• Title/Summary/Keyword: explosive concentration

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Numerical investigation on the performance of the aluminized HMX with varying aluminum concentration (알루미늄 함유량 변화에 따른 알루미늄 입자가 함유된 HMX 성능에 관한 수치 연구)

  • Kim, Wuhyun;Gwak, Min-cheol;Yoh, Jai-ick
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.617-621
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    • 2017
  • The performance characteristics of aluminized high explosive are considered by varying the aluminum(Al) concentration in a two-phase model. Since the time scales of the characteristic combustion process of high explosives and Al particles differ, the process of energy release behind the leading detonation wave front occurs over an extended period of time. Two cardinal observations are reported: a decrease in detonation velocity with an increase in Al concentration and a double front detonation (DFD) feature when anaerobic Al reaction occurs behind the front. In the current study, a series of confined rate sticks are considered for characterizing the performance of aluminized HMX with a maximum Al concentration of 50%. The simulated results are compared with the experimental data for 5%-25% concentrations.

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Risk Assessment of Fire and Explosion of Methane (메탄의 화재 및 폭발 위험성 평가)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.1-7
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    • 2005
  • The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Verifying Rehabilitation and Evaluation of Bedrock Wells using Air-brush Surging and Explosive Methods (공기-브러쉬와 폭약 세척 방법에 의한 암반관정의 세척 효과 검증)

  • Lee, Jeong-Hwan;Hamm, Se-Yeong;Han, Suk-Jong;Ok, Soon-Il;Cha, Eun-Jee;Cho, Heuy-Nam;Choo, Chang-Oh;Kim, Moo-Jin
    • The Journal of Engineering Geology
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    • v.21 no.4
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    • pp.369-379
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    • 2011
  • The application of appropriate rehabilitation works can improve productivity and water quality of clogged wells, with extending the operation of the wells for a certain period. This study verified rehabilitation effect of the clogged wells by means of explosive method and air brush surging and by using hydraulic tests, water quality, and geophysical logs (optical and acoustic televiewer logs) before and after the cleaning works on the two wells drilled in bedrock in Mt. Geumjeong, Busan City. Air-brush surging method resulted in maximum 273% increase of the productivity with the concentration of $F^-$, $SiO_2$, and a decrease of turbidity and the concentration of $Cl^-$, $NO_3^-$. The explosive method resulted in maximum 156% increase of the productivity with an increase of the concentration of $F^-$, $SiO_2$ and a decrease of turbidity, $Cl^-$, $NO_3^-$.

Screening and Possibility of Semi-quantitative Analysis of Explosive Compounds in Soil Using EXPRAY$^{(R)}$ Explosives Field Detection Kit (화약물질 현장검출시약 EXPRAY$^{(R)}$를 이용한 토양내 화약물질 스크리닝 및 준정량화 가능성)

  • Bae, Bum-Han;Cho, Jung-Hyun
    • Journal of Soil and Groundwater Environment
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    • v.14 no.2
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    • pp.45-53
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    • 2009
  • A quick and simple detection method of explosive compounds in environmental matrix (soil and water) can provide a screening step which reduces the number of unnecessary samples and the cost of expensive laboratory analysis at a site investigation. A commercially available EXPRAY$^{(R)}$Explosives Field Detection Kit (EXPRAY) was used to determine the minimum detection concentration and to test the possibility of semi-quantitative analysis of 14 explosive compounds using standard solutions. The results showed that EXPRAY could detect 5 explosive compounds, TNT, RDX, HMX, Tetryl, and TNB, out of 14 US EPA designated explosives. The minimum detection limit of the nitramine explosives was 14 ng/$^2$ for HMX and RDX. EXPRAY was more sensitive to nitroaromatics than the nitramines and the minimum detection limits per unit area (mm$^2$) for Tetryl, TNB, and TNT, were 3 ng, 3 ng, and 0.3 ng, respectively. The semi-quantification of 5 explosive compounds in an order ofmagnitude could be achieved by the intensity of developed color only when EXPRAY was applied on the standard solutions under controlled laboratory conditions. With contaminated soil samples, however, only the presence and type of explosive compounds was identified. Therefore, EXPRAY is an economic and sensitive method that can be used in a screening step for the identification of explosives in the field samples.

A Forensic Engineering Study on Evaluation of Explosive Pressure and Velocity for LNG Explosion Accident using AUTODYN (AUTODYN을 이용한 LNG 폭발 사고 위력 평가에 관한 법공학적 연구)

  • Kim, Eui Soo;Kim, Jong Hyuk;Shim, Jong Heon;Kim, Jin Pyo;Goh, Jae Mo;Park, Nam Kyu
    • Journal of the Korean Society of Safety
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    • v.30 no.4
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    • pp.56-63
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    • 2015
  • Gas explosion accidents could cause a catastrophe. we need specialized and systematic accident investigation techniques to shed light on the cause and prevent similar accidents. In this study, we had performed LNG explosion simulation using AUTODYN which is the commercial explosion program and predicted the damage characteristics of the structures by LNG explosive power. In the first step, we could get LNG's physical and chemical explosion properties by calculation using TNT equivalency method. And then, by applying TNT equivalency value about the explosion limit concentration of LNG on the 2D-AUTODYN simulation, we could get the explosion pressure wave profiles (explosion pressure, explosion velocity, etc.). In the last step, we performed LNG explosion simulation by applying to the explosion pressure wave profiles as the input data on the 3D-AUTODYN simulation. As a result, we had performed analyzing of the explosion characteristics of LNG in accordance with concentration through the 3D-AUTODYN simulation in terms of the explosion pressure behavior and structure's destruction and damage behavior.

Analysis of Ventilation Performance of PCVD Facility for Solar Cell Manufacturing (Explosion Prevention Aspect) (태양전지 제조용 PCVD설비의 환기 성능 분석(폭발 방지 측면))

  • Lee, Seoung-Sam;An, Hyeong-hwan
    • Journal of the Korean Institute of Gas
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    • v.26 no.5
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    • pp.35-40
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    • 2022
  • PCVD (Plasma Chemical Vapor Deposition), a solar cell manufacturing facility, is a facility that deposits plasma generated in a chamber (NH3, SIH4, O2 on a wafer. In the PCVD facility, gas movement and injection is performed in the gas cabinet, and there are many leak points inside because MFC, regulator, valve, pipe, etc. are intricately connected. In order to prevent explosion in case of leakage of NH3 with an upper explosive limit (UEL) of 33.6% and a lower explosive limit (LEL) of 15%, the dilution capacity must be capable of allowing the concentration of NH3 to be out of the explosive range. This study was analyzed using the CFD analysis technique, which can confirm the dilution ability in 3D and numerical values when NH3 gas leaks from the existing PCVD gas cabinet. As a result, it was concluded that it corresponds to medium dilution and that testicular ventilation is possible through facility improvement.

A Study on the Detection Behavior of Chlorine Dioxide on Metal Oxide Sensors (금속산화물센서의 이산화염소 가스에 대한 감지거동에 관한 연구)

  • Yu, Joon-Boo;Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.29 no.3
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    • pp.211-214
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    • 2020
  • Chlorine dioxide is very effective gas for sterilization or disinfection (in manufacturing), and does not produce harmful by-products after use. However, if its concentration exceeds 10 %, it become explosive and cannot be compressed or stored. Therefore, it is necessary to measure its concentration. In this study, the concentration of chlorine dioxide with a high oxidizing strength was measured using a metal oxide sensor. The sensor was a commercially available TGS series from Figaro. The sensitivity of the sensor was inversely proportional to a low concentration of chlorine dioxide gas below 6 ppm and returned to the initial resistance at about 6 ppm. When the gas concentration reached multiples of 10 ppm, resistance of the sensor increased to several megaohms.

Changes in the CO2 and amount of mycelium growth of the liquid spawn on Flammulina velutipes (팽나무버섯 액체 종균 배양시 이산화탄소 농도와 균사 생장량 변화)

  • Shim, Kyu-Kwang;Yoo, Young-Jin;Koo, Chang-Duck;Kim, Young-Seok;Kim, Myung-Koon
    • Journal of Mushroom
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    • v.10 no.1
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    • pp.3-8
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    • 2012
  • In this study, to produce Flammulina velutipes mushroom liquid spawn efficiently and effectively the effects of explosive aeration (supplying air with tiny bubbles) of the liquid culture medium on carbon dioxide concentration and residual sugar content in the medium on carbon dioxide concentration and residual sugar contentin the medium were measured. Carbon dioxide concentrations were measured at the outlet of the incubator. On the third day the explosive aeration greatly increased mycelial growth of the liquid spawn, and carbon dioxide concentration also greatly increased but decreased after 5 days. Free sugar contents in the liquid culture consistantly decreased up to 7 days and thereafter was not detected. The weight of the mycelia were maintained similar levels after 3 days. Total nitrogen content in the liquid medium constantly decreased during the 11days of explosive aeration. The content of free sugars in 7 days of culture was the lowest level, thus the inoculum incubated for 6~7 days was thought to be the most effective. Carbon dioxide concentration measurement at the outlet of the container during the liquid spawn incubation required low cost but was efficient to estimate the degree of mycelial growth to be used as a simple indicator.

A study of flour dust explosion (사료분진의 폭발특성에 관한 연구)

  • Lee, Hong-Ju;Woo, In-Sung;Hong, Hyun-Kyoung;Sa, Min-Hyung;Kim, Yun-Seon;Hwhag, Myung-Whan;Hwang, Seong-Min;Park, Hee-Chul;Lee, Ju-Yup
    • Journal of the Korea Safety Management & Science
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    • v.13 no.4
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    • pp.109-116
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    • 2011
  • This study examined into property of flour dust explosion to get the basic data for safety of industry by protecting accident of dust explosion. The experiment was conducted to know the effect of distance between explodes in the experiment device, effect of flour dust concentration, effect of humidity, effect of explosion pressure to the dust concentration and effect of inactive substance additive. The study indicated that explosion was happened effectively at the optimum distance 100mm or less in inter-polar distance, and minimum ignition energy was measured at 6mm. The data of feed concentration to the probability of explosion showed that the smaller the particle diameter was, the larger probability of explosion was, and the higher the dust concentration was, the more increased the pressure of explosion was, but more than upper limit of dust concentration, then the explosion of pressure decreased. For the effect of humidity, the more it contained water, the more decreased the ignition energy of dust was, so increased minimum explosive concentration, and effective water content was minimum 10% or more. Inactive substance additive was effective in adding more than 15% CaCO3 and CaO as substance inhibiting dust explosion, in which CaCO3 was more effective than CaO. the analysis of the flame of dust explosion was performed by high-speed video camera, it showed the size of flame bacame smaller in order that sub feed, main feed, wheat powder. As a result, sub feed was expected to be less dangerous than others.

Removal of RDX using Lab-scale Plug Flow Constructed Wetlands Planted with Miscanthus sacchariflorus (Maxim.) Benth (물억새를 식재한 플러그 흐름 습지에서의 RDX 제거동역학)

  • Lee, Ahreum;Kim, Bumjoon;Park, Jieun;Bae, Bumhan
    • Journal of Soil and Groundwater Environment
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    • v.20 no.6
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    • pp.85-94
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    • 2015
  • RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) is the most important explosive contaminant, both in concentration and in frequency, at military shooting ranges in which green technologies such as phytoremediation or constructed wetlands are the best option for mitigation of explosive compounds discharge to the environment. A study was conducted with two identical lab-scale plug flow constructed wetlands planted with Amur silver grass to treat water artificially contaminated with 40 mg/L of toxic explosive compound, RDX. The reactor was inoculated with or without RDX degrading mixed culture to evaluate plant-microorganism interactions in RDX removal, transformation products distribution, and kinetic constants. RDX and its metabolites in water, plant, and sediment were analyzed by HPLC to determine mass balance and kinetic constants. After 30 days of operation, the reactor reached steady-state at which more than 99% of RDX was removed with or without the mixed culture inoculation. The major transformation product was TNX (Trinitroso-RDX) that comprised approximately 50% in the mass balance of both reactors. It was also the major compound in the plant root and shoot system. Acute toxicity analysis of the water samples showed more than 30% of toxicity reduction in the effluent than that of influent containing 40 mg/L of RDX. In the Amur silver grass mesocosm seeded with the mixed culture, the specific RDX removal rate, that is 1st order removal rate normalized to plant fresh weight, was estimated to be 0.84 kg−1 day−1 which is 16.7% higher than that in the planted only mesocosm. Therefore, the results of this study proved that Amur silver grass is an effective plant for RDX removal in constructed wetlands and the efficiency can be increased even more when applied with RDX degrading microbial consortia.