• 제목/요약/키워드: exfoliation

검색결과 393건 처리시간 0.026초

Alveolar bone necrosis and spontaneous tooth exfoliation associated with trigeminal herpes zoster: a report of three cases

  • Kim, Nam-Kyoo;Kim, Bong-Chul;Nam, Jung-Woo;Kim, Hyung-Jun
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • 제38권3호
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    • pp.177-183
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    • 2012
  • Herpes zoster is a viral infection caused by the reactivation of the varicella zoster virus, an infection most commonly affecting the thoracolumbar trunk. Herpes Zoster Infection (HZI) may affect the cranial nerves, most frequently the trigeminal. HZI of the trigeminal nerve distribution network manifests as multiple, painful vesicular eruptions of the skin and mucosa which are innervated by the infected nerves. Oral vesicles usually appear after the skin manifestations. The vesicles rupture and coalesce, leaving mucosal erosions without subsequent scarring in most cases. The worst complication of HZI is post-herpetic neuralgia; other complications include facial scarring, motor nerve palsy and optic neuropathy. Osteonecrosis with spontaneous exfoliation of the teeth is an uncommon complication associated with HZI of the trigeminal nerve. We report several cases of osteomyelitis appearing on the mandible, caused by HZI, and triggering osteonecrosis or spontaneous tooth exfoliation.

Solution-Processed Two-Dimensional Materials for Scalable Production of Photodetector Arrays

  • Rhee, Dongjoon;Kim, Jihyun;Kang, Joohoon
    • 센서학회지
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    • 제31권4호
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    • pp.228-237
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    • 2022
  • Two-dimensional (2D) nanomaterials have demonstrated the potential to replace silicon and compound semiconductors that are conventionally used in photodetectors. These materials are ultrathin and have superior electrical and optoelectronic properties as well as mechanical flexibility. Consequently, they are particularly advantageous for fabricating high-performance photodetectors that can be used for wearable device applications and Internet of Things technology. Although prototype photodetectors based on single microflakes of 2D materials have demonstrated excellent photoresponsivity across the entire optical spectrum, their practical applications are limited due to the difficulties in scaling up the synthesis process while maintaining the optoelectronic performance. In this review, we discuss facile methods to mass-produce 2D material-based photodetectors based on the exfoliation of van der Waals crystals into nanosheet dispersions. We first introduce the liquid-phase exfoliation process, which has been widely investigated for the scalable fabrication of photodetectors. Solution processing techniques to assemble 2D nanosheets into thin films and the optoelectronic performance of the fabricated devices are also presented. We conclude by discussing the limitations associated with liquid-phase exfoliation and the recent advances made due to the development of the electrochemical exfoliation process with molecular intercalants.

층간삽입 반응을 이용한 그래핀/탄소나노튜브 동시 개별 분산 및 전도성 복합 필름으로의 응용 (Simultaneous Exfoliation and Dispersion of Graphene/Carbon Nanotube via Intercalation Reaction and Its Application as Conductive Composite Film)

  • 김정모;김진;윤혜원;박민수;;;이진호;전석우
    • Composites Research
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    • 제29권3호
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    • pp.104-110
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    • 2016
  • 본 논문은 층간 삽입 반응을 이용하여 그래핀을 박리하는 동시에 탄소나노튜브를 개별 분산시키고 이를 복합 필름으로 제조한 결과를 보고한다. 일반적으로 그래핀과 탄소나노튜브의 경우 흑연과 탄소나노튜브 번들로부터의 개별적 박리를 통해 제조될 수 있으나 장시간의 공정 시간을 요구하게 된다. 본 연구에서는 그래핀과 탄소나노튜브의 동시 박리 및 분산을 위해 흑연 및 탄소나노튜브 번들 내로 포타슘 소듐 타르트레이트를 삽입했으며 XRD 분석을 통해 흑연 층간 거리 및 탄소나노노튜브 번들 내 거리의 증가를 확인했다. 제조된 층간삽입화합물로부터 박리된 그래핀 및 탄소나노튜브의 경우 매우 낮은 산화도(< 8.3 at%)를 나타냈으며 제조된 물질을 여과 장치 및 스프레이 전사를 통해 복합 필름으로 제조한 결과 그래핀 및 탄소나노튜브의 단일 필름에 대비하여 복합 필름의 경우 전도성의 향상을 보였다.

식용작물을 이용한 전복 박리 (Exfoliation of abalone, Haliotis discus hannai using edible plants)

  • 김위식;김종오;오명주
    • 한국어병학회지
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    • 제30권1호
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    • pp.63-66
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    • 2017
  • 본 연구에서는 29종의 식용작물을 이용하여 전복박리 효과를 조사한 결과, 스피아민트, 레몬밤, 로즈플라워, 양파, 와사비분, 겨자분, 오미자 및 히비스커스 용액에서 박리효과가 관찰되었다. 특히, 오미자와 히비스커스 용액에서는 90% 이상의 박리율이 관찰되었다. 양식장에서 사육중인 전복을 대상으로 오미자 및 히비스커스 용액을 사용하여 전복 박리 및 회복 효과를 조사한 결과, 3%와 4%의 오미자 용액에 노출된 전복은 각각 93.6% (850/908)와 97.1% (810/834)의 박리율을 보였으며 1분 15초 이내에 회복되었다. 3%와 4%의 히비스커스 용액에서는 각각 96.1% (780/812)와 97.4%(700/719)의 박리율을 보였고, 박리된 전복은 1분 39초 이내에 회복되었다. 이상의 결과, 오미자와 히비스커스 용액은 양식현장에서 전복을 박리하는데 실용적으로 사용 가능할 것으로 사료된다.

Organoclay로 보강된 NR/BR Blends의 기계적 특성 (Mechanical Properties of Organoclay filled NR/BR Blends)

  • 김원호;김상균;김상권;정경훈;변지영
    • Elastomers and Composites
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    • 제39권1호
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    • pp.51-60
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    • 2004
  • 본 연구에서는 organoclay를 혼합한 NR/BR blend의 가황특성, 동적점탄성 및 기계적 물성을 carbon black 및 silica를 함유한 배합고무와 비교 평가하였다. Solution 혼합법을 이용함으로써 광범위한 나노 복합체를 제조할 수 있었으며, 충전제의 함량은 10phr로 고정하였다. XRD 실험으로 clay의 삽입 및 박리정도를 측정하였다. 통상적인 혼합법을 이용할 경우 clay의 박리 또는 삽입정도가 미약한 반면 solution 혼합법을 이용할 경우 광범위한 박리형태의 clay 배합고무를 얻을 수 있음을 확인하였다. Clay 배합고무는 carbon black 및 silica를 함유한 배합고무에 비해 높은 tan ${\delta}$값을 나타내며, solution 혼합법을 이용할 경우 통상적인 혼합법에 의해 제조된 clay 배합고무에 비해 우수한 기계적 물성을 가짐을 확인할 수 있었다.

심지에 관한 연구(I) -접착심지의 polyethylene 수지량에 따른 물성변화- (Studies on Interlining -The change of the physical properties based on the weight polyethylene resin of the fusible interlining-)

  • 조경애;유덕환
    • 한국의류학회지
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    • 제6권1호
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    • pp.17-26
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    • 1982
  • This article aims to determine the interrelation among exfoliation strength, the repeated laundry number, the coefficient of friction and the cover factor about the fusible interlining produced by using different amount resin. The practicality of stiffness and warmth of the fusible interling were examined. The results are summarized as follows: 1) As a factor that affecting the exfoliation strength of fusible interlining, the coefficient of friction and the cover factor about the fusible interlining produced by using different amount resin. (2) Regardless of the weight of the resin, the exfoliation strength of fusible interlining declined gradually as the repeated laundry number increased. This tendency arises much more in the case of the filament yarn fabric than in that of the spun yarn fabric. The stability of the exfoliation strength was better, regardless of the increase of the repeated laundry number, when the weight of the weight of the resin was 10 g/$m^2$. (3) The spun yarn fabric, which has more fuzz than the filament yarn fabric, is more suitable for the fabric of fusible interlining. The smaller the cover factor difference between the face cloth and the interlining cloth, the stronger the exfoliation strength. (4) When the stability of the shape is a necessary factor in the consumption of the fusible interlining, a resin weight of 20 g/$m^2$ is the most suitable; however when stiffness and warmth are necessary factors, a resin weight of 10 g/$m^2$ is the most suitable.

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플래즈머용사에 의한 세라믹 코팅 강재의 음향방출 특성 (Acoustic Emission Characteristics of Ceramic Coated Steel by Plasma Spraying)

  • 김귀식
    • 동력기계공학회지
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    • 제2권3호
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    • pp.49-54
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    • 1998
  • This paper is investigated of hardness and adhesiveness of plasma sprayed coating steels by AE(Acoustic Emission) testing when loading a tensile. AE Parameters used are Event, Count, Energy and Amplitude. Test specimens are carbon steel(S45C) with sprayed coating layers of Ni-4.5wt.%Al(bond coating) and $TiO_2$(top coating), and carry out heat treatment at $800^{\circ}C\;and\;1000^{\circ}C$, respectively. The micro-hardness of the heat treatment specimen have been improved more than that of non-heat treatment. On the tensile test, the process and occurence of the exfoliation of the sprayed coating layer can be estimated by AE Characteristics of AE parameters, such as event, count, amplitude and energy, on the layer exfoliation are shown the similar aspects. The exfoliation of bond coating occure at about 20% of strain and top coating is about 5% of strain.

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광전기화학 셀 적용을 목적으로 하는 화학적 박리법을 통한 그래핀의 제조 (Preparation of graphene by chemical exfoliation for application to the photoelectrochemical cell)

  • 윤상혁;이대원;김교선
    • 산업기술연구
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    • 제35권
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    • pp.59-65
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    • 2015
  • As the fossil fuels are depleted nowadays, development of alternative energies is absolutely required in the world. Efficient production of hydrogen by water-splitting using solar energy can be one of the methods to solve the global energy and environmental problems. But this method has a problem of low conversion efficiency. The application of graphene can be one method to help increase the conversion efficiency. For this reason, mass production of high quality graphene is required. In this study, we prepared graphene using the chemical exfoliation method. We applied the Hummer's method and Tour's method to oxidize the graphite and could get the different Graphene Oxide(GO) from different process conditions. We also tried to convert the GO to graphene by thermal reduction and could remove functional group of GO effectively. The control of oxidation conditions was quite important to obtain the high quality graphene.

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Changing the sp2 Carbon Clusters in Graphene Oxide During Exfoliation

  • Ahn, Sung Il
    • Transactions on Electrical and Electronic Materials
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    • 제16권1호
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    • pp.49-52
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    • 2015
  • The change of the chemical structure of graphene oxide (GO) was investigated by periodical sampling of GO during exfoliation by using a sonicator. A significant amount of GO was exfoliated during up to 10 hr of sonication. Raman and Fourier transform infrared spectroscopy revealed a continuous increase of the G/D or C=C/C=O peak ratio of GO, as the sonication time increases. The photoluminescence (PL) intensity of each GO sample also decreased as a function of the sonication time. PL excitation spectra with three major peaks indicate that the sizes of $sp^2$ carbon clusters were enlarged by longer sonication. In addition, new excitation at around 300 nm proves the existence of newly developed small clusters of $sp^2$ carbons as the sonication time increased.

Effect of Matrix Viscosity on Clay Dispersion in Preparation of Polymer/Organoclay Nanocomposites

  • Ko, Moon-Bae;Jho, Jae-Young;Jo, Won-Ho;Lee, Moo-Sung
    • Fibers and Polymers
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    • 제3권3호
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    • pp.103-108
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    • 2002
  • The viscosity effect of matrix polymer on melt exfoliation behavior of an organoclay in poly($\varepsilon$-caprolactone) (PCL) was investigated. The viscosity of matrix polymer was controlled by changing the molecular weight of poly($\varepsilon$-eaprolactone), the processing temperature, and the rotor speed of a mini-molder. Applied shear stress facilitates the diffusion of polymer chains into the gallery of silicate layers by breaking silicate agglomerates down into smaller primary particles. When the viscosity of PCL is lower, silicate agglomerates are not perfectly broken into smaller primary particles. At higher viscosity, all of silicate agglomerates are broken down into primary particles, and finally into smaller nano-scale building blocks. It was also found that the degree of exfoliation of silicate layers is dependent upon not only the viscosity of matrix but thermodynamic variables.