}m$ and volume weighted mean is $14.77{\mu}m$. And it has rod type particles which caused hair and husk structure parts. Surface weighted mean of rice husk ash powder is $1.55{\mu}m$ and volume weighted means is $8.20{\mu}m$. Surface weighted mean of shell powder is $2.53{\mu}m$ and volume weighted mean is $5.79{\mu}m$. The tensile decreased with increasing the content of micro filler in CFRP composites. In case of rice husk, the significant decrement of tensile strength was observed. and in case of shell powder, there is no effect of changes take place in tensile strength.

Effect of pH of Aluminum Hydroxides Gel Obtained by Hydrolysis of Al2(SO4)3 Solution on Crystal Growth of α−Al2O3 (Al2(SO4)3 용액의 가수분해에 의해 얻어진 Aluminum Hydroxides Gel의 pH가 판상 α−Al2O3의 결정성장에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Han, Myung-Wan
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.562-567
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    • 2007
  • To precipitate the complex gels of the pH 6, 7, 8, 9 included in a flux and an aluminum hydroxides gel, an aqueous solution of a mixture of $Na_2CO_3\;and\;Na_2PO_4{\cdot}12H_2O$ was added with stirring in an aqueous solution of a mixture of $Al_2(SO_4){_3}{\cdot}18H_2O,\;Na_2SO_4\;and\;K_2SO_4$, and then the complex gels were aged in 20 h at $90^{\circ}C$. As the hydrolysis pH changed, it had an effect on the physical properties such as the crystal structure, crystal morphology and a phase transition temperature of the AlO(OH) gel, and also on the crystal structure, crystal morphology, particle size and particle size distribution of the ${\alpha}-Al_2O_3$ platelets prepared by molten-salt precipitation. Also, in this study, the complex gels were crystallized at $1,200^{\circ}C$ and thereafter dried at $110^{\circ}C$, and then it was investigated to effect of the hydrolysis pH on the crystal structure, morphology and particle size distribution of the ${\alpha}-Al_2O_3$ platelets crystals using XRD, DTA, SEM and particle size analyzer.

Wear Behavior of Silica filled Styrene-Butadiene Rubber: A Comparative Study Between the Blade-Type and Akron-Type Abrader

  • Gi-Bbeum Lee;Dongwon Kim;Seowon Lee;Seonhong Kim;Myung-Su Ahn;Bismark Mensah;Changwoon Nah
    • Elastomers and Composites
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    • v.58 no.4
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    • pp.179-190
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    • 2023
  • The effect of the particle size and silica structure on the wear behavior of Silica/Styrene-Butadiene Rubber (SBR) compounds was investigated using a blade-type abrader and the findings were compared with those obtained with an Akron abrader. The compensated characteristic parameter (Ψc), which was the contributory factor of the combined effect of the particle size and filler structure, was introduced. This parameter was found to exhibit a linear relationship with the Young's modulus. The Young's modulus correlated more with Ψc than the uncompensated characteristic parameter (Ψ) modeled for carbon black. The wear rate and volume loss measured using a blade-type abrader and Akron abrader were respectively observed to be inversely proportional to Ψc, that is, the wear resistance of Silica/SBR compound improved as the particle size became smaller and the silica structure became intricate. The coefficient of determination (R2) obtained from the linear relationship between Ψc and wear rate was higher than those between Ψc and volume loss for the Silica/SBR compound. Thus, the blade-type abrader exhibited high potential to be used for accurately evaluating the effect of particle size and structural properties of silica on the wear behavior of SBR compounds.