• Title/Summary/Keyword: extraction constant

검색결과 251건 처리시간 0.023초

진한 염산용액에서 구리(II)와 알루미늄(III)이 Alamine336에 의한 백금(IV)과 팔라듐(II)의 추출 및 분리에 미치는 영향 (Effect of Cu(II) and Al(III) on the Extraction and Separation of Pt(IV) and Pd(II) from Concentrated Hydrochloric Acid Solution with Alamine336)

  • 이만승;안종관;손반반
    • 대한금속재료학회지
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    • 제48권2호
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    • pp.148-153
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    • 2010
  • The effects of Cu(II) and Al(III) on the extraction and separation of Pt(IV) and Pd(II) have been investigated in a mixed chloride solution using Alamine336 as the extractant. In the HCl concentration range of 1 to 5 M, more than 99% of Pt and Pd could be extracted by Alamine336 from all of the mixed chloride solutions investigated in this study. Lower HCl concentration led to a higher separation factor between Pd and Pt when Alamine336 concentration was constant. Extraction percentage of Cu increased with the increase of HCl concentration, while that of Al was nearly constant at 33% in our experimental range. The optimum conditions to extract Pt and Pd from Cu or Al and the separation factor under these conditions were obtained.

비선형 효과를 고려한 IPM형 전동기의 DQ축 인덕턴스 및 역기전력상수 파라미터 추출 (Parameter Extraction of DQ-Axis Inductance and Back-EMF Constant For IPM Type Motors Based on Nonlinear Finite Element Analysis)

  • 최홍순
    • 전기학회논문지
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    • 제56권3호
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    • pp.519-523
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    • 2007
  • In this paper, we propose a precise parameter extraction of interior permanent magnet (IPM) motors based on finite element analysis. For the calculation of the two-axis inductances Ld and Lq, the slotting effect and cross magnetization due to torque angle are considered. It is examined that back electro-motive force (BEMF) constant is affected by the magnetic saturation in different ways dependent on motor types. Numerical analyses and some measurements are performed for a spoke type and a flux barrier type IPM motors

지지막을 이용하는 액막 추출기 내에서 아연 이온의 이동 (Transport of Zinc Ion in a Contained Liquid Membrane Permeator with Two Micro-Porous Films)

  • 주창식;이석희;이민규;홍성수;하홍두;정석기
    • 한국환경과학회지
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    • 제9권2호
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    • pp.159-164
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    • 2000
  • For the purpose of development of a liquid membrane permeator which separates metal ions from aqueous solutions continuously and effectively, a continuous membrane permeator with the membrane solution trapped between extraction and stripping phases by two micro-porous hydrophilic films was manufactured. Experimental researches on the separation of zinc ion from aqueous solutions were performed in the liquid membrane permeator with 30 vol % D2EHPA solution in kerosine as liquid membrane. As results, the liquid membrane permeator separates zinc ion from aqueous solutions continuously and effectively in the wide range of operating conditions. A simple mass transfer rate model using equilibrium constant of the extraction reaction for the system used were proposed, and the model was compared with experimental results of separation of zinc ion in the permeator. And the effects of operating factors, such as space time, pH of extraction solution, extraction temperature, on the separation rate of zinc ion in the permeator were experimentally examined.

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벌집형 소형 태양열 저장수조의 열저장층 내의 온도변화에 관한 실험적 연구 (An Experimental Study on the Temperature Variation in Heat Storage Zone in the Honeycomb-covered Small Saltless Solar Pond)

  • 박이동;황성일;한동균
    • 태양에너지
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    • 제9권1호
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    • pp.30-35
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    • 1989
  • This paper dealt with an experiments on temperature vairation in the heat storage zone due to change of vertical location (height) of sink diffuser and flow extraction in small saltless solar pond ($0.5{\times}0.5{\times}1.0M$), and the honeycomb device for this experimental purpose consisted of one-tired, sealed, and air filled by honeycomb panels. As results of experiments, 1) The storage zone was formed under lower region below the honeycomb device. 2) The higher vertical location of sink diffuser was placed, the more mixing phenomenon increased in the pond at steady flow extraction. 3) The more flow extraction increased, the more mixing phenomenon decreased at constant heat exchanger and variable flow extraction.

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Active components delivery rate from acrylic resin maxillary surgical obturator: Part I

  • Al-Kaabi, Arshad;Hamid, Mohammed A.
    • Advances in materials Research
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    • 제9권2호
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    • pp.109-114
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    • 2020
  • The purpose of this study was to observe the trend of compounds release from acrylic resin oral prosthesis when used for drug delivery as well as a restoration. In this study, 10 specimens of heat-cured polymethylmethacrylate material were prepared and loaded with methylene blue biological stain. The specimens were then submerged in vials with 5 ml distilled water for 24 hours. The extraction procedure continued for 4 days, each day the specimens were immersed in another 5 ml distilled water vial. All extracted solutions were analyzed by visible light spectroscopy for absorbance comparison. The statistical results showed that the absorbance values were significantly different in the first day of extraction than the following days. However, there was no statistical difference among the 2nd, 3rd and 4th days of extraction. Biological stain loading to acrylic resin at the mixing stage, and then after extraction in distilled water, showed a burst release during the first day followed by a constant release during the following few days.

실리콘기판 효과를 고려한 전송선 파라미터 추출 및 신호 천이 (Parameter extraction and signal transient of IC interconnects on silicon substrate)

  • 유한종;어영선
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 하계종합학술대회논문집
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    • pp.871-874
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    • 1998
  • A new transmission line parameter extraction method of iC interconnects on silicon substrate is presented. To extract the acurate parameters, the silicon substrate effects were taken into account. Since the electromagnetic fields under the silicon substrate are propagated with slow wave mode, effective dielectric constant and different ground plane with the multi-layer dielectric structures were employed for inductance and capacitance matrix determination. Then accurate signal transients simulation were performed with HSPICE by using the parameters. It was shown that the simulation resutls has an excellent agreement with TDR/TDT measurements.

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아민 추출제에 의한 유기산의 반응추출(I) (유기산의 반응추출시 추출도에 미치는 추출제 및 용매의 영향에 관한 연구) (Reactive Extraction of Organic Acid with Amine Extractant, I. (A Study on the Effects of Extractant and Solvent on the Degree of Extraction in Reactive Extraction of Organic Acid))

  • 류운형;이한섭;유철휘;김용렬;강안수
    • 공업화학
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    • 제7권1호
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    • pp.203-213
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    • 1996
  • 평형 추출장치를 사용하여 유기산의 물리추출과 반응추출에서 추출도에 미치는 추출제의 종류와 농도, 용매의 영향을 조사하였다. 사용된 유기산은 아크릴산과 메타크릴산이었고, 추출제로는 n-octylamine(OA)과 di-n-octylamine(DOA), tri-n-octylamine(TOA)및 tri-octylmetyl ammonium chloride(TOMAC ; Aliquat 336)을 사용하였다. 실험결과 반응추출에서 추출도는 물리추출의 경우보다 2~9배 정도 증가 되었으며, 유기산의 추출도에 미치는 추출제의 영향은 OA, TOMAC, DOA 및 TOA의 순서로 추출도가 증가하였으며, 또한 추출제의 농도가 증가할수록 추출도가 증가하였다. 용매의 영향은 종래의 용매의 유전상수보다는 용해도인자에 의한 용매선택 방법이 신뢰성이 있었고, 용질과 용매의 용해도인자의 차이가 작을수록 추출도가 증가하여 케로진, 크실렌, 클로로포롬, MIBK 및 n-BAc의 순서로 좋아졌다.

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Characterization of the Yellow Croaker Larimichthys polyactis muscle Oil Extracted with Supercritical Carbon Dioxide and an Organic Solvent

  • Lee, Joo-Hee;Asaduzzaman, A.K.M.;Yun, Jun-Ho;Yun, Jun-Hyun;Chun, Byung-Soo
    • Fisheries and Aquatic Sciences
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    • 제15권4호
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    • pp.275-281
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    • 2012
  • Yellow croaker Larimichthys polyactis muscle oil was extracted using an environmental friendly solvent, supercritical carbon dioxide (SC-$CO_2$), in a semi-batch flow extraction process. SC-$CO_2$ was applied at temperature $35^{\circ}C$ to $45^{\circ}C$ and $150^{\circ}C$ to $250^{\circ}C$ bar of pressure. The flow rate of $CO_2$ (27.79 g/min) was constant throughout the entire 1.5 h extraction period. The oil extraction yield was influenced by the physical properties of SC-$CO_2$ at different temperatures and pressures. The extracted oil was analyzed by gas chromatography to determine the fatty acid composition. According to our results, the SC-$CO_2$ extracted oil was high in eicosapentaenoic acid and docosahexaenoic acid. In addition, the SC-$CO_2$ extracted oil showed greater stability than n-hexane extracted oil based on the peroxide value and acid value. Thus, the quality of yellow croaker oil obtained by SC-$CO_2$ extraction was slightly higher than that of oil obtained by n-hexane extraction.

Correlation Between Arrhenius Equation and Binding Energy by X-ray Photoelectron Spectroscopy

  • Oh, Teresa
    • Transactions on Electrical and Electronic Materials
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    • 제14권6호
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    • pp.329-333
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    • 2013
  • SiOC films were prepared by capacitively coupled plasma chemical vapor deposition, and the correlation between the binding energy by X-ray photoelectron spectroscopy and Arrhenius equation for ionization energy was studied. The ionization energy decreased with increase of the potential barrier, and then the dielectric constant also decreased. The binding energy decreased with increase of the potential barrier. The dielectric constant and electrical characteristic of SiOC film was obtained by Arrhenius equation. The dielectric constant of SiOC film was decreased by lowering the polarization, which was made from the recombination between opposite polar sites, and the dissociation energy during the deposition. The SiOC film with the lowest dielectric constant had a flat surface, which depended on how carbocations recombined with other broken bonds of precursor molecules, and it became a fine cross-linked structure with low ionization energy, which contributed to decreasing the binding energy by Si 2p, C 1s electron orbital spectra and O 1s electron orbital spectra. The dielectric constant after annealing decreased, owing to the extraction of the $H_2O$ group, and lowering of the polarity.

Kelex100로부터 구리입자 분말 합성 (Composite copper powder from Kelex 100)

  • 조종상;;양권승
    • 한국결정성장학회지
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    • 제8권1호
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    • pp.131-137
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    • 1998
  • 구리입자를 코딩한 분말 합성은 Kelex 100 solvent extraction으로부터 silica powder에 수소압력 stripping copper에 의하여 생성하였다. Solvent extraction의 범위내인 일정한 조건에서 loading level과 stripping rate등을 재생하였으며 stripping copper kinetics는 divalent상태에서 metallic 상태로 감소하면서 silica 입자에 침적하였다. Copper들은 seed 입자에 heterogeneous 핵을 형성하면서 이들은 agglomeration 상태로 생성되었고 불균일한 분말로 형성하였다.

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