• Title/Summary/Keyword: ethylene vinyl-acetate copolymer

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Foaming Characteristics of Ethylene Vinyl Acetate/Styrene Vinyl Isoprene Styrene Triblock Copolymer Blend (Ethylene Vinyl Acetate / Styrene Vinyl Isoprene Styrene Triblock Copolymer 블렌드의 발포특성)

  • Heo, Jae-Young;Kim, Jin-Tae;Yoon, Jung-Sik;Yoo, Jong-Sun;Kim, Won-Ho
    • Elastomers and Composites
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    • v.35 no.2
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    • pp.106-114
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    • 2000
  • The foam of ethylene vinyl acetate (EVA)/styrene-vinyl isoprene-styrene triblock copolymer(SVIS) blend was prepared to improve the shock-absorption and compression set characteristics at room temperature. The effects of blowing agent and blend ratio of EVA/SVIS on expansion ratio, cell structure and mechanical properties of the foam were investigated. As the SVIS content increased, the viscosity of blends was increased but the crosslinking rate was slow down, the expansion ratio was decreased. and the specific gravity was increased. At room temperature, the resilience was not affected by increasing the amount of blowing agent. The value of tan ${\delta}$ was increased by increasing the amount of SVIS. As a result, the value of compression set was decreased. This is due to the increased values of specific gravity and crosslinking density of the EVA/SVIS foam.

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Development of functional microsphere (I) - Formation and characteristics of poly(ethylene-co-vinyl acetate) microspheres via thermally induced phase separation - (기능성 마이크로스피어의 개발 (I) - 열유도 상분리에 의한 Poly(ethylene-co-vinyl acetate) 마이크로스피어의 제조와 특성 -)

  • 이신희;김효정;박수민
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.57-64
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    • 2003
  • Poly(ethylene-co-vinyl acetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluent used was toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by SEM observation and particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, and the cooling rate of EVA copolymer solution was lower.

Preparation and Properties of Ethylene Vinyl Acetate/Ethylene-1-Butene Copolymer Blend Based Foam (Ethylene Vinyl Acetate / Ethylene-1-Butene Copolymer 블렌드 발포체의 제조와 특성)

  • Cha, Gil-Soo;Kim, Jin-Tae;Yoon, Jung-Sik;Kim, Won-Ho
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.14-21
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    • 2001
  • To increase the properties of EVA foam such as tensile strength, rebound resilience, and compression set, ethylene-1-butene copolymer (EtBC) was blended with EVA. After that crosslink characteristics of the blends and cell structures and mechanical properties of the foam were studied. As the amount of EtBC increased in EVA/EtBC blends, torque values of oscillating disc rheometer(ODR) increased and the foaming ratio decreased because the viscosity and crosslink density of EVA/EtBC blends increased. Foaming ratio and cell size of the foam increased by increasing the amount of foaming agent. When compared the mechanical properties of the foam which have same densities, tensile strength, rebound resilience, and compression set properties of the foam were improved by increasing the amount of EtBC in the EVA/EtBC blends.

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A Study on the Dyeing Property of EVA Blended Polypropylene Fiber (EVA로 Blending된 Polypropylene Fiber의 염색성에 관한 연구)

  • 장철민;임상규;김삼수;손태원;서말용
    • Textile Coloration and Finishing
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    • v.10 no.5
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    • pp.13-18
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    • 1998
  • Polypropylene-ethylene/vinyl acetate copolymer (PP-EVA) blends were prepared by mechanical blending using relatively semi-crystaline ethylene-vinyl acetate copolymer and polypropylene. In order to obtain dyeable PP fiber, PP-EVA blends were prepared using below 10wt.% of EVA and formed a filament by the melt spinning method. The resultant fibers had tensile strengh of 2∼3g/d, elongation of 330∼600%, initial modulus of 22∼46g/d, and exhibited markedly improved dyeing property.

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Properties of the Blends of Ethylene-Vinyl Acetate and Ethylene-$\alpha$-Olefins Copolymers

  • Park Soochul;Yim Chaiseok;Lee Byung H.;Choe Soonja
    • Macromolecular Research
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    • v.13 no.3
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    • pp.243-252
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    • 2005
  • The effect of the vinyl acetate (VA) content on the thermal, viscoelastic, rheological, morphological and mechanical behaviors in various blends of ethylene-vinyl acetate (EVA)/ethylene-$\alpha$-olefin copolymers was investigated using 28, 22 and $15 mol\%$ of VA in EVA. In the DSC melting and crystallization thermograms of all of the EVA systems blended with ethylene-$\alpha$-olefin copolymers, discrete peaks were observed which were related to the constituents. In the dynamic mechanical thermal analysis, the storage modulus increased with increasing content of ethylene-$\alpha$-olefin copolymers. In addition, the transition regions relating to the tan bpeaks varied with the VA content. The crossover point between G' and G" varied depending on the VA contents, and shear-thinning was more prominent in the EVA/EtBC system. In the SEM investigation, a discrete phase morphology was observed in both the EVA/EtBC and EVA/EtOC blends, but the contrast improved with decreasing VA content. However, the tensile strength and modulus improved, but the elongation at break reduced with decreasing VA content, implying that the ethylene-$\alpha$-olefin copolymers play the role of reinforcing materials. Thus, the EVA and ethylene-$\alpha$-olefin components in the copolymers are immiscible in the molten and solid states, but are nevertheless mechanically compatible.

Foaming Characteristics and Physical Properties of Ethylene Vinyl Acetate Copolymer Foams (Ethylene Vinyl Acetate Copolymer 발포체의 발포특성 및 물리적 특성)

  • Kim, Jin-Tae;Son, Woo-Jung;Ahn, Byung-Hyun;Kim, Won-Ho
    • Elastomers and Composites
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    • v.36 no.1
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    • pp.52-60
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    • 2001
  • Physical properties of foams depend on the density of foams, Physical properties of base polymers, open ceil contents, and cell structures including the size, size distribution, shape of ceil and the thickness of membrane and strut. The density of foam is affected by raw materials, concentration oi crosslinking agent and blowing agent and process parameters such as processing technique and condition. Ethylene vinyl acetate copolymer(EVA) foam is a crosslinked cellular material. The foaming characteristics and physical properties of EVA foam are affected by decomposition rate of blowing agent. In this study, the decomposition rate of blowing agent and crosslinking rate, foaming characteristics and physical properties of foams were evaluated. The slow decomposition rate of blowing agent results in low density foam, good shock absorption property and uniform cell size distribution compared to the high decomposition rate of blowing agent.

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Transdermal Delivery of Ethinylestradiol UsingEthylene-vinyl Acetate Membrane

  • Shin, Sang-Chul;Byun, Soo-Young
    • Journal of Pharmaceutical Investigation
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    • v.25 no.3
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    • pp.53-59
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    • 1995
  • Ethinylestradiol (EE)-containing matrix was fabricated with ethylene-vinyl acetate(EVA) copolymer to control the release of the drug, Effect of addition of PEG 400 as receptor solution, the stripping of skin and Azone pretreatment on skin on the permeation of EE through the excised mouse skin was also studied. The permeation rate of EE through the excised mouse skin was affected by the PEG 400 volume fraction. The Azone pretreatment on skin didn't affect on the steady state flux, however, the lag time was shortened. The permeation rate of EE through the stripped skin was much larger than that through the whole skin. It showed that the stratum corneum acts as a barrier of skin permeation. The fact that there is little difference in EE permeation between the intact skin and the stripped skin with EVA membrane shows the permeation of EE through the mouse skin is mainly controlled by the membrane.

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Microbial Inhibition and Migration of Nisin-incorporated Antimicrobial Polymer Coating on Paperboard

  • Kim, Young-Min;Lee, Dong-Sun
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.16 no.1
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    • pp.5-7
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    • 2010
  • Two kinds of polymer coating (acrylic polymer and vinyl acetate ethylene copolymer) added with 5% nisin were fabricated on the paperboards and tested in their antimicrobial activity against Micrococcus flavus ATCC 10240 inoculated into water contacting the coating at $10^{\circ}C$. Vinyl acetate ethylene copolymer giving faster and higher nisin migration presented the greater reduction in the microbial count than the other coating, which endorsed that the migrated nisin is mainly responsible for the microbial inhibition or destruction. There was also a slight effect of the coating polymer itself in the microbial inhibition.

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