• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.472-477
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• 2016

We studied the effects of anodic oxidation treatments of carbon fibers on interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites with various current densities. The surface of treated carbon fibers was characterized by atomic force microscope (AFM), field emission-scanning electron microscope (FE-SEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS). The interlaminar shear strength (ILSS) of the composites was determined by a short beam shear test. This result showed that both the roughness and oxygen group of the carbon fibers surface increased in proportion to the current density. After anodic-oxidation-treated, the ILSS also increased as a function of the current density. In addition, the proportional relationship between ILSS and phenolic hydroxyl group was confirmed. The ILSS of the CF-2.0 sample increased by 4% compared to that of the CF-AS sample, because the anodic oxidation treatment increased the oxygen group and roughness on the carbon fibers surface, which leading to the improvement of the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites. Among these, the phenolic hydroxyl group which has the proportional relationship with ILSS is found to be the most important factor for improving the interfacial adhesion of the carbon fibers-reinforced epoxy matrix composites.

• Journal of the Korean Geosynthetics Society
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• v.17 no.4
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• pp.169-177
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• 2018

Glass fiber reinforced polyester (GFRP) composites are widely used as structural materials in harsh environment such as underground pipes, tanks and boat hulls, which requires long-term water resistance. Especially, these materials might be damaged due to delamination between gelcoat and composites through an osmotic process when they are immersed in water. In this study, GFRP laminates were prepared by surface treatment of UPE (unsaturated polyester) gelcoat by vacuum infusion process to improve the durability of composite materials used in underground pipes. The composite surface coated with gelcoat was examined for surface defects, cracking, and hardness change characteristics in water-immersion environments (different temperatures of $60^{\circ}C$, $75^{\circ}C$, and $85^{\circ}C$). The penetration depth of cracks was investigated by micro CT imaging according to water immersion temperature. It was confirmed that cracks developed into the composites material at $75^{\circ}C$ and $85^{\circ}C$ causing loss of durability of the materials. The point at which the initial crack initiated was defined as the failure time and the life expectancy at $23^{\circ}C$ was measured using the Arrhenius equation. The results from this study is expected to be applied to reliability evaluation of various industrial fields where gelcoat is applied such as civil engineering, construction, and marine industry.

• Journal of the Korean Society of Clothing and Textiles
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• v.30 no.3 s.151
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• pp.447-457
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• 2006

The purpose of this study is to document and preserve an unidentified textile purchased at a flea market. This study object is important because it is one of the very rare silk insert series from 1930s which were created for commercial use(as inclusion in cigarette packages). The investigation was conducted by researching the limited publications that discuss silk inserts, visiting many sites on the internet that offer such inserts for sale or catering to the collectors of these silk inserts, and especially visiting the collection of silk inserts, named the J.R. Burdick Collection, at the Metropolitan Museum of Art, New York. Several pieces matched the patches used in the study piece. But Buidick's description on time frame(1912-1915) did not indicate the full range of production of silk inserts. After the identification of object, the conservation treatment was carefully done using adhesives. The results of this study can be summarized as follows; 1. The silk inserts of the study object were included as promotions by some company owned by the American Tobacco Company, probably at some time between 1934 and 1939. 2. The initial stage in the conservation treatment was mechanical surface cleaning using a vacuum cleaner. After vacuuming, humidification was conducted to reduce creases in the top of the object. The damaged areas were backed with stabiltax coated with a solution of Elvace 45675 since the fiber of this object was too deteriorated. 3. Adhesive treatments using Elvace showed satisfactory results: flexibility, strength, no damaging effects on the study object, removability without damaging the object.

• Membrane and Water Treatment
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• v.9 no.5
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• pp.327-334
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• 2018

The nano/micro composites with highly porous surface area have attracted of great interest, particularly the synthesis of porous and thin film sheets of high performance. In this paper, an easy method of cost-effective synthesis of thin film ceramic fiber membranes based on Hydroxyapatite, and activated carbon by turned into studied to be applied within the service-facilitated the transport of radioactive waste such as $^{90}Sr$, $^{137}Cs$ and $^{60}Co$) as activated product of radioisotopes from ETRR-2 research reactor and dissolved in 3M $HNO_3$, across a thin flat-sheet supported liquid membrane (TFSSLM). Radionuclides are transported from alkaline pH values. The presence of sodium salts in the aqueous media improves in $HNO_3$, the lowering of permeability because the initial $HNO_3$ concentration is improved. The study some parameters on the thin sheet ceramic supported liquid membrane. EDTA as stripping phase concentration, time of extraction and temperature were studied. The study of maximum permeability of radioisotopes for all parameters. The pertraction of a radioactive waste solution from nitrate medium were examined at the optimized conditions. Under the optimum experimental 98.6-99.9% of $^{90}Sr$, 79.65-80.3% of $^{137}Cs$ and $^{60}Co$ 45.5-55.5% in 90-110 min with were extracted in 10-30 min, respectively. The process of diffusion in liquid membranes is governed by the chemical diffusion process.

• International Journal of Concrete Structures and Materials
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• v.7 no.1
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• pp.35-50
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• 2013

Rapid and effective repair methods are desired to enable quick reopening of damaged bridges after an earthquake occurs, especially for those bridges that are critical for emergency response and other essential functions. This paper presents results of tests conducted as a proof-of-concept in the effectiveness of a proposed method using externally bonded carbon fiber reinforced polymer (CFRP) composites to rapidly repair severely damaged RC columns with different damage conditions. The experimental work included five large-scale severely damaged square RC columns with the same geometry and material properties but with different damage conditions due to different loading combinations of bending, shear, and torsion in the previous tests. Over a three-day period, each column was repaired and retested under the same loading combination as the corresponding original column. Quickset repair mortar was used to replace the removed loose concrete. Without any treatment to damaged reinforcing bars, longitudinal and transverse CFRP sheets were externally bonded to the prepared surface to restore the column strength. Measured data were analyzed to investigate the performance of the repaired columns compared to the corresponding original column responses. It was concluded that the technique can be successful for severely damaged columns with damage to the concrete and transverse reinforcement. For severely damaged columns with damaged longitudinal reinforcement, the technique was found to be successful if the damaged longitudinal reinforcement is able to provide tensile resistance, or if the damage is located at a section where longitudinal CFRP strength can be developed.

• Membrane and Water Treatment
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• v.8 no.3
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• pp.225-244
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• 2017

A novel thin-film nanocomposite (TFN) reverse osmosis (RO)/non-woven fabric (NWF) membrane was prepared by adding zinc oxide (ZnO) nanospheres ($30{\pm}10nm$) during the interfacial polymerization process of m-phenylenediamine (MPD) and trimesoyl chloride (TMC) on self-made polysulfone (PSF) membrane/polyester (PET) non-woven fabric support. The improved performance of TFN RO membrane was verified in terms of water contact angle (WCA), water flux, salt rejection, antifouling properties and chlorine resistance. The results showed that the WCA value of TFN RO surface had a continuous decrease with the increasing of ZnO content in MPD aqueous solution. The water flux of composite TFN RO membranes acquired a remarkable increase with a stable high solute rejection (94.5 %) in $1g{\cdot}L^{-1}$ NaCl aqueous solution under the optimized addition amount of ZnO (1 wt%). The continuous testing of membrane separation performance after the immersion in sodium hypochlorite solution indicated that the introduction of ZnO nanospheres also dramatically enhanced the antifouling properties and the chlorine resistance of composite RO membranes.

• Archives of Pharmacal Research
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• v.26 no.4
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• pp.286-293
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• 2003

Several polyphenolic compounds and complex mixtures were isolated from brown algae species. The 1,1-diphenyl-2-picryhydarzyl (DPPH) radical scavenging activity and ferric reducing antioxidant power (FRAP) of these compounds were evaluated to determine their physiological usefulness as antioxidants for vascular protection. The antioxidative protection of low-density lipoprotein (LDL) was also evaluated and compared with that of catechin, because the generation of oxidized LDL is one of the most active and specific risk factors contributing to atherogenesis. Oral administration to rats of a commercially available sample ($VNP^{TM}$) containing 30% of these polyphenolic compounds and 70% dietary fiber revealed that the serum reducing capacity measured in terms of FRAP value was significantly elevated 30 min after the treatment, but declined rather quickly thereafter, indicating the good oral absorption of the compounds and their fast binding to the lumenal surface of the blood vessels. An eight-week, human, clinical trial (n=31) of $VNP^{TM}$ showed significant improvement in erectile function measured by IIEF (international index of erectile function) score. These results collectively demonstrated the usefulness of these polyphenolic compounds as fundamental chemopreventive agents against vascular risk factors originating from oxidative stress.

• Fibers and Polymers
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• v.6 no.4
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• pp.322-331
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• 2005

Graduated compression stockings (GCS) have been widely used for the prophylaxis and treatment of venous diseases. Their gradient pressure function largely related to their fabric structure and material properties. By combing fabric physical testing and wear trials, this study investigated the GCSs fabric structure and material properties at different locations along the stocking hoses, and quantitatively analyzed the effects of fabrics on skin pressure longitudinal and transverse distributions. We concluded that, Structural characteristics and material properties of stocking fabrics were not uniform along the hoses, but a gradual variation from ankle to thigh regions, which significantly influenced the corresponding skin pressure gradient distributions; Tensile (WT, EM) and shearing properties (G) generated most significant differences among ankle, knee and thigh regions along the stocking hose, which significantly influenced the skin pressure lognitudinal gradient distribution. More material indices generating significant gradual changes occurred in the fabric wale direction along stocking hose, meaning that materials properties in wale direction would exert more important impact on the skin pressure gradient performances. And, the greater tensibility and smoother surface of fabric in wale direction would contribute to put stocking on and off, and facilitate wearers' leg extension-flexion movements. The indices of WT and EM of stocking fabrics in series A have strong linear correlations with skin pressure lognitudinal distribution, which largely related to their better performances in gradual changes of material properties. Skin pressure applied by fabric with same material properties produced pronounced differences among four different directions around certain cross-sections of human leg, especially at the ankle region; and, the skin pressure magnitudes at ankle region were more easily influenced by the materials properties, which were considered to be largely related to the anatomic structure of human leg.

• Membrane Journal
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• v.30 no.5
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• pp.293-306
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• 2020

Increasing harmful effects of climate change, such as its effect on water scarcity, has led to a focus on developing effective water purification methods to obtain pure water. Additionally, rising levels of water pollution is increasing levels of environmental degradation, calling for sources of water treatment to remove contaminants. To purify water, osmotic processes across a semipermeable membrane can take place, and recent studies are showing that incorporating nanoparticles, including carbon quantum dots (CQDs), graphene carbon dots (GQDs), and graphene oxide quantum dots (GOQDs) are making thin film composite (TFC) membranes more effective by increasing water flux while maintaining similar levels of salt rejection, increasing the hydrophilicity of the membrane surface, showing bactericidal properties, exhibiting antifouling properties to prevent accumulation of bacteria or other microorganisms from reducing the effectiveness of the membrane, and more. In the review, the synthesis process, applications, functionality, properties, and the role of several types of quantum dots are discussed in the composite membrane for water purification.

• Tribology and Lubricants
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• v.33 no.1
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• pp.15-22
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• 2017

Because the running speed of vehicles is increasing and a shorter braking distance is required, high heat-resistant brake pads are needed to satisfy the requirements of customers and car makers. In the near future, hazardous materials such as Cu, Cr, Zn, and Sb will be restricted from use in friction materials. Ceramic composites reinforced by carbon fibers are good candidates for eco-friendly friction materials. In this study, we develop ceramic composite friction materials. The friction materials are composed of carbon fibers, Si, SiC, graphite, and phenol resin and are prepared by hot forming and heat treatment at high temperatures. The density, void ratio, and compressive strength are $1.59-1.66g/cm^3$, 16.6-20, and 70-90 MPa, respectively. Friction and wear tests are performed using a pin-on-plate-type reciprocating friction tester at 25, 100, and $200^{\circ}C$. The counterpart material is a CrMoV steel extracted from a KTX brake disc. Friction coefficient, wear amount, and wear mechanism are measured and examined. We determine that the friction coefficients depend on the temperature and the fluctuation of the friction coefficients is larger at higher temperatures. The amount of wear increases with the surface temperatures of the specimens. The tribological properties of the developed composites are similar to those of a Cu-based sintered friction material. Through this study, it is confirmed that ceramic composite materials can be used as friction materials.