• Applied Chemistry for Engineering
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• v.22 no.4
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• pp.416-422
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• 2011

In this study, the effect of cosurfactant on the phase equilibrium and dynamic behavior was studied in systems containing NP7 nonionic surfactant solutions and nonpolar hydrocarbon oils. All cosurfactants used during this study such as n-pentanol, n-octanol and n-decanol acted as a hydrophobic additive and thus promoted the transition from an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with an excess oil phase to a three-phase region containing excess water, excess oil, and a middle-phase microemulsion and further to a water in oil (W/O) ${\mu}E$ in equilibrium with the excess water phase. The transition temperature was found to decrease with both increases in the chain length and amount of addition of a cosurfactant. Dynamic behavior studies under O/W ${\mu}E$ conditions showed that an oil drop size decreased with time due to the solubilization into micelles. On the other hand, both the spontaneous emulsification of water into the oil phase and the expansion of oil drop were observed under W/O ${\mu}E$ conditions because of the diffusion of surfactant and water into the oil phase. Under conditions of a three-phase region including a middle-phase ${\mu}E$, both the rapid solubilization and emulsification of the oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Dynamic interfacial tension measurements have been found to be in a good agreement with dynamic behavior results.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.473-478
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• 2009

Phase equilibrium and dynamic behavior studies were performed on systems containing $C_{10}E_5$ nonionic surfactant solutions and nonpolar hydrocarbon oils. The phase behavior showed an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with excess oil phase at low temperatures and a water in oil (W/O) ${\mu}E$ in equilibrium with excess water phase at high temperatures. For intermediate temperatures a three-phase region containing excess water, excess oil, and a middle-phase microemulsion was observed and the transition temperature was found to increase with an increase in the chain length of a hydrocarbon oil. Dynamic behavior at low temperatures showed that an oil drop size decreased linearly with time due to solubilization into micelles and the solubilization rate decreased with an increase in the chain length of a hydrocarbon oil. On the other hand, both spontaneous emulsification of water into oil phase and expansion of oil drop were observed because of diffusion of surfactant and water into oil phase. Under conditions of a 3 phase region including a middle-phase ${\mu}E$, both rapid solubilization and emulsification of oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Interfacial tensions were measured as a function of time for n-decane oil drops brought into contact with 1 wt% surfactant solution at $25^{\circ}C$. Both equilibrium interfacial tension and equilibration time increased with an increase in the chain length of a hydrocarbon oil.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.10 no.1
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• pp.13-19
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• 2012

The long-lived fission products $^{79}Se$ and $^{99}Tc$ have been considered as the major concern nuclides for the disposal of radioactive waste because of their high solubilities and the existence of anionic species in natural water. In this study, the solubilities of $FeSe_2(s)$ and $TcO_2(s)$, known as respective Solubility Limiting Solid Phase (SLSP) of selenium and technetium, were measured in the KURT (KAERI Underground Research Tunnel) groundwater under various pH and redox conditions. And their solubilities and major species were also calculated using geochemical codes under conditions similar to experimental solutions. Experimental results and calculation for $FeSe_2$ show that the solubility of selenium was found to be below $1{\times}10^{-6}mol/L$ under the condition of pH 8~9.5 and Eh=-0.3~-0.4 V while the dominant species was identified as $HSe^-$. For $TcO_2$, the solubility of technetium was found to be $5{\times}10^{-8}{\sim}1{\times}10^{-9}mol/L$ in the solutions of pH 6~9.5 and Eh<-0.1 V, while the dominant species was $TcO(OH)_2$. However, when the Eh of the solution is -0.35 V, $TcO(OH)_3^-$ and $TcO_4^-$ are calculated as the dominant species at pH 10.5~12 and pH>12, respectively.

• 지역과문화
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• v.7 no.2
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• pp.85-111
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• 2020

In Korea, the independent publication market has grown since it came into existence in the 1990s. In 2008, the country's first independent bookstores selling independent publications opened. As of late 2019, there were a total of 466 independent bookstores in Korea and the number of independent bookstores rapidly increased for the last decade. However, the closing rate of independent bookstores is rapidly increasing. This trend is also shown in independent bookstores in Gwangju. Recently, the closing rate of independent bookstores in Gwangju is more than twice as high as the national average. Against this backdrop, this study intended to identify the current conditions of independent bookstores in the city, analyze the problems facing them, and find solutions. Independent bookstores in Gwangju currently make various efforts such as book curation, management of various supplementary programs, and book markets. However, the bookstores have problems including the curation and programs focused on specific areas, focus on limited generations, dependence on publications from the Seoul metropolitan area. To address these problems, this study proposed solutions such as diversifying publications through planning and developing of local contents, strengthening the taste-based salon nature, organizing networks of independent bookstores, and systematically incubating independent bookstores. At the system level, this study also suggested a need for local bookstore certification system, a complete execution of a fixed book price system, and a fair provision rate.

• Journal of the Korean Mathematical Society
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• v.48 no.4
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• pp.669-689
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• 2011

The notion of quasi-Einstein manifolds arose during the study of exact solutions of the Einstein field equations as well as during considerations of quasi-umbilical hypersurfaces. For instance, the Robertson-Walker spacetimes are quasi-Einstein manifolds. The object of the present paper is to study Lorentzian quasi-Einstein manifolds. Some basic geometric properties of such a manifold are obtained. The applications of Lorentzian quasi-Einstein manifolds to the general relativity and cosmology are investigated. Theories of gravitational collapse and models of Supernova explosions [5] are based on a relativistic fluid model for the star. In the theories of galaxy formation, relativistic fluid models have been used in order to describe the evolution of perturbations of the baryon and radiation components of the cosmic medium [32]. Theories of the structure and stability of neutron stars assume that the medium can be treated as a relativistic perfectly conducting magneto fluid. Theories of relativistic stars (which would be models for supermassive stars) are also based on relativistic fluid models. The problem of accretion onto a neutron star or a black hole is usually set in the framework of relativistic fluid models. Among others it is shown that a quasi-Einstein spacetime represents perfect fluid spacetime model in cosmology and consequently such a spacetime determines the final phase in the evolution of the universe. Finally the existence of such manifolds is ensured by several examples constructed from various well known geometric structures.

• Advances in nano research
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• v.8 no.3
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• pp.215-228
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• 2020

In this paper, a new method based on the Sander theory is developed for SWCNTs to predict the vibrational behavior of length and ratio of thickness-to-radius according to various end conditions. The motion equation for this system is developed using Rayleigh-Ritz's method. The proposed model shows the vibration frequencies of armchair (5, 5), (7, 7), (9, 9), zigzag (12, 0), (14, 0), (19, 0) and chiral (8, 3), (10, 2), (14, 5) under different support conditions namely; SS-SS, C-F, C-C, and C-SS. The solutions of frequency equations have been given for different boundary condition, which have been given in several graphs. Several parameters of nanotubes with characteristic frequencies are given and vary continuously in length and ratio of thickness-to-radius. It has been illustrated that an enhancing the length of SWCNTs results in decreasing of the frequency range. It was demonstrated by increasing of the height-to-radius ratio of CNTs, the fundamental natural frequency would increase. Moreover, effects of length and ratio of height-to-radius with different boundary conditions have been investigated in detail. It was found that the fundamental frequencies of C-F are always lower than that of other conditions, respectively. In addition, the existence of boundary conditions has a significant impact on the vibration of SWCNTs. To generate the fundamental natural frequencies of SWCNTs, computer software MATLAB engaged. The numerical results are validated with existing open text. Since the percentage of error is negligible, the model has been concluded as valid.

• Korean Journal of Chemical Engineering
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• v.35 no.12
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• pp.2442-2451
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• 2018

Novel highly active visible-light photocatalysts in the form of zinc bismuth oxide ($ZnBi_2O_4$) and graphite hybrid composites were prepared by coupling via a co-precipitation method followed by calcination at $450^{\circ}C$. The asprepared $ZnBi_2O_4$-graphite hybrid composites were tested for the degradation of rhodamine B (RhB) solutions under visible-light irradiation. The existence of strong electronic coupling between the two components within the $ZnBi_2O_4$-graphite heterostructure suppressed the photogenerated recombination of electrons and holes to a remarkable extent. The prepared composite exhibited excellent photocatalytic activity, leading to more than 93% of RhB degradation at an initial concentration of $50mg{\cdot}L^{-1}$ with 1.0 g catalyst per liter in 150 min. The excellent visible-light photocatalytic mineralization of $ZnBi_2O_4-1.0graphite$ in comparison with pristine $ZnBi_2O_4$ could be attributed to synergetic effects, charge transfer between $ZnBi_2O_4$ and graphite, and the separation efficiency of the photogenerated electrons and holes. The photo-induced $h^+$ and the superoxide anion were the major active species responsible for the photodegradation process. The results demonstrate the feasibility of $ZnBi_2O_4-1.0graphite$ as a potential heterogeneous photocatalyst for environmental remediation.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.10
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• pp.894-898
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• 2016

Solution plasma is a unique method which provides a direct discharge in solutions. It is one of the promising techniques for various applications including the synthesis of metallic/non-metallic nanomaterials, decomposition of organic compounds, and the removal of microorganism. In the context of nanomaterial syntheses, solution plasma has been utilized to produce carbon nanoparticles and metallic-carbon nanoparticle systems. The main purpose of this study was to synthesize nickel nanoparticles embedded in a matrix of carbon particles by solution plasma in one-step using waste vegetable oil as the carbon source. The experimental setup was done by simply connecting a bipolar pulsed power generator to nickel electrodes, which were submerged in the waste vegetable oil. Black powders of the nickel nanoparticles-embedded carbon (NiNPs/Carbon) particles were successfully obtained after discharging for 90 min. The morphology of the synthesized NiNPs/Carbon was investigated by a scanning electron microscope, which revealed a good dispersion of NiNPs in the carbon-particle matrix. The X-ray diffraction of NiNPs/Carbon clearly showed the co-existence of crystalline Ni nanostructures and amorphous carbon. The crystallite size of NiNPs (through the Ni (111) diffraction plane), as calculated by the Scherrer equation was found to be 64 nm. In addition, the catalytic activity of NiNPs/Carbon was evaluated by cyclic voltammetry in an acid solution. It was found that NiNPs/Carbon did not show a significant catalytic activity in the acid solution. Although this work might not be helpful in enhancing the activity of the fuel cell catalysts, it is expected to find application in other processes such as the CO conversion (by oxidation) and cyclization of organic compounds.

• Geomechanics and Engineering
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• v.15 no.2
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• pp.793-803
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• 2018

Based on the theory of porous media, an interaction system of a floating pile and a saturated soil in cylindrical coordinates subjected to vertical harmonic load is presented in this paper. The surrounding soil is separated into two distinct layers. The upper soil layer above the level of pile base is described as a saturated viscoelastic medium and the lower soil layer is idealized as equivalent spring-dashpot elements with complex stiffness. Considering the cylindrically symmetry and the pile-soil compatibility condition of the interaction system, a frequency-domain analytical solution for dynamic impedance of the floating pile embedded in saturated viscoelastic soil is also derived, and reduced to verify it with existing solutions. An extensive parametric analysis has been conducted to reveal the effects of the impedance of the lower soil base, the interaction coefficient and the damping coefficient of the saturated viscoelastic soil layer on the vertical vibration of the pile-soil interaction system. It is shown that the vertical dynamic impedance of the floating pile significantly depends on the real stiffness of the impedance of the lower soil base, but is less sensitive to its dynamic damping variation; the behavior of the pile in poro-visco-elastic soils is totally different with that in single-phase elastic soils due to the existence of pore liquid; the effect of the interaction coefficient of solid and liquid on the pile-soil system is limited.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.43 no.3
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• pp.21-28
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• 2020

Aftermarket refers to a market in which a company sells complementary goods, replacements of parts, and upgrade or maintenance services to consumers after selling them main durable goods. Intuitively, consumers who purchase main durable goods become major potential customers in subsequent aftermarket. Thus the existence of the aftermarket has a significant impact on pricing of the main durable goods as well as the aftermarket products. In this study, we analyze the effect of aftermarket on the pricing strategy for a company selling both main durable goods and aftermarket products. To do this we first divided the market into markets where the aftermarket products are indispensable and optional. Based on the proposed market types, the profit maximizing solutions are derived using two-period model, and the impacts of consumers' undervaluation of aftermarket product prices on pricing strategy are analyzed. The results can be summarized as follows : (1) Regardless of the market type, the total profits were found to be inversely proportional to the consumer's awareness accuracy of product prices in the aftermarket. This is in line with marketing efforts that sales companies have made intuitively to make consumers underestimate the cost of the aftermarket. (2) If aftermarket product is indispensable, only revenue from the aftermarket is sought. On the other hand, if aftermarket product is optional, revenue from the main durable good as well as the aftermarket product will be sought simultaneously. (3) Moreover, when aftermarket product is optional, the lower the awareness accuracy of consumers, the higher the price and profit of the main durable goods, while the lower the price and profit of the aftermarket products. This is contrary to the intuition that the lower the consumer's valuation of the costs of aftermarket, the more advantageous it would be to rely on aftermarket products rather than on main durable goods.