Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore

  • Jeong, Dae-Cheol (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • Published : 2006.12.20
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Abstract

The polymeric membrane electrodes based on urea derivative as an ionophore were prepared and studied for the iodide-ion selective electrode. This membrane exhibits a linear stable response over a wide concentration range ($1.0\;{\times}\;10^{-5}\sim1.0\;{\times}\;10^{-2}$) with a slope of -57.7 mV/decade, a detection limit of log[$I^-$] = -5.63, and a selectivity coefficient for iodide against perchlorate anion (log$K^{pot}_{I^-,j}$ = -1.42). The selectivity series of the membrane gives the follow as $I^-$ > $SCN^-$, $Sal^-$ > $ClO_4^-$ > $NO_3^-$ > $Br^-$ > $NO_2^-$ > $Cl^-$ > $F^-$. The proposed electrode showed good selectivity and response for iodide anion over a wide variety of other anions in pH 5.0 buffer solutions.

Keywords

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