• Journal of the Korean Society of Clothing and Textiles
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• v.29 no.7 s.144
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• pp.1027-1036
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• 2005

Based on the correlation analysis result of preceding research, the biodegradabilities of cellulose fibers were closely related to the moisture regain of the samples, which reflects the hydrophilicity and internal structure of the fibers. In addition to this factor, it was expected that the biodegradation conditions influence the biodegradability of fibers. In this study, widely used cellulose fibers including cotton, rayon, and acetate were used. The biodegradabilities of cellulose fibers were measured by soilburial test, and then the degradation behaviors based on each condition were compared. Moreover, the effects of degradation conditions such as humidity of the soil were investigated. Changes in the internal structure of samples were also observed by X-ray analysis according to the soil burial time. It was shown that humidity of soil facilitated the degradation of cotton, rayon, and acetate fibers, showing higher degradation rate with higher humidity in soil. This effect was shown to be much greater in the fibers of high moisture regain such as cotton and rayon. In respect of microstructure change, crystallinities and their crystal size of fibers decreased remarkably in the soil of higher humidity. It was revealed that degradation of crystalline area was more dependent on the soil humidity than that of amorphous area.

• Advances in nano research
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• v.1 no.4
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• pp.183-192
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• 2013

One-dimensional multiferroic nanostructured composites have drawn increasing interest as they show tremendous potential for multifunctional devices and applications. Herein, we report the synthesis, structural and dielectric characterization of barium titanate ($BaTiO_3$)-bismuth ferrite ($BiFeO_3$) composite fibers that were obtained using a novel sol-gel based electrospinning technique. The microstructure of the fibers was investigated using scanning electron microscopy and transmission electron microscopy. The fibers had an average diameter of 120 nm and were composed of nanoparticles. X-ray diffraction (XRD) study of the composite fibers demonstrated that the fibers are composed of perovskite cubic $BaTiO_3$-$BiFeO_3$ crystallites. The magnetic hysteresis loops of the resultant fibers demonstrated that the fibers were ferromagnetic with magnetic coercivity of 1500 Oe and saturation magnetization of 1.55 emu/g at room temperature (300 K). Additionally, the dielectric response of the composite fibers was characterized as a function of frequency. Their dielectric permittivity was found to be 140 and their dielectric loss was low in the frequency range from 1000 Hz to $10^7$ Hz.

• Fibers and Polymers
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• v.5 no.1
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• pp.31-38
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• 2004

In the present paper, a variety of fiber reinforcements, for instance, stabilized OXI-PAN fibers, quasi-carbon fibers, commercial carbon fibers, and their woven fabric forms, have been utilized to fabricate pseudo-unidirectional (pseudo-UD) and 2-directional (2D) phenolic matrix composites using a compression molding method. Prior to fabricating quasi-carbon fiber/phenolic (QC/P) composites, stabilized OXI-PAN fibers and fabrics were heat-treated under low temperature carbonization processes to prepare quasi-carbon fibers and fabrics. The thermal conductivity and thermal expansion/contraction behavior of QC/P composites have been investigated and compared with those of carbon fiber/phenolic (C/P) and stabilized fiber/phenolic composites. Also, the chemical compositions of the fibers used have been characterized. The results suggest that use of proper quasi-carbonization process may control effectively not only the chemical compositions of resulting quasi-carbon fibers but also the thermal conductivity and thermal expansion behavior of quasi-carbon fibers/phenolic composites in the intermediate range between stabilized PAN fiber- and carbon fiber-reinforced phenolic composites.

• Carbon letters
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• v.13 no.4
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• pp.191-204
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• 2012

Carbon nanotubes (CNTs) have exceptional mechanical, electrical, and thermal properties compared with those of commercialized high-performance fibers. For use in the form of fabrics that can maintain such properties, individual CNTs should be held together in fibers or made into yarns twisted out of the fibers. Typical methods that are used for such purposes include (a) surfactant-based coagulation spinning, which injects a polymeric binder between CNTs to form fibers; (b) liquid-crystalline spinning, which uses the nature of CNTs to form liquid crystals under certain conditions; (c) direct spinning, which can produce CNT fibers or yarns at the same time as synthesis by introducing a carbon source into a vertical furnace; and (d) forest spinning, which draws and twists CNTs grown vertically on a substrate. However, it is difficult for those CNT fibers to express the excellent properties of individual CNTs as they are. As solutions to this problem, post-treatment processes are under development for improving the production process of CNT fibers or enhancing their properties. This paper discusses the recent methods of fabricating CNT fibers and examines some post-treatment processes for property enhancement and their applications.

• Carbon letters
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• v.9 no.4
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• pp.324-339
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• 2008

The principal aims of the review paper are (1) to establish broad overview information, both qualitative and quantitative, relating to the world market for polyacrylonitrile (PAN) or pitch-based carbon fibers; and (2) to generate an effective analysis and break down of consumption by process route and eventual end-use. The review paper also designed specifically to provide subscribers with an accurate, independent, and realistic assessment of the current status and future perspective of the market for carbon fibers in the world. The world market for carbon fibers continues to grow rapidly, fuelled by new industrial end uses, such as sport and leisure goods, aerospace, automotive applications, civil engineering and infrastructure repair, and immerging applications in energy generation. Demands for properties of carbon fibers used in those applications include many things such as strength, toughness, fatigue property, corrosion resistance, heat resistance, etc., and these become to be higher level. On the other hand, demands for manufacturing technologies of carbon fibers become to be difficult with these demands for properties, and these are wide variety such as high efficiencies, high qualities, many functions, labor saving, and low cost. In this review paper, thus, the recent carbon fibers corresponded to these needs, and its latest manufacturing technologies as well as market prospects are described.

• Textile Coloration and Finishing
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• v.26 no.3
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• pp.230-236
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• 2014

The kapok fibers which are the functional fiber materials having natural hollows are environment friendly materials the demand and interest of which are increasing. The kapok fibers are environment friendly and natural hollow fibers which are 5-8 times lighter than cottons and have excellent performances in thermo keeping property, air permeability, bulkiness and resilience. In this study, the pretreatment according to the dyeing behaviors of kapok fibers were studied. Pretreatment(scouring, bleaching) were a variety of conditions. Scouring and bleaching, images of changed surfaces and cross-sections and dyeing behaviors of the dye-o-meter according to the concentration measured in meters and compared. Although the final exhaustion ratio of the kapok fibers scoured with a high concentration recipe was almost as same as that of the kapok fibers bleached with a high concentration recipe, the initial absorption speed of the kapok fibers scoured with the high concentration recipe was faster than that of the kapok fibers bleached with the high concentration recipe.

• Macromolecular Research
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• v.16 no.1
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• pp.21-30
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• 2008

Based on the sheath-core bicomponent composite fibers with modified polystyrene (PS) and the modified polypropylene (PP), composite fibers obtained were further cross-linked and sulphonated with chlorosulphonic acid to produce strong acidic cation ion exchange fibers. The structures of the fibers obtained were characterized using Fourier transform infrared (FT-IR) spectroscopy, differential scanning calorimetry (DSC) etc. The optimal technology of the fibers obtained is discussed. The static absorption capacity of the sheath-core bicomponent composite cation exchange fibers for $Zn^{2+}$, $Cu^{2+}$ was determined. The absorption kinetics and major factors affecting the absorption capacities of $Zn^{2+}$, $Cu^{2+}$ were studied, and its chemical stability and regenerating properties were probed. The results suggest that cation exchange fibers with better mechanical properties and higher exchange capability were obtained. Moreover, this type of ion exchange fiber has good absorption properties and working stability to various metal ions. Hence, they have higher practicability.

• Textile Coloration and Finishing
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• v.15 no.3
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• pp.161-167
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• 2003

The preparations of deodorizing fibers using $TiO_2$ have been investigated. The fibers were coated with $TiO_2$ for the purpose of deodorizing by dipping fibers into the $TiO_2$ sol solutions and calcined at $450^\circ{C}$, $500^\circ{C}$ and $750^\circ{C}$ for 1 h after coating. The surface structure of the coated fibers was studied with XRD on the different preparation conditions of calcination temperatures. The deodorizing function of the prepared fibers was studied by the determination of the decomposing capability for $NH_3,\;CH_3SH\;and\;CH_3CHO$. The deodorant activity(D.A.) of these deodoriBing fibers was measured by chromogenic gas detector tubes. The deodorizing effect of the prepared fibers were shown to be similar for the three model compounds; 5wt% $TiO_2$ sol solution calcined at $450^\circ{C}$ < 5 wt% $TiO_2$ sol solution calcined at $500^\circ{C}$< 5 wt% TiO$_2$ sol solution calcined at $750^\circ{C}$.

• Macromolecular Research
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• v.15 no.5
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• pp.449-458
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• 2007

The aims of this study were to investigate the intercalation of polymer chains with organoclays and improve the thermo-mechanical properties of poly(butylene terephthalate) (PBT) hybrids by comparing PBT hybrids synthesized using two different organoclays. The organoclays; dodecyltriphenylphosphonium-montmorillonite ($C_{12}PPh-MMT$) and dodecyltriphenylphosphonium-mica ($C_{12}PPh-Mica$), were used to fabricate the PBT hybrid fibers. Variations in the properties of the hybrid fibers with the organoclays within the polymer matrix, as well as the draw ratio (DR), are discussed. The thermo-mechanical properties and morphologies of the PBT hybrid fibers were characterized using differential scanning calorimetry, thermogravimetric analysis, wide-angle X-ray diffraction, electron microscopy and mechanical tensile properties analysis. The nanostructures of the hybrid fibers were determined using both scanning and transmission electron microscopies, which showed some of the clay layers to be well dispersed within the matrix polymer, although some clustered or agglomerated particles were also detected. The thermal properties of the hybrid fibers were found to be better than those of the pure PBT fibers at a DR = 1. The tensile mechanical properties of the $C_{12}PPh-MMT$ hybrid fibers were found to worsen with increasing DR. However, the initial moduli of the $C_{12}PPh-Mica$ hybrid fibers were found to slightly increase on increasing the DR from 1 to 18.

• Structural Engineering and Mechanics
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• v.59 no.1
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• pp.133-151
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• 2016

Self-Compacting Concrete (SCC) has been originally developed in Japan to offset a growing shortage of skilled labors, is a highly workable concrete, which is not needed to any vibration or impact during casting. The utilizing of fibers in SCC improves the mechanical properties and durability of hardened concrete such as impact strength, flexural strength, and vulnerability to cracking. The purpose of this investigation is to determine the effect of steel fibers on mechanical performance of traditionally reinforced Self-Competing Concrete beams. In this study, two mixes Mix 1% and Mix 2% containing 1% and 2% volume friction of superplasticizer are considered. For each type of mixture, four different volume percentages of 60/30 (length/diameter) fibers of 0.0%, 1.0%, 1.5% and 2% were used. The mechanical properties were determined through compressive and flexural tests. According to the experimental test results, an increase in the steel fibers volume fraction in Mix 1% and Mix 2% improves compressive strength slightly but decreases the workability and other rheological properties of SCC. On the other hand, results revealed that flexural strength, energy absorption capacity and toughness are increased by increasing the steel fiber volume fraction. The results clearly show that the use of fibers improves the post-cracking behavior. The average spacing of between cracks decrease by increasing the fiber volume fraction. Furthermore, fibers increase the tensile strength by bridging actions through the cracks. Therefore, steel fibers increase the ductility and energy absorption capacity of RC elements subjected to flexure.