• Title/Summary/Keyword: external materials

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A Case Study of Different Configurations for the Performance Analysis of Solid Oxide Fuel Cells with External Reformers (외부 개질형 평판형 고체 산화물 연료전지 시스템 구성법에 따른 효율특성)

  • Lee, Kang-Hun;Woo, Hyun-Tak;Lee, Sang-Min;Lee, Young-Duk;Kang, Sang-Gyu;Ahn, Kook-Young;Yu, Sang-Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.3
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    • pp.343-350
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    • 2012
  • A planar solid oxide fuel cell (PSOFC) is studied in its application in a high-temperature stationary power plant. Even though PSOFCs with external reformers are designed for application from the distributed power source to the central power plant, such PSOFCs may sacrifice more system efficiency than internally reformed SOFCs. In this study, modeling of the PSOFC with an external reformer was developed to analyze the feasibility of thermal energy utilization for the external reformer. The PSOFC system model includes the stack, reformer, burner, heat exchanger, blower, pump, PID controller, 3-way valve, reactor, mixer, and steam separator. The model was developed under the Matlab/Simulink environment with Thermolib$^{(R)}$ modules. The model was used to study the system performance according to its configuration. Three configurations of the SOFC system were selected for the comparison of the system performance. The system configuration considered the cathode recirculation, thermal sources for the external reformer, heat-up of operating gases, and condensate anode off-gas for the enhancement of the fuel concentration. The simulation results show that the magnitude of the electric efficiency of the PSOFC system for Case 2 is 12.13% higher than that for Case 1 (reference case), and the thermal efficiency of the PSOFC system for Case 3 is 76.12%, which is the highest of all the cases investigated.

An Experimental Study on Fire Spreading External Wall of Buildings Using Dry Construction Method (건식공법을 이용한 건축물의 외벽 화재 확산의 실험적 연구)

  • Park, Jung-Woo;Cho, Nam-Wook
    • Fire Science and Engineering
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    • v.32 no.4
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    • pp.75-85
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    • 2018
  • The Grenpell tower fire in England in June of 2016 is a representative example of damage caused by a vertical fire spreading through external insulation. Organic insulation materials, which are widely used in external insulation, have the disadvantage that they have good insulation performance but are vulnerable to fire. Aluminum composite panels are used as exterior wall finishing materials, and plastics used in aluminum are regarded as the cause of vertical fire spread. Due to the steel frame used to secure the aluminum composite panel to the outer wall, a cavity is formed between the outer wall and outer wall finish. When a fire occurs on the outer wall, the flammable outer wall as well as the flame generated from the heat-insulating material spreads vertically through the cavity, resulting in damage to people and property. In Korea, material unit performance tests are carried out by the Ministry of Land, Infrastructure and Transport notice 2015 - 744. However, in the UK, the BS 8414 test is used to measure the vertical fire spreading time on the outer wall in real scale fire tests. In this study, the risk of external wall fire was evaluated in an actual fire by conducting a real scale wall fire test (BS 8414), which was carried out in Europe, using aluminum composite panels of semi-noncombustible materials suitable for current domestic standards. The purpose of this study was to confirm the limitations of material unit evaluation of finishing materials and to confirm the necessity of introducing a system to prevent the spread of outer wall fire through an actual scale fire test.

In situ Electric-Field-Dependent X-Ray Diffraction Experiments for Ferroelectric Ceramics (강유전 세라믹의 전기장 인가에 따른 in situ X-선 회절 실험)

  • Choi, Jin San;Kim, Tae Heon;Ahn, Chang Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.431-438
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    • 2022
  • In functional materials, in situ experimental techniques as a function of external stimulus (e.g., electric field, magnetic field, light, etc.) or changes in ambient environments (e.g., temperature, humidity, pressure, etc.) are highly essential for analyzing how the physical properties of target materials are activated/evolved by the given stimulation. In particular, in situ electric-field-dependent X-ray diffraction (XRD) measurements have been extensively utilized for understanding the underlying mechanisms of the emerging electromechanical responses to external electric field in various ferroelectric, piezoelectric, and electrostrictive materials. This tutorial article briefly introduces basic principles/key concepts of in situ electric-field-dependent XRD analysis using a lab-scale XRD machine. We anticipate that the in situ XRD method provides a practical tool to systematically identify/monitor a structural modification of various electromechanical materials driven by applying an external electric field.

Organic nonlinear optic materials for intergated optics and optical teclecommunications (집적광학과 광통신을 위한 비선형광학 유기물질)

  • 윤촌섭
    • Proceedings of the Optical Society of Korea Conference
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    • 1991.07a
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    • pp.5-8
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    • 1991
  • New nonliner organic materials have been developed for all-optical signal processing. The organic materials possess many interesting features for this purpose. Unlike inorganic molecules the delocalized $\pi$-electron distribution and intramolecular charge transfer mevhanism allows certain organic molecules to respond highly anharmonically to an external field. In the present paper the origins of nonlinear phenomena, advantages of orgnic materials and structures of organic devices will be discussed.

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Modeling of damage in cement paste subject to external sulfate attack

  • Xiong, Chuansheng;Jiang, Linhua;Zhang, Yan;Chu, Hongqiang
    • Computers and Concrete
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    • v.16 no.6
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    • pp.847-864
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    • 2015
  • This study aimed to develop models of sulfate diffusion and ettringite content profile in cement paste for the predication of the damage behavior in cement paste subject to external sulfate. In the models, multiphase reaction equilibrium between ions in pore solution and solid calcium aluminates phases and the microstructure changes in different positions of cement paste were taken into account. The distributions of expansive volume strain and expansion stress in cement paste were calculated based on the ettringite content profile model. In addition, more sulfate diffusion tests and SEM analyses were determined to verify the reliability and veracity of the models. As the results shown, there was a good correlation between the numerical simulation results and experimental evidences. The results indicated that the water to cement ratio (w/c) had a significant influence on the diffusion of sulfate ions, ettringite concentration profile and expansion properties in cement paste specimens. The cracking points caused by ettringite growth in cement paste specimens were predicted through numerical methods. According to the simulation results, the fracture of cement paste would be accelerated when the specimens were prepared with higher w/c or when they were exposed to sulfate solution with higher concentration.

Effects of Powder Melting Degree on Microstructural Features of Plasma Sprayed Y2O3 Coating (플라즈마 제트에서의 분말 용융특성에 따른 Y2O3 코팅층의 미세조직 형성거동)

  • Kang, Sang-Woon;Baik, Kyeong-Ho
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.229-234
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    • 2016
  • In this study, the degree of particle melting in $Y_2O_3$ plasma spraying and its effects on coating characteristics have been investigated in terms of microstructural features, microhardness and scratch resistance. Plasma sprayed $Y_2O_3$ coatings were formed using two different powder feeding systems: a system in which the powder is fed inside the plasma gun and a system in which the powder is fed externally. The internal powder spraying method generated a well-defined lamellae structure that was characterized by a thin porous layer at the splat boundary and microcracks within individual splats. Such micro-defects were generated by the large thermal contraction of splats from fully-molten droplets. The external powder spraying method formed a relatively dense coating with a particulate deposition mode, and the deposition of a higher fraction of partially-melted droplets led to a much reduced number of inter-splat pores and intra-splat microcracks. The microhardness and scratch resistance of the $Y_2O_3$ coatings were improved by external powder spraying; this result was mainly attributed to the reduced number of micro-defects.

Hot Rolling Properties of Non-combustible AZ31-xCa Magnesium Alloys (난연성 AZ31-xCa 마그네슘합금의 열간압연 특성)

  • Yim C. D.;You B. S.;Lee J. S.;Kim W. C.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.08a
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    • pp.55-62
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    • 2004
  • In this study, the effects of Ca content and processing variables on hot rolling properties of gravity cast AZ31-xCa alloys were evaluated systematically. The number and length of side crack were decreased with increasing preheating temperature and decreasing reduction ratio per pass and Ca content. The UTS and YS were not strongly dependent on the Ca content but the elongation decreased with increasing Ca content. The decrease of elongation in Ca containing alloys was least when the sheets were fabricated under preheating temperature of $400^{\circ}C$ and reduction ratio per pass of $15\%$. The sheets had the sound external features with little side cracks by homogenization of gravity cast AZ31-xCa alloys before hot rolling. In the cases of AZ31-xCa alloys containing under $1wt.\%$ Ca, the annealed sheets after homogenization and hot rolling had the similar tensile properties to those of AZ31 sheet.

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A Hybrid Audio ${\Delta}{\Sigma}$ Modulator with dB-Linear Gain Control Function

  • Kim, Yi-Gyeong;Cho, Min-Hyung;Kim, Bong-Chan;Kwon, Jong-Kee
    • ETRI Journal
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    • v.33 no.6
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    • pp.897-903
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    • 2011
  • A hybrid ${\Delta}{\Sigma}$ modulator for audio applications is presented in this paper. The pulse generator for digital-to-analog converter alleviates the requirement of the external clock jitter and calibrates the coefficient variation due to a process shift and temperature changes. The input resistor network in the first integrator offers a gain control function in a dB-linear fashion. Also, careful chopper stabilization implementation using return-to-zero scheme in the first continuous-time integrator minimizes both the influence of flicker noise and inflow noise due to chopping. The chip is implemented in a 0.13 ${\mu}m$ CMOS technology (I/O devices) and occupies an active area of 0.37 $mm^2$. The ${\Delta}{\Sigma}$ modulator achieves a dynamic range (A-weighted) of 97.8 dB and a peak signal-to-noise-plus-distortion ratio of 90.0 dB over an audio bandwidth of 20 kHz with a 4.4 mW power consumption from 3.3 V. Also, the gain of the modulator is controlled from -9.5 dB to 8.5 dB, and the performance of the modulator is maintained up to 5 nsRMS external clock jitter.