• Title/Summary/Keyword: f-structure

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Solution-State Structure of Native Coenzyme F430 by NMR Methods

  • 원호식;Karl D. Olson;박지석;Ralph S. Wolfe;Dennis R. Hare;Michael F. Summers
    • Bulletin of the Korean Chemical Society
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    • v.16 no.7
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    • pp.649-653
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    • 1995
  • Solution-state structure of native F430 was determined by using NMR methods and NMR-based distance geometry (DG) computations. Structures were generated with loose NOE-derived interproton distance restraints (2.0-2.5 Å, 2.0-3.5 Å and 2.0-4.5 Å for strong, medium, and weak NOE cross-peak intensities, respectively). 2D NOESY back-calculations of structures were subsequently carried out for establishing the consistence between experimental data and DG-model structures. The back-calculated 2D NOESY spectra of resulting DG structures were well consistent with experimental 2D NOESY spectra. Superposition of 20 independent structures with macrocyclic ring atoms and all atoms of F430 afforded pairwise root mean square deviations (RMSD) of 0.025-0.125 Å and 0.64-1.3 Å, respectively. The macrocyclic rings of structures are well converged to a unique conformation with saddle-shaped deformation whereas most of side chains are not converged. The average dihedral angle (N1-N2-N3-N4, 27.78±1.50°) of 20 DG-structures exhibits that the macrocyclic ring conformation is puckered as much as 12,13-diepimeric F430 (28.75±4.07°).

Lock-on Characteristics of wake behind a Rotationally Oscillating Circular Cylinder (주기적으로 회전진동하는 원주 후류의 공진특성)

  • Lee Jung Yeop;Lee Sang Joon
    • 한국가시화정보학회:학술대회논문집
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    • 2004.11a
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    • pp.18-21
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    • 2004
  • Lock-on characteristics of the flow around a circular cylinder performing a rotationally oscillation with a relatively high forcing frequency have been investigated experimentally using flow visualization and hot-wire measurements. Dominant parameters are Reynolds number (Re), amplitude of oscillation $(\theta_A)$, and frequency ratio $F_R=f_f\;/\;f_n$, where $f_f$ is the forcing frequency and if is the natural frequency of vortex shedding. Experiments were carried out under the conditions of $Re=4.14\times10^3,\;\pi/15\leq\theta_A\leq\pi/3$, and $F_R=1.0$. The effects of this active control technique on the lock-on flow regime of the cylinder wake were evaluated through wake velocity measurements and spectral analysis of hot-wire signals. The rotary oscillation modified the flow structure of near wake significantly. The lock-on phenomenon was found to occur in the range of frequency encompassing the natural vortex shedding frequency. In addition, when the amplitude of oscillation is less than a certain value, the lock-on phenomenon was occurred only at $F_R=1.0$. The lock-on range expanded and vortex formation length decreased as the amplitude of oscillation increases. The rotary oscillation generated small-scale vortex structure just near the cylinder surface.

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Finite Element Vibration/Shock Analysis of Double Stage Elastic Mounting System with Viscoelastically Damped Foundation Structure (유한용소법을 이용한 점탄성 감쇠구조물이 포함된 2단 탄성마운트 시스템의 진동/충격응답 해석)

  • 정우진;류정수;배수룡;함일배
    • Journal of KSNVE
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    • v.10 no.3
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    • pp.508-516
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    • 2000
  • To study the possibility of F.E.M application to vibration and shock response of double stage elastic mounting system with complicated damped foundation structure like common-bed or raft in ships foundation structure model which has complicated damped sandwich cross-section is analyzed first. And then vibration responses experimental results and shock response of double stage elastic mounting system with complicated damped foundation structure like common-bed or raft in ships foundation structure model which adopts the above damped structure as intermediate foundation were compared. As a result it is found that F.E.M could be effectively used in analyzing the vibration and shock response of double and multi-stage elastic mounting system with complicated damped foundation structures.

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INDEFINITE GENERALIZED SASAKIAN SPACE FORM ADMITTING A GENERIC LIGHTLIKE SUBMANIFOLD

  • Jin, Dae Ho
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.6
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    • pp.1711-1726
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    • 2014
  • In this paper, we study the geometry of indefinite generalized Sasakian space form $\bar{M}(f_1,f_2,f_3)$ admitting a generic lightlike submanifold M subject such that the structure vector field of $\bar{M}(f_1,f_2,f_3)$ is tangent to M. The purpose of this paper is to prove a classification theorem of such an indefinite generalized Sasakian space form.

Indefinite Generalized Sasakian Space Form Admitting a Lightlike Hypersurface

  • JIN, DAE HO
    • Kyungpook Mathematical Journal
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    • v.55 no.4
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    • pp.1097-1104
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    • 2015
  • In this paper, we study the geometry of indefinite generalized Sasakian space form $\bar{M}(f_1,f_2,f_3)$ admitting a lightlike hypersurface M subject such that the almost contact structure vector field ${\zeta}$ of $\bar{M}(f_1,f_2,f_3)$ is tangent to M. We prove a classification theorem of such an indefinite generalized Sasakian space form.

Experimental Study on Flow Structure of Wake Behind a Rotationally Oscillating Circular Cylinder (주기적으로 회전진동하는 원주 후류의 유동구조에 관한 실험적 연구)

  • Lee Jung-Yeop;Lee Sang-Joon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.4 s.247
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    • pp.298-305
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    • 2006
  • The flow around a circular cylinder which oscillates rotationally with a relatively high forcing frequency has been investigated experimentally using flow visualization and hot-wire measurements. Dominant parameters are Reynolds number (Re), oscillation amplitude $({\theta}_A)$, and frequency ratio $F_R=f_f/f_n$, where $f_f$ is the forcing frequency and $f_n$ is the natural frequency of vortex shedding. Experiments were carried out under the conditions of $Re=4.14{\times}10^3,\;{\theta}_A={\pi}/6$, and $0{\leq}F_R{\leq}2$. The effect of frequency ratio $F_R$ on the flow structure of wake was evaluated by measuring wake velocity profile and spectral analysis of hot-wire signal. Depending on the frequency ratio $F_R$, the cylinder wake has 5 different flow regimes. The vortex formation length and vortex shedding frequency are changed significantly before and after the lock-on regime. The drag coefficient was reduced under the condition of $F_R<1.0$ and the maximum drag reduction is about 33% at $F_R=0.8$. However, the drag is increased as $F_R$ increases beyond $F_R=1.0$. This active flow control method can be effective in aerodynamic applications, if the forcing parameters are selected optimally.

Measurements of the Silica-Silica Interaction Parameter (αF) of the Silane treated Silica Filled Natural Rubber Compound (실란처리된 실리카가 천연고무 복합소재 내에서 실리카 입자간 상호 관계 계수(αF)에 미치는 영향의 비교)

  • Kim, Sung-Min;Choi, Chang-Yong;Jang, Mi-Kyeong;Nah, Jae-Woon;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.47 no.1
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    • pp.18-22
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    • 2012
  • The silica-silica interaction parameter (${\alpha}_F$) of the silane treated silica filled natural rubber (NR) compound was investigated. The measured ${\alpha}_F$ values using mass fraction method following Wolff's theory were compared with volume fraction method. As silica concentration increased, the ${\alpha}_F$ value increased for both methods. The value of ${\alpha}_F$ expressed as volume fraction was higher than that of mass fraction, which resulted in large gaps between ${\alpha}_F$ values. The effect of accelerator (MBT) concentration on ${\alpha}_F$ values was compared.

Isolation and Structural Identification of Antioxidant Substances from Ethyl Acetate Extract of Conyza canadensis (망초(Conyza canadensis) Ethyl Acetate 추출물의 항산화성 물질의 분리와 동정)

  • Hyun Sook Song
    • Journal of Naturopathy
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    • v.12 no.1
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    • pp.7-15
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    • 2023
  • Background: As a result of analyzing the components of wild Conyza canadensis, it contains physiologically active ingredients, so it is necessary to identify the compound. Purposes: It was to study the compound's molecular structure; a previous study showed that C. canadensis contains antioxidant substances. Methods: The ultrasonic pulverized lysate of C. canadensis stem and leaves was first extracted with 90% methanol and then five organic solvents. Next, the extracts was fractionated by HPLC, LC/MS chromatography, and NMR analyzers identified the molecular structure. Results: 100 g of dry C. canadensis was sonicated in 90% methanol and concentrated under reduced pressure to 11.96 g of a crude extract. Then, this crude was extracted with five types of solvents to obtain 123.8 mg of n-hexane, 448.2 mg of dichloromethane, 1047.7 mg of ethyl acetate (EA), 2563.8 mg of butanol, and 7.04 g of water. The EA extracts were fractionated by LC-MS and then re-fractionated to obtain F1 to F20. Next, the F15 was further fractionated to obtain nine fine fractions. Finally, the F17 fraction was re-fractionated to obtain ten fine fractions. As a result of LC-MS and NMR spectrometer analysis of the F15-7, the structure of this compound was confirmed as 3,5-dicaffeoylquinic acid. As a result of examining the structures of the F17-4 and F17-5 fractions, Quercetin-3-o-β-galactose was identified. In addition, the form of the F17-10 was confirmed to be 1,3,4-tri-caffeoylquinic acid. Conclusions: This study demonstrated that C. canadensis contained phenolic antioxidants, and its utilization may be expected.

Semantic Structure of Double Nominative Constructions (이중주격구문의 의미구조)

  • Kim, Kyunghwan
    • The Journal of the Korea Contents Association
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    • v.20 no.5
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    • pp.338-343
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    • 2020
  • This paper provides a semantic account of double nominative constructions in the framework of Autolexical Grammar, which views syntax, semantics, morphology, and other language components as modules generated simultaneously and independently. Some syntactocentric models in the past analyzed double nominatives as a result of possessor raising, ECM or incorporation. This paper provides a semantic explication of double nominatives through function-argument (F/A) structure of internal possession and external possession. The possessum used in double nominatives is a relational noun which takes a possessor as its argument in F/A structure. If the possessor directly combines with the relational noun, then internal possession is generated. If the possessor is a gap in F/A structure, then the argument which is coreferential with the gap combines later with the predicate, resulting in external possession, in which the possessor is in the nominative case. Unlike internal possession, the F/A structure of external possession structurally shows that the sentence is predicated of the possessor.