• Title/Summary/Keyword: ethylene propylene diene ethylene

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Thermal, Curing, Elastic, and Mechanical Properties of Ethylene Propylene Diene Monomer/Polybutadiene/Carbon Black Composites

  • Tae-Hee Lee;Keon-Soo Jang
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.142-151
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    • 2023
  • In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.

Studies on Incombustibility Improvement of EPDM Rubber with $Al(OH)_3$ and $Sb_2O_3$ ($Al(OH)_3$$Sb_2O_3$의 첨가에 따른 EPDM계 고무의 난연성 향상 연구)

  • Kim, Jin-Yong;Lee, Won-Bok;Lim, Dae-Hyun;Suh, Hyuk;Rhee, Young-Woo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.449-452
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    • 2009
  • In order to improve incombustibility of EPDM(Ethylene propylene diene monomer)-based rubber, inorganic materials as $Al(OH)_3$ and $Sb_2O_3$ were added. The mechanical and thermal properties have been measured for vulcanized rubber loaded with different concentrations of $Al(OH)_3$ and $Sb_2O_3$. As inorganic material contents increases from 5phr to 30phr, the specific gravity and hardness increase while elongation at break decreases. This study performed incombustibility test and thermal analysis through TGA(Thermogravimetric Analyzer). As a results, incombustible and thermal properties of EPDM-based rubber were improved as $Al(OH)_3$ and $Sb_2O_3$ contents increase.

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Cure Behavior, Compression Set and Dynamic Mechanical Properties of EPDM/NBR Blend Vulcanizates (EPDM/NBR 블렌드 가황체의 가교 거동, 영구 압축 줄음율 및 동적 기계적 성질)

  • 박찬영
    • Polymer(Korea)
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    • v.25 no.2
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    • pp.233-239
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    • 2001
  • The ethylene propylene diene terpolymer (EPDM) blends with acrylonitrile butadiene rubber (NBR) were prepared by mechanical mixing method. Mooney viscosity, cure behaviors, compression set and dynamic mechanical properties were subsequently examined. Dynamic characteristics of the entire blends determined from a Rheovibron generally showed two glass transitions (T'$_{g}$s), -43$^{\circ}C$ and -4$^{\circ}C$ for NBR and EPDM, respectively. The tan $\delta$ peak monotonically shifted toward the higher temperature with increasing NBR content. It was also found that the optimum cure time was significantly decreased with loading of NBR.

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A Study on the Ultraviolet Aging Characteristics of Outdoor Polymeric Insulating Materials (옥외용 고분자 절연재료의 자외선 열화특성 연구)

  • Kim, Yeong-Seong;Jeong, Sun-Ok
    • Korean Journal of Materials Research
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    • v.9 no.4
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    • pp.409-413
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    • 1999
  • Recently, the polymeric insulators have been accepted in several countries for the outdoor high voltage applications. In comparison with the conventional porcelain, polymeric insulators offer various advantages such as light weight, superior vandal resistance and better contamination performance. The outdoor polymeric insulating materials such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged such as silicone rubber, ethylene propylene diene monomer(EPDM), ethylene vinyl acetate(EVA) and epoxy are aged under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-under the various natural environment with the long-term performance in outdoor. In this paper, the effects of UV-ray on the surface of silicone rubber were investigated by using the weather-Ometer. The accelerated aging stresses were simulated by UV radiation, high temperature and humidity as well as water spray. These aging characteristics were examined through contact angle measurements, tracking resistance test, FT-IR and SEM/EDS analysis. The experimental results showed that tracking resistance decreases with increase in the UV-ray irradiation period. But the surface of silicone rubber kept hydrophobicity. It is found that the inorganic filler such as)$ Al(OH_3$ improves tracking resistance and the $Tio_2$is very effective in preventing degradation of silicone rubber surface from UV-ray.

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A Study on Composites of Ethylene-Vinyl Acetate Copolymer and Ethylene-Propylene-Diene Rubber with Aluminum Hydroxide as a Fire Retardant

  • Lee, Yu Jun;Lee, Su Bin;Jung, Jae Young;Lee, Dam Hee;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.51 no.2
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    • pp.93-98
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    • 2016
  • The composites of EVA/EPDM including aluminum trioxide (ATH) as a fire retardant were manufactured for the purpose of improving low temperature property and flame resistance in the rubbery materials. The ratio of EVA to EPDM didn't affect the flame resistance of the rubber composites. The addition of ATH resulted in increase of the flame resistance. In the evaluation of the cold resistance, the increasing EPDM content showed enhancement of cold resistance in the composites due to increasing low Tg EPDM. It was found out that tensile strengths of the composites showed a maximum value at 100 phr of ATH by reinforcing effect, but a minimum value at 200 phr of ATH owing to slippage between the flame retardant by the external stress. In the measurement of solvent resistance in tetrahydrofuran, the increasing ATH content yielded enhancement of solvent resistance by reducing swelling of the composite, and increasing EPDM content also resulted from increase of the solvent resistance by reduction of polarizability as well as increase of crosslink in the composites.

Influence of Partial Discharge Properties due to Void in Cable Joint Parts (케이블 접속재 부분방전 특성에 미치는 보이드의 영향)

  • 신종열;홍진웅
    • Journal of the Korean Society of Safety
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    • v.18 no.3
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    • pp.69-74
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    • 2003
  • To investigate the partial discharge and electric field distribution in cable joint parts, we measured the partial discharge and electric field in specimen. The specimens which cross-linked polyethylene(XLPE) and ethylene propylene diene ethylene(EPDM) are used to insulating material for underground cable md cable jointing parts. The polymers are used to insulating material in switchgear which is a kind of transformer equipment and in ultra-high voltage cable. Its using is increasing gradually, the electrical insulation properties are not only excellent but also mechanical property is excellent. And because it is possible to be made void of several type in insulator while it is produced, which the electrical field distribution is changed by void, it has a critical influence to insulator performance. The underground cable is connecting by the jointing material, insulating breakdown and the electric ageing which are caused by several mixing impurity and the damage of cable insulator layer, which reduced the life of cable while intermediate joint kit is connected. Therefore, the computer simulation is used to estimating insulator performance, XLPE is used to the insulating material of ultra-high voltage cable and EPDM is used to insulator layer in joint material kit, and which are produced as specimen. And it is analyzed the electric field concentrating distribution and partial discharge by modeling of computer simulation in void and cable joint kit.

The Study on the Properties of EPDM/NR Blends (EPDM/NR 블랜드의 물성에 관한 연구)

  • Go, Jin-Hwan;Park, Sung-Soo
    • Elastomers and Composites
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    • v.29 no.2
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    • pp.121-130
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    • 1994
  • The physical properties of rubber blend between natural rubber(NR) and ethylene propylene diene terpolymer(EPDM) were investigated as a study of EPDM composite materials. For EPDM/NR blends, the effects of ethylene and diene contents in EPDM, blend ratio, dicumyl peroxide(DCP) curing system on the physical properties, interfacial adhesion force and dynamic crack growth etc. were studied. EPDM/NR blends loaded with carbon black were prepared by mechanical mixing and cured by plate heating cure press. Crosslinking density was measured by swelling method with toluene. The physical properties of all blends were measured with Instron, fatigue to failure(FTF), Demattia flex cracking tester(DMFC), scanning electron microscopy (SEM), etc. As the ethylene and diene contents in EPDM increased, the physical properties, such as dynamic crack growth, adhesion to other component were increased too. Interfacial adhesion force of EPDM/NR blends to dissimilar layer was improved by the use of optimum peroxide curing system.

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Combustion Properties of Ethylene-propylene diene monomer/polypropylene/Clay Nanocomposites Based on EDPM/PP (EPDM/PP에 바탕을 둔 에칠렌-프로필렌 디엔 모노머/폴리프로필렌/클레이 나노복합체의 연소특성)

  • Chung, Yeong-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.4
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    • pp.410-417
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    • 2011
  • Effects of ethylene-propylene diene monomer (EPDM)/polypropylene (PP), zinc oxide, stearic acid, and clay on the combustive properties based on EDPM/PP were investigated. The EDPM/PP/clay nanocomposites was compounded to prepare specimen for combustive analysis by cone calorimeter (ISO 5660-1). It was found that the specific mass loss rate (SMLR) in the nanocomposites decreased due to the fire resistance compared with unfilled EDPM/PP, while the nanocomposites showed the higher total heat release (THR), higher CO production release, and higher specific extinction area (SEA) than those of virgin EPDM/PP. The stearic acid for softening ruber increased the THR and amount of smoke by itself, combustible.

Study on Manufacturing and Characteristics of Silicone/EPDM Rubber Blend (실리콘/EPDM고무 블렌드의 제조와 특성에 관한 연구)

  • 김진국;이형규
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.406-413
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    • 2001
  • Blending has become an interesting way for preparing new materials with tailored properties. Unfortunately, many materials are incompatible due to the difference in their viscoelastic properties, surface energy and interaction. Therefore, the properties of polymer blends are not obtained as expected levels. Silicone rubber has an excellent heat-resistance and electrical characteristics, and ethylene propylene diene monomer (EPDM) rubber also has good mechanical properties. The purpose of this study is to develop a new engineering material which has excellent electrical and mechanical properties through blending of silicone with EPDM rubber.

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Optimal Design for CLIP EPDM Rubber Products using a Flow Analysis

  • Huh, Young-Min;Lee, Kwang-O;Kang, Sung-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.7 no.4
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    • pp.23-27
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    • 2006
  • Rubber is used in many industrial products, such as hoses, rubber belts, and oil seals. In particular, more than 200 rubber parts are used in automobiles. The design technology of these parts is largely dependent on field experience, which leads to lengthy and expensive developing procedures. However, with the help of recent developments in nonlinear computer analysis, new rubber products can be developed at low cost. In this study, rubber injection molding design variables, such as location and number of gates, were optimized using computer-aided engineering with the cross-WLF equation to produce CLIP rubber products made from ethylene propylene diene monomer(EPDM). The validity of the proposed design was evaluated by comparison with actual forming results.