• Transactions of the Korean hydrogen and new energy society
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• v.13 no.1
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• pp.42-51
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• 2002

Methane can be converted directly to hydrogen by pyrolysis. The reaction is highly endothemic and heat must be supplied at high temperatures. Gibbs free energy minimization calculations have been carried out for the methane pyrolysis to determine equilibrium products. The calculation parameters are the temperature, the initial H/C ratio, the pressure and Gibbs energies of each substance. Methane, ethylene, acetylene, benzene, naphthalene, and hydrogen are the main products. Excluding hydrogen, it is observed that ethylene and aromatics(benzene+naphthalene) are predominant products below 1400K, whereas acetylene is significantly formed above 1400K. Hydrogen dilution increases the selectivities for ethylene and acetylene and decreases the selectivity for aromatics. Increasing the pressure also decreases the decomposition of methane.

• Textile Coloration and Finishing
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• v.3 no.2
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• pp.25-33
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• 1991

Poly(ethylene terephthalate)(PET) and nylon 6 films stretched uniaxially and biaxially were sputter etched in the presence of argon gas. The surface of the etched films was investigated using a scanning electron microscope(SEM). While cracks perpendicular to the stretched direction were observed in the uniaxil stretched films sputter etched for 30 min., many protrusions were formed in the biaxial stretched films at the height of 0.3-0.4 gm for PET and $0.1-0.2\mum$ for nylon 6. The tops of two or three protrusions merged etching time increased to 60 min. The contact angle to water of the sputter etched PET and nylon 6 films decreased steeply when etched for one to 3 min. In order to investigate chemical changes on the surface ESCA analysis was carried out. In both films sputter etched $C_{1s}$ intensity decreased and $O_{1s}$ intensity increased compared with the unetched ones.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.773-776
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• 2009

In this paper, new concept of the diesel fuel processing is introduced for the stable operation of solid oxide fuel cells (SOFCs). Heavier hydrocarbons than $CH_4$, such as ethylene, ethane, propane, and etc., induce the carbon deposition on anode of SOFCs. In the reformate of heavy hydrocarbons (diesel, gasoline, kerosene, and JP-8), concentration of ethylene is usually higher than low hydrocarbons such as ethane, propane, and butane. So, removal of low hydrocarbons (over C1-hydrocarbons), especially ethylene, at the reformate gases is important for stable operation of SOFCs. New methodology as named "post-reformer" is introduced for removing the low hydrocarbons at the reformate gas stream. Catalyst of the NECS-PR4 is selected for post-reforming catalyst because the catalyst of NECS-PR4 shows the high selectivity for removing low hydrocarbons and achieving the high reforming efficiency. The diesel reformer and post-reformer are continuously operated for about 200 hours as integrated mode. The reforming performance is not degraded and low hydrocarbons in the diesel reformate are completely removed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.05a
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• pp.771-774
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• 2000

RP techniques have inherent disadvantages caused by their working principles: stair-stepped surface of parts due to layer-by-layer stacking of layers, low build speed caused by line-by-line solidification to finish one layer, and post processing to improve surface finish, etc. The objective of this study is to propose a new RP technique, variable deposition manufacturing (VDM), which can make up for the disadvantages of the existing RP techniques, and to develop an apparatus to implement the technique. The proposed process can greatly reduce the building time and improve the surface finish of parts generated. The experiments are carried out to obtain the range of temperature of molten material to maintain its fluidity and to investigate the effect of gas cooling on the preservation of the slopes. Based on the results, some simple shapes such as a line-shape. an S-shape, and a circle-shape were fabricated from Ethylene Vinyl Acetatecopolymer (EVA). In order to examine the applicability of VDM to more general shapes, a tensile specimen and a yo-yo shape were manufactured by the proposed RP method using EVA material as the first trial approach. The present basic study has shown the possibility of a practicable utilization of the proposed VDM process to prototyping of a general three-dimensional shape.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.4
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• pp.407-411
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• 2011

The technology of line heating has evolved in various methods. Among them, fossil fuels like ethylene gas and LPG(Liquid Petroleum Gas) are widely used due to their simple utility. In the meantime, the technology implementing high frequency for line heating has also been developed continually, but its manufacturing technology or application includes lots of problems by now. One of the main characteristics of line heating using conventional technolob'Y is the quenching effect followed by heating process. On the other hand, hydrox gas which is mixed by hydrogen and oxygen is a prominent candidate for an application without above shortcomings. Especially, it is found that line heating using hydrox gas is tremendously effective taking low cost as well as low noise. In this paper, a small cell with high efficiency which can minimize installing space is developed to deal with the problem installing in narrow place. Experiments to prove the validation, efficiency and effectiveness is carried out by characterizing in the line heating of steel. It is found that the energy saving of using hydrox gas for line heating is significant and that the deviation performance is reduced by 78~89%. Furthermore, the noise is also reduced as amount of 18.3% though the heating time is not too different.

• Proceedings of the Korean Fiber Society Conference
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• 2003.04a
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• pp.52-55
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• 2003

Poly (ethylene 2, 6-naphthalate) (PEN) has been used for a high performance engineering plastics such as fiber, film, and packaging, because of excellent physical properties and outstanding gas barrier characteristics [1-2]. However, the application of PEN is limited because PEN exhibits a relatively high melt viscosity. Recently, many researches for organic/inorganic composites by applying nano-particles to the polymer matrix have been carried out [3], and the nano-particles exhibited greatly improved mechanical and rheological properties [4]. (omitted)

• Proceedings of the Korean Environmental Health Society Conference
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• 2005.11a
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• pp.150-153
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• 2005

A gas chromatography/electron impact mass spectrometric assay method was developed for the determination of Hb-adduct, 2-(hydroxyethyl)valine (HEVal), of ethylene oxide(EO). Globin was separated from hemoglobin by acid iso-propanol and ethyl acetate, then HEVal was isolated as PFPITH-HEVal by Edman degradation. PFPITH-HEVal was silylated with N-methyl-N-(tert-butyl-dimethylsilyl)trifluoroacetamide(MTBDMSTFA)-NH4I (1000:4) under catalysis of dithioerythritol. The detection limit of the assay was 5.8 pmol/g based upon assayed hemoglobin of 0.1g. Two groups of mice were exposed to EO for 0.5 and 1.0 hr/day, respectively at 400ppm during 4 weeks. As the result, the adduct levels increased according to the exposure time with the linearity of 0.7011 and 0.8914, respectively, HEVal was very valuable as biomarker for the exposure of EO. In human, HEVal was analyzed until 8.33 pmol/mg.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.618-621
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• 2005

In this study, the phenomena of hydrate formation and inhibition were investigated according to varying the concentrations using methanol and ethylene glycol as chemical additives. The results reveal that the used additives display better inhibition effects compared to pure water by decreasing the formation temperature and the inhibition performance of methanol is superior to that of ethylene glycol. As a conclusion, the plugging phenomena of flowline in natural gas product ion. subsea and frozen field pipelines can be predicted by examining the hydrate formation and inhibition conditions. Specifically, the results of this study can be applied to the selection of the prevention criteria and method of hydrate formation.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2008.05a
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• pp.93-96
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• 2008

This study was performed for merge characteristic of Hybrid Rocket with multi-port. PE(Poly Ethylene) is fuel with 4 and 5 port grain and GOX(Gas Oxygen) is oxidizer. This study according to number of ports The multi-port grain merge with other grains during a combustion, then Hybrid Rocket performance is changed by change of a combustion area.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.5
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• pp.40-54
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• 1999

The flame structure and soot formation in the counterflow Ethylene-Air nonpremixed flame are numerically analyzed. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of benzene and acetylene. In terms of the centerline velocity and the soot volume fraction, the predicted results are compared with the experimental data. The detailed discussion has been made for the sensitivity of model constants and the deficiencies of the present model. Numerical results indicated that the acetylene addition to the soot surface plays the dominant role in the soot mass growth for the counterflow nonpremixed flame.