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The Effect of Mg Precursors on Optical and Structural Characteristics of Sol-Gel Processed Mg0.3Zn0.7O Thin Films (졸-겔법으로 성장시킨 Mg0.3Zn0.7O 박막의 Mg 전구체의 종류에 따른 광학적·구조적 특성에 관한 연구)

  • Yeom, Ahram;Kim, Hong Seung;Jang, Nak Won;Yun, Young;Ahn, Hyung Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.214-218
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    • 2020
  • In this study, MgxZn1-xO thin films, which can be applied not only to active layers of light-emitting devices (LEDs), such as UV-LEDs, but also to solar cells, high mobility field-effect transistors, and power semiconductor devices, are fabricated using the sol-gel method. ZnO and Mg0.3Zn0.7O solution synthesized by the sol-gel method and the thin film were grown by spin coating on a Si (100) substrate and sapphire substrate. The solutions are synthesized by dissolving precursor materials in 2-methoxyethanol (2-ME) solvent, and then monoethanolamine (MEA) was added to the mixed solution as a sol stabilizer. Zinc acetate dihydrate is used as a ZnO precursor, while Mg nitrate hexahydrate and Mg acetate tetrahydrate are used as an MgO precursor. Then, the optical and structural characteristics of the fabricated thin films are compared. The molar concentration of the Zn precursor in the solvent is fixed at 0.3 M, and the amount of the Mg precursor is 30% of Mg2+/Zn2+. The optical characteristics are measured using an UV-vis spectrophotometer, and the transmittance of each wavelength is measured. Structural characteristics are measured using X-ray diffraction (XRD) and transmission electron microscopy (TEM). Composition analyses are performed using energy dispersive X-ray spectroscopy (EDS). The Mg0.3Zn0.7O thin film was well formed at the ratio of the Mg precursor added regardless of the type of Mg precursor, and the c-axis of the thin film was decreased, while the band gap was increased to 3.56 eV.

Recrystallization TEP Behavior of Zr-based alloy by addition of Nb and Sn (Nb과 Sn 첨가에 따른 Zr 합금의 재결정 및 TEP 거동)

  • Jeong, Heung-Sik;O, Yeong-Min;Jeong, Yong-Hwan;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.11 no.2
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    • pp.104-114
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    • 2001
  • To investigate the effects of the addition of Nb and Sn on the recrystallization of Zr- Sn-Nb alloys, both Vickers micro-hardness test and TEP measurement were carried out on cold-worked specimens annealed at various temperatures from $300^{\circ}C$ to 75$0^{\circ}C$. The microstructures of heat treated specimens were analyzed by optical microscope, SEM, and TEM. The study of microhardness and microstructures showed that both recrystallization process and grain growth were retarded as the activation energy was increased by the addition of Nb and Sn. Especially, the addition of Sn was more effective on retarding recrystallization. Precipitates were formed more easily when Nb was added because the solubility of Nb into Zr is lower than that of Sn. However, the recrystallization process was affected more by Sn than Nb because the strain field formed by substitutional Sn repressed the dislocation movement. TEP was increased due to the decrease of electron scattering as recovery and recrystallization were proceeded and saturated when the recrystallization completed. However, when precipitates formed, TEP was increased because the decrease of solute concentration near the precipitates caused the decrease of electron scattering.

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The Present Status and Development Plan in the Field of Climate Change Science in Korea analyzed by the IPCC-IV Reports (IPCC-IV 국가 보고서 분석에 의한 한국의 기후변화과학 분야의 현황과 발전방향)

  • Chung, Yun-Ang;Chung, Hyo-Sang;Ryu, Chan-Su
    • Journal of Integrative Natural Science
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    • v.4 no.1
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    • pp.38-43
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    • 2011
  • The recent global warming may be estimated to give lots of impacts to the human society and biosphere of influencing climate change included by the natural climate variations through the human activity which can directly and/or indirectly play a major role of total atmospheric composition overall. Therefore it currently appears evidences such as hot wave, typhoon, and biosphere disturbance, etc. over the several regions to be influenced by global warming due to increasing the concentration of greenhouse gases in the atmosphere through inducing forest destruction, fossil fuel combustion, greenhouse gases emission, etc. since industrial revolution era. Through the working group report of IPCC (Intergovernmental Panel on Climate Change) for climate change was analyzed by the individual country's current status and figure out the important issues and problems related to the future trend of climate change science with advanced countries preparedness and research, In this study, the first working group report of IPCC focuses on those aspects of the current understanding of the physical science of climate change that are judged to be most relevant to policymakers. As this report was assessed and analyzed by including the progress of climate change science, the role of climate models and evolution in the treatment of uncertainties. This consists of the changes in atmospheric constituents(both aerosols and gases) that affect the radiative energy balance in the atmosphere and determine the Earth's climate, considering the interaction between biogeochemical cycles that affect atmospheric constituents and climate change, including aerosol/cloud interactions, the extensive range of observations snow available for the atmosphere and surface, for snow, ice, and frozen ground and for the oceans, respectively and changes in sea level, the paleoclimate perspective and assessment of evidence for past climate change and the extension, the ways in which physical processes are simulated in climate models and the evaluation of models against observed climate, the development plans and methods of improving expert and building manpower urgently and R&D fund expansion in detail for climate change science in Korea will be proposed.

Feasibility Study of Phosphor Particle Blended Hybrid Dosimeter for Quality Assurance in Radiation Therapy (Phosphor Particle 혼합형 Hybrid 선량계의 방사선치료 Quality Assurance에 대한 적용가능성 평가)

  • Shin, Yohan;Han, Moojae;Jung, Jaehoon;Cho, Heunglae;Park, Sungkwang
    • Journal of the Korean Society of Radiology
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    • v.13 no.3
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    • pp.333-338
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    • 2019
  • In the field of radiotherapy, the Quality Assurance(QA) procedure to verify the safety of treatment is considered to be very important. However, due to various problems of the conventional dosimeters used for the QA, researches on these dosimeters have been actively carried out to replace them. In this study, to maximize the sensitivity by visible light(VL) emitted from phosphors, blended hybrid sensors were fabricated by blending various weight percent(wt%) of $Gd_2O_2S:Tb$ which is a phosphor with excellent fluorescence efficiency into $PbI_2$. Then, the electrical properties to high energy radiation from the blended sensors and the pure $PbI_2$ sensor were compared and evaluated. As a result of the sensitivity evaluation, the sensor of 3wt% showed the highest value with more than 40% difference from the other sensors, and gradual decreasing in sensitivity was observed with increasing wt% except for the sensor of 3wt%. Also, in the reproducibility evaluation, the pure $PbI_2$ sensor exhibited a large variation in coefficient of variation(CV)>0.015, while all the blended sensors showed CV<0.015.

Performance of Railway Roadbed Reinforced by Acrylate in Laboratory Experiment (실내실험을 통한 아크릴레이트의 철도노반 보강 성능)

  • Yoon, Hwan-Hee;Son, Min;Kim, Jin-Hwan;Kim, Dong-Hyun;Kim, Byung-Hyun;Jung, Hyuk-Sang
    • Journal of the Korean Geosynthetics Society
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    • v.20 no.1
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    • pp.9-19
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    • 2021
  • This paper deals with the reinforcement performance of acrylate for reinforcing the settled railway roadbed. Concrete tracks have the advantage of reducing track maintenance costs and high resistance to track destruction. However, roadbed settlement is occurring in some construction sections, and the safety of railways is a serious concern because of difficulties in maintenance. Currently, maintenance through the track restoration method is being carried out in Korea as a way of roadbed settlement in concrete tracks, but continuous re-settlement can occur because the roadbed itself cannot be reinforced, and there are very few cases of reinforcement of railway roadbeds and field application. So the development of reinforcement materials and construction methods to reinforce railway roadbeds is required. Therefore, in this paper, acrylate was selected as reinforcement material for railway roadbed, and the reinforcement performance of acrylate was analyzed through experiment. As a result, it was analyzed that the acrylate can penetrate into a permeability coefficient of 1×10-4 cm/sec, and secure uniaxial compression strength of 0.5 MPa/30min or more and stiffness of 80 MPa or more.

A Qualitative Study of the Parenting Experience of Adolescents (청소년기 자녀 어머니의 양육경험에 대한 질적 연구)

  • Choi, Ji-Won;Kim, Soo-young
    • The Journal of the Korea Contents Association
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    • v.21 no.5
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    • pp.837-854
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    • 2021
  • This study was conducted to explore parenting experiences for mothers of adolescent children. Participants in the study were 7 primary caregivers of children in the first to third grades of middle school in the Seoul area, and in-depth interviews were conducted from September to November 2019. After recording the interviews of each participant, the transcripts of verbal words and documents that were the summary of the interview were collected as data. In this study, the participants' perceptions of experiences and actions were analyzed by Smith & Osborn (2003)'s interpretative phenomenological method, which allows researchers to make meanings. As a result of data analysis, 6 major topics and 25 sub-themes were derived. The results derived from the parenting experiences of mothers of adolescents are largely six types: the implications of spending time with their children, unnatural act, the aesthetics of expression, the way to recharge energy, the mental heritage that they want to leave for their children, and resilience. The research results of this study can be presented so that they can learn the healthy responses and interaction of care-givers in a preventive educational dimension, as it provides both generality and specificity of how mothers should interact with their adolescent children in the field of clinical practice.

A Study on Algorithm of the Integrated Communication System in Radio Station (무선국의 통합 시스템에 대한 알고리즘의 연구)

  • 조학현;최조천;김기문
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.2 no.4
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    • pp.545-551
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    • 1998
  • The Radio communication by existing SSB, VHF, etc. in a coast station and a base station for military affairs is still used to a very important the device of information delivery or transmitting and receiving by the remote controller to using to the exclusive cable for a equipment established at a long distance. When a number of consumer to connected and operated by a number of transceiver is essential for a circuit controller of ICS, in KOREA, is devoted by import to considerable quantity because of to be delayed development of this field. This Paper has been realized to optimal algorithm and designing of a circuit connection controller by multi-processor to pre-stage for the development of ICS. The H/W is composed able to remote control to circuit connector with the several slave processor and a processor for master, and this has taken possible through without any obstacle to communication circuits of a control signal by FSK system. The S/W make possible monitoring for communication condition of other circuits by means of a serial communication system by the multi-processing. This paper has been studied for connecting to a circuits wished to rapidly and precisely by the full application to a interrupt technique. A technique to control by remote to a number of transceiver is a way increasing to application for a frequency resource of the limited MF/SF, VHF and the existing radio communication technique. According to, this paper will achieve to be the reduction of energy & equipment and multiplicity of information delivery in the general communication and disposal to rapid and exact for the important communication as distress, urgency and safety on the sea.

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Monitoring on the Marine Environment and Phytoplankton of Kongsfjorden, Svalbard, Arctic (북극 스발바드섬 Kongsfjorden의 해양 환경 및 식물플랑크톤 모니터링 연구)

  • Kang, Sung-Ho;Kim, Yea-Dong;Kang, Jae-Shin;Yoo, Kyu-Cheul;Yoon, Ho-Il;Lee, Won-Cheol
    • Ocean and Polar Research
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    • v.25 no.2
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    • pp.213-226
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    • 2003
  • Kongsfjorden near Korean Arctic Station, Dasan, is a glacial fjord in the Svalbard archipelago, Arctic that is influenced by both Atlantic and Arctic water masses. During the Arctic field season August 2002, surface temperature, salinity, density, and phytoplankton biomass (chi a) was measured in Kongsfjorden. A total of 15 surface samples were collected for the phytoplankton related measurements. Chl a values ranged from 0.08 to 1.4mg chi a $m^{-3}$ (mean of 0.53mg chl a $m^{-3}$) in the overall surface stations. The highest values of the chi a concentrations (> 1.0mg chi a $m^{-3}$) were found near glacier in the northeastern part of Kongsfjorden. Nanoplanktonic (< $20{\mu}m$) phytoflagellates were important contributors for the increase of the chi a. The nano-sized phytoflagellates accounted for more than 90% of the total chi a biomass in the study area. Surface temperatures and salinities ranged from 2.5 to $7.18^{\circ}C$ (mean of $4.65^{\circ}C$) and from 22.55 to 32.97 psu (mean of 30.16 psu), respectively. The physical factors were not highly correlated with phytoplankton distribution. The character of surface water due to down-fjord wind was highly similar to phytoplankton distribution. Drifting ice, freshwater, and semdiment inputs from large tidal glaciers located in the inner part of Konsfjorden create steep physico- and biogeochemical environmental gradients along the length of this ford. The glacial inputs cause reduced biodiversity biomass and productivity in the pelagic community in the inner fjord. Primary production of benthic and pelagic microalgae is reduced due to the limited light levels in the turbid and mixed inner waters. The magnitude of glacial effects diminishes towards the outer fjord. Kongsfjorden is an important feeding ground fer marine mammals and seabirds. Especially, seabirds play the largest energy intake and also export nutrients for primary production of the marine microalgae. Kongsfjorden has received a lot of research attention as a site for exploring the impacts of climate changes. Dasan Station in Kongsfjorden will be an important Arctic site for monitoring and detecting future environmental changes.

Characterization and Seawater Filtration Performance of Commerical Microfiltration and Ultrafiltration Membranes (상업용 정밀여과/한외여과막의 특성 분석 및 해수 여과 성능 평가)

  • Choi, Changkyoo;Kim, In S.
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.9
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    • pp.542-547
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    • 2017
  • This paper was to analyze the membrane characterization of hydrophilicity, surface morphology and membrane chemical anlysis of three commercial microfiltration/ultrafiltration membranes, and evaluate the filtration performance of a seawater to assess the availability for pretreatment of desalination process. From the results of contact angle, Mem-3, fabricated with polyacrylonitrile, was highly hydrophilic. It find out that Mem-3 has more anti-biofouling property. In Field emission scanning electron microscope (FESEM), Mem-1 (polyethylene) and Mem-2 (Polyvinylidenefluoride) showed the sponge-like shape and Mem-3 showed finger-like shape. Membrane chemical analysis by energy dispersive spectrometer (EDS) presented that Mem-2 was mostly fluoride and Mem-3 had s high ratio of N (32.47%) due to the nitrile group. The permeation flowrate per time on suction pressures using deionized water (D.I. water) tends that permeation rate of Mem-3 more increased when the pressure was increased compared to other membranes. From the results of turbidity and total suspended solids (TSS) removal, turbidity of permeate was 0.191 NTU to 0.406 NTU and TSS was 2.2 mg/L to 3.0 mg/L in all membranes, indicating that it was not suitable for the pretreatment of seawater desalination by short-term experiments.

Numerical simulation of gasification of coal-water slurry for production of synthesis gas in a two stage entrained gasifier (2단 분류층 가스화기에서 합성가스 생성을 위한 석탄 슬러리 가스화에 대한 수치 해석적 연구)

  • Seo, Dong-Kyun;Lee, Sun-Ki;Song, Soon-Ho;Hwang, Jung-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.417-423
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    • 2007
  • Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

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