• 제목/요약/키워드: f-stable

검색결과 791건 처리시간 0.023초

비 유지방 분말크림 제조시 유화 안정성의 비교 (A Comparison of Emulsion Stability as Non-Dairy Coffee Whitener Preparation)

  • 이병영
    • 한국식품영양학회지
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    • 제4권1호
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    • pp.91-98
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    • 1991
  • This study was carried out to investigate the effect of the emulsion stability according to the quantity of emulsifiers and the pressure of homogenizer in coffee whitener preparation. The results of this study are as follow : 1. To obtain a standard emulsifier, the ratio of mono and triglycerides(Atoms 150), sorbitan monostearate (Span 60) and polyoxylene(20) sorbitan monostearate(Tween 60) was 60 . 20 : 20 and the optimum quantity was about 0.9fS for stable emulsion. 2. Characteristics as coffee whitner were markedly improved when the pressure of homogenizer was 200∼250kg1cmz and homogenizing times are over 4. 3. The good whitening capacity was showed when fat glouble's average diameter was under 0.5 Um.

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Vanadium Oxide 나노구조 형성 (Anodic Growth of Vanadium Oxide Nanostructures)

  • 이현권;이기영
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2018년도 춘계학술대회 논문집
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    • pp.68-68
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    • 2018
  • Nanoporous or nanotubular metal oxide can be fabricated by anodization of metal substrate in fluoride contained electrolytes. The approach allows various transition metals such as Zr, Hf, Nb, Ta to form highly ordered oxide nanostructures. These oxide nanostructures have various advantages such as high surface area, fast electron transport rate and slow recombination in semiconductive materials. Recently, vanadium oxide nanostructures have been drawn attentions due to their superior electronic, catalytic and ion insertion properties. However, anodization of vanadium metal to form oxide layers is relatively difficult due to ease formation of highly soluble complex in water contained electrolyte during anodization. Yang et al. reported $[TiF_6]^{2-}$ or $[BF_4]^-$ in electrolyte helps to formation of stable oxide layer [1, 2]. However, the reported approaches are very sensitive in other parameters. In this presentation, we deal with the other important key parameters to form ordered anodic vanadium oxide such as pH, temperatures and applied potential.

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Thermally Stable and Processible Norbornene Copolymers

  • Yoo Dong-Woo;Yang Seung-Jae;Lee Jin-Kyu;Park Joohyeon;Char Kookheon
    • Macromolecular Research
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    • 제14권1호
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    • pp.107-113
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    • 2006
  • Processible norbornene copolymers were realized by judiciously designing norbomene comonomers, which were themselves prepared by the Diels-Alder reaction of cyclopentadiene and benzoquinone followed by the isomerization and alkylation of alcohols. The norbornene copolymers containing these derivatized comonomers, prepared by [Pd($x_{2}CH-{3} $)$_{4}$][$SbF_{6}$]$_{2}$ catalyst, exhibited excellent solubility in many organic solvents as well as good thermal stability, as evidenced by their high glass transition ($T_{g}$) and decomposition ($\∼$350$^{circ}C$) temperatures. In addition, fairly strong adhesion to substrates such as glasses and silicon wafers was also achieved with these copolymers to overcome the limitations experienced by polynorbornene homopolymers and to make them attractive for many important industrial applications.

EDLC용 폴리머 겔 전해질 (Polymer Gel Electrolytes for EDLCs)

  • 정세일;정현철;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2003년도 추계학술대회
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    • pp.351-357
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    • 2003
  • The optimum polymer gel electrolyte composition ratio was 23 : 66 : 11 wt% of P(VdF-co-HFP) : PVP =20 : 3), (PC: EC =44 : 22) and TEABF$_4$. And the optimal thickness of polymer gel electrolyte was 50 ${\mu}{\textrm}{m}$. The electrochemical characteristics result of unit cell were 31.41 Fig of specific capacitance, and 3.21$\times$10$^{-3}$ S/cm of ion conductivity. Ion conductivity of polymer gel electrolytes decreased according to added PVP through impedance analysis, and it was higher in 7 wt%, but electrochemical characteristics of unit cell were better in 3 wt% PVP. And for excellent ion conductivity of polymer gel electrolytes, the use of a thin layer electrolyte(20 $\mu\textrm{m}$) was an effective method, but with unit cell application, the best thickness was 50 $\mu\textrm{m}$. Unit cell showed higher capacitance and more stable electrochemical performance when hot pressed between polymer gel electrolyte and electrode. This results from enhancement of the physical contact between the electrode and the polymer gel electrolyte and good accessibility of the liquid electrolyte to the electrode surface.

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Conformational Investigations of HMPAO Isomers and Their Zinc(II) Complexes

  • Ruangpornvisuti, Vithaya;Pulpoka, Buncha;Tuntulani, Thawatchai;Thipyapong, Khajadpai;Suksai, Chomchai
    • Bulletin of the Korean Chemical Society
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    • 제23권4호
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    • pp.555-562
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    • 2002
  • Isomers based on the RS and EZ geometrical isomerism of the neutral, deprotonated species of HMPAO and their complexes with zinc(Ⅱ) ion have been investigated by semiempirical AM1 optimization method. The Hartree-Fock energies on AM1 geometries o f HMPAO species were calculated with HF/6-31G* methods. Twenty-two isomers of the neutral and twenty isomers of the deprotonated species of HMPAO have been found. The presence of four EE-series isomers of both zinc(Ⅱ) complexes with the neutral and deprotonated HMPAO have been expected and the SREE typical isomer of both types of complexes is the most stable isomer. Energies of complexation of zinc(Ⅱ)/HMPAO isomers with AM1 geometries were calculated by HF/ 6-31G*method. Due to the complexations with zinc(Ⅱ), the structural reorganizations of some isomers of the neutral HMPAO have been occurred. The optimized geometrical parameters of the related conformations have been discussed in terms of their stabilities and existences.

다양한 활성탄 종류에 따른 EDLC 전기화학적 특성 (The electrochemical characteristics of EDLC with various activated carbons)

  • 윤홍진;이창호;이종대
    • 한국응용과학기술학회지
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    • 제28권2호
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    • pp.225-231
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    • 2011
  • The electrochemical characteristics of electric double layer capacitor(EDLC) were investigated using various carbon materials. The physical properties such as specific surface area and mean pore size of activated carbon were analyzed by BET. The results of the activated carbon used for electrode material showed that the specific surface areas varied from 600 to 1500 $m^2$/g and mean pore sizes from 1.74 to 2.88 nm. A maximum specific capacitance of 0.30 F/$cm^2$ was obtained for the activated carbon with the highest specific surface area and ionic conductivity. Also, it was found that the electrochemical results of the cyclic charge-discharge tests were stable.

High Dose $^{60}Co\;{\gamma}$-Ray Irradiation of W/GaN Schottky Diodes

  • Kim, Jihyun;Ren, F.;Schoenfeld, D.;Pearton, S.J.;Baca, A.G.;Briggs, R.D.
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제4권2호
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    • pp.124-127
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    • 2004
  • W/n-GaN Schottky diodes were irradiated with $^{60}Co\;{\gamma}-rays$ to doses up to 315Mrad. The barrier height obtained from current-voltage (I-V) measurements showed minimal change from its estimated initial value of ${\sim}0.4eV$ over this dose range, though both forward and reverse I-V characteristics show evidence of defect center introduction at doses as low as 150 Mrad. Post irradiation annealing at $500^{\circ}C$ increased the reverse leakage current, suggesting migration and complexing of defects. The W/GaN interface is stable to high dose of ${\gamma}-rays$, but Au/Ti overlayers employed for reducing contact sheet resistance suffer from adhesion problems at the highest doses.

Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore

  • Jeong, Dae-Cheol;Lee, Hyo-Kyoung;Jeon, Seung-Won
    • Bulletin of the Korean Chemical Society
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    • 제27권12호
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    • pp.1985-1988
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    • 2006
  • The polymeric membrane electrodes based on urea derivative as an ionophore were prepared and studied for the iodide-ion selective electrode. This membrane exhibits a linear stable response over a wide concentration range ($1.0\;{\times}\;10^{-5}\sim1.0\;{\times}\;10^{-2}$) with a slope of -57.7 mV/decade, a detection limit of log[$I^-$] = -5.63, and a selectivity coefficient for iodide against perchlorate anion (log$K^{pot}_{I^-,j}$ = -1.42). The selectivity series of the membrane gives the follow as $I^-$ > $SCN^-$, $Sal^-$ > $ClO_4^-$ > $NO_3^-$ > $Br^-$ > $NO_2^-$ > $Cl^-$ > $F^-$. The proposed electrode showed good selectivity and response for iodide anion over a wide variety of other anions in pH 5.0 buffer solutions.

Wide Speed Direct Torque and Flux Controlled IPM Synchronous Motor Drive Using a Combined Adaptive Sliding Mode Observer and HF Signal Injection

  • Foo, Gilbert;Rahman, M.F.
    • Journal of Power Electronics
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    • 제9권4호
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    • pp.582-592
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    • 2009
  • This paper proposes a new speed sensorless direct torque and flux controlled interior permanent magnet synchronous motor (IPMSM) drive. Closed-loop control of both the torque and stator flux linkage are achieved by using two proportional-integral (PI) controllers. The reference voltage vectors are generated by a SVM unit. The drive uses an adaptive sliding mode observer for joint stator flux and rotor speed estimation. Global asymptotic stability of the observer is achieved via Lyapunov analysis. At low speeds, the observer is combined with the high frequency signal injection technique for stable operation down to standstill. Hence, the sensorless drive is capable of exhibiting high dynamic and steady-state performances over a wide speed range. The operating range of the direct torque and flux controlled (DTFC) drive is extended into the high speed region by incorporating field weakening. Experimental results confirm the effectiveness of the proposed method.

Novel Small Molecular Materials For Solution Green Phosphorescent OLEDs

  • Lee, Ho-Jae;Yu, Eun-Sun;Jung, Sung-Hyun;Kim, Hyung-Sun;Kang, Eui-Su;Chae, Mi-Young;Chang, Tu-Won
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.791-793
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    • 2009
  • We have developed novel small molecular materials for solution phosphorescent OLEDs having multilayered device structures. These novel materials are applied as an interlayer which is between a buffer layer (or hole injection layer) and an emitting layer to improve the luminance efficiency of solution green phosphorescent OLEDs. In order to form stable double layers by spincoating process, we take the advantage of solubility differences of interlayer materials and emitting materials. Using CIM3 as an interlayer, we have attained the best luminance efficiency, 36 cd/A at a given constant of 2000cd/$m^2$ in the structure of ITO/PEDOT:PSS/CIM3/CIM6:Ir(mppy)$_3$/BAlq/Alq$_3$/LiF/Al.

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