• Title/Summary/Keyword: eta potential

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Treatment of ETA wastewater using GAC as particle electrodes in three-dimensional electrode reactor (활성탄 충진 3D 복극전기분해조를 이용한 ETA 처리)

  • Kim, Ran;Kim, Yu-Jin;Shin, Ja-Won;Kim, Jeong-Joo;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.2
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    • pp.241-249
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    • 2013
  • Ethanolamine (ETA) is widely used for alkalinization of water in steam cycles of nuclear power plants with pressurized water reactor. When ETA contained wastewater was released, it could increase COD and T-N. The treatment of the COD and T-N from ETA wastewater was investigated using the GAC as particle electrodes in three-dimensional electrode reactor (TDE). This study evaluated the effectiveness of GAC as particle electrode using different packing ratio at 300 V. The results showed that GAC-TDE could reduce ETA much more efficiently than ZVI-TDE at the mass ratio of GAC to insulator, 1:2. Additionally, The effect of applied electric potential to COD and T-N reduction was investigated. The results showed the high COD, T-N reduction and current efficiency at the low electric potential. Using the GAC-TDE will provide a better ETA reduction with reducing electrical potential dissipation.

Conditional Feynman Integrals involving indefinite quadratic form

  • Chung, Dong-Myung;Kang, Si-Ho
    • Journal of the Korean Mathematical Society
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    • v.31 no.3
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    • pp.521-537
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    • 1994
  • We consider the Schrodinger equation of quantum mechanics $$ i\hbar\frac{\partial t}{\partial}\Gamma(t, \vec{\eta}) = -\frac{2m}{\hbar}\Delta(t, \vec{\eta}) + V(\vec{\eta}\Gamma(t, \vec{\eta}) (1.1) $$ $$ \Gamma(0, \vec{\eta}) = \psi(\vec{\eta}), \vec{\eta} \in R^n $$ where $\Delta$ is the Laplacian on $R^n$, $\hbar$ is Plank's constant and V is a suitable potential.

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SOME RESULTS IN η-RICCI SOLITON AND GRADIENT ρ-EINSTEIN SOLITON IN A COMPLETE RIEMANNIAN MANIFOLD

  • Mondal, Chandan Kumar;Shaikh, Absos Ali
    • Communications of the Korean Mathematical Society
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    • v.34 no.4
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    • pp.1279-1287
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    • 2019
  • The main purpose of the paper is to prove that if a compact Riemannian manifold admits a gradient ${\rho}$-Einstein soliton such that the gradient Einstein potential is a non-trivial conformal vector field, then the manifold is isometric to the Euclidean sphere. We have showed that a Riemannian manifold satisfying gradient ${\rho}$-Einstein soliton with convex Einstein potential possesses non-negative scalar curvature. We have also deduced a sufficient condition for a Riemannian manifold to be compact which satisfies almost ${\eta}$-Ricci soliton.

Chiral [Iminophosphoranyl]ferrocenes: Synthesis, Coordination Chemistry, and Catalytic Application

  • Co, Thanh Thien;Shim, Sang-Chul;Cho, Chan-Sik;Kim, Dong-Uk;Kim, Tae-Jeong
    • Bulletin of the Korean Chemical Society
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    • v.26 no.9
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    • pp.1359-1365
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    • 2005
  • A series of new chiral [iminophosphoranyl]ferrocenes, {${\eta}^5-C_5H_4-(PPh_2=N-2,6-R_2-C_6H_3)$}Fe{${\eta}^5-C_5H_3-1-PPh^2-2-CH(Me)NMe_2$} (1: R = Me, $^iPr$), {${\eta}^5{-C_5H_4-(PPh_2=N-2,6-R_2}^1-C_6H_3)$}Fe{${\eta}^5-C_5H_3-1-(PPh_2=N-2,6-R_2-C_6H_3)-2-CH(Me)R_2$} (2: $R^1\;=\;Me,\;^iPr;\;R^2\;=\;NMe_2$, OMe), and $({\eta}^5-C_5H_5)Fe${${\eta}^5-C_5H_4-1-PR_2-2-CH(Me)N=PPh_3$} (3:R = Ph, $C_6H_{11}$) have been prepared from the reaction of [1,1'-diphenylphosphino-2-(N,N-dimethylamino) ethyl]ferrocene with arylazides (1 & 2) and the reaction of phosphine dichlorides ($R_3PCl_{2}$) with [1,1'-diphenylphosphino-2-aminoethyl]ferrocene (3), respectively. They form palladium complexes of the type $[Pd(C_3H_5)(L)]BF_4$ (4-6: L = 1-3), where the ligand (L) adopts an ${\eta}^2-N,N\;(2)\;or\;{\eta}^2$-P,N (3) as expected. In the case of 1, a potential terdentate, an ${\eta}^2$-P,N mode is realized with the exclusion of the –=NAr group from the coordination sphere. Complexes 4-6 were employed as catalysts for allylic alkylation of 1,3-diphenylallyl acetate leading to an almost stoichiometric product yield with modest enantiomeric excess (up to 74% ee). Rh(I)-complexes incorporating 1-3 were also prepared in situ for allylic alkylation of cinnamyl acetate as a probe for both regio- and enantioselectivities of the reaction. The reaction exhibited high regiocontrol in favor of a linear achiral isomer regardless of the ligand employed.

Photoelectrochemical Characteristics at the Titanium Oxide Electrode with Light Intensity and pH of the Solution (산화 티타늄 전극의 광학농도와 pH에 따른 광전기화학적 특성)

  • Park, Seong-Yong;Cho, Byung-Won;Yun, Kyung-Suk
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.255-262
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    • 1994
  • Arc melted Ti-5Bi alloy was oxidized by thermal oxidation method. In the present study free energy efficiency(${\eta}_e$) of titanium oxide electrode(TOE) was measured as a function of light intensity and light energy. Flat-band potential of TOE was measured as a function of the light intensity and the solution pH. The ${\eta}_e$ of TOE increased with the increase of light intensity and tight energy to maximum value of 3.2% and 13%, respectively, at $0.2W/cm^2$ and 4.0eV. The ${\eta}_e$ was strongly dependent on the magnitude of the bias voltage. Maximum value was found at 0.5V bias. Photocurrent of TOE was controlled by electron-hole pair generation in depletion layer. The flat-band potential of the illuminated TOE shifted to -0.065V/decade with increasing light intensity. With the decrease of pH of electrolyte, flat-band potential shifted to anodic direction. The experimental slope was in good agreement with the Nernstian value of 0.059V/pH decade.

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Simulation on Surface Tracking Pattern using the Dielectric Breakdown Model

  • Kim, Jun-Won;Roh, Young-Su
    • Journal of Electrical Engineering and Technology
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    • v.6 no.3
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    • pp.391-396
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    • 2011
  • The tracking pattern formed on the dielectric surface due to a surface electrical discharge exhibits fractal structure. In order to quantitatively investigate the fractal characteristics of the surface tracking pattern, the dielectric breakdown model has been employed to numerically generate the surface tracking pattern. In dielectric breakdown model, the pattern growth is determined stochastically by a probability function depending on the local electric potential difference. For the computation of the electric potential for all points of the lattice, a two-dimensional discrete Laplace equation is solved by mean of the successive over-relaxation method combined to the Gauss-Seidel method. The box counting method has been used to calculate the fractal dimensions of the simulated patterns with various exponent $\eta$ and breakdown voltage $\phi_b$. As a result of the simulation, it is found that the fractal nature of the surface tracking pattern depends strongly on $\eta$ and $\phi_b$.

STUDY OF GRADIENT SOLITONS IN THREE DIMENSIONAL RIEMANNIAN MANIFOLDS

  • Biswas, Gour Gopal;De, Uday Chand
    • Communications of the Korean Mathematical Society
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    • v.37 no.3
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    • pp.825-837
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    • 2022
  • We characterize a three-dimensional Riemannian manifold endowed with a type of semi-symmetric metric P-connection. At first, it is proven that if the metric of such a manifold is a gradient m-quasi-Einstein metric, then either the gradient of the potential function 𝜓 is collinear with the vector field P or, λ = -(m + 2) and the manifold is of constant sectional curvature -1, provided P𝜓 ≠ m. Next, it is shown that if the metric of the manifold under consideration is a gradient 𝜌-Einstein soliton, then the gradient of the potential function is collinear with the vector field P. Also, we prove that if the metric of a 3-dimensional manifold with semi-symmetric metric P-connection is a gradient 𝜔-Ricci soliton, then the manifold is of constant sectional curvature -1 and λ + 𝜇 = -2. Finally, we consider an example to verify our results.

Inhibitory Effect of Bee Venom on Lipopolysaccharide-induced Memorial Impairment and Acetylcholine Esterase, Secretase Activity

  • Kwon, Dae-Hyun;Song, Ho-Sueb
    • Journal of Acupuncture Research
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    • v.23 no.2
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    • pp.33-46
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    • 2006
  • Alzheimer's disease (AD) is the most prevalent form of neurodegenerative disease associated with aging in the human population. This disease is characterized by the extracellular deposition of beta-amyloid peptide $(A{\beta})$ in cerebral plaques. $A{\beta}$ is derived from the ${\beta}-amyloid$ precursor protein (APP) by the enzymes, ${\beta}-$ and ${\eta}o-secretase$. Compounds that ${\beta}-$ or ${\eta}o-secretase$ inhibit activity, can reduce the production of $A{\beta}$ peptides, and thus have therapeutic potential in the treatment of AD. Increasing body of evidence has been demonstrated that Bee Venom(BV) Acupuncture could compete with complex protein involving in multiple step of $NF-{\kappa}B$ activation and exert the anti-inflammatory potential of combined inhibition of the prostanoid and nitric oxide synthesis systems by inhibition of IKK and $NF-{\kappa}B$. In this study, I investigated possible effects of BV on memory dysfunction caused by lipopolysaccharide (LPS) and $A{\beta}$ through inhibition of secretases activities and $A{\beta}$ aggregation. I examined the improving effect of BV on the LPS (2.5 mg/Kg, i.p.)-induced memory dysfunction using passive avoidance response and water maze tests in the mice. BV (0.84, $1.67\;{\mu}g/ml$) reversed the LPS-induced memorial dysfunction in dose dependent manner. BV also dose-dependently attenuated LPS-induced ${\beta}$ and ${\eta}o-secretase$ activities in cerebral cortex and hippocampus of the mice brain. This study therefore suggests that BV acupuncture method may be useful for prevention of development or progression of AD.

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Reactivity of RhCp* Complexes Containing Labile Ligands toward Potential Linking Ligands Containing Terminal Thiophene or Furan Rings:Preparation and Structures of [Cp*Rh(L1)Cl2], [Cp*Rh(η2-NO3)(L1)](OTf),and {[Rh(L2)] · (OTf)}[L1 = 1,2-Bis((thiophen-2-yl)methylene)hydrazine); L2 = 1,2-Bis((furan-2-yl)methylene)hydrazine]

  • Lee, Kyung-Eun;Lee, Soon-W.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3600-3604
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    • 2010
  • Rhodium(III)-$Cp^*$ complexes containing labile ligands, $[Cp^*RhCl_2]_2$, [$Cp^*Rh({\eta}^2-NO_3)$(OTf)], and $[Cp^*Rh(OH_2)_3](OTf)_2$, reacted with potential linking ligands [$L^1$ = (2-thiophene)-CH=N-N=CH-(2-thiophene); $L^2$ = (2-furan)-CH=N-N=CH-(2-furan)] to give two molecular compounds, [$Cp^*Rh(L^1)Cl_2$] (1) and [$Cp^*Rh({\eta}^2-NO_3)(L^1)$]$(OTf){\cdot}CH_2Cl_2$ ($2{\cdot}CH_2Cl_2$), and one 1-dimensioanl coordination polymer, $\{[Rh(L^2)]{\cdot}(OTf)}_{\infty}$ (3). Whereas one imine nitrogen atom within the ligand is coordinated to the Rh metal in compounds 1 and 2, both nitrogen atoms are bound to two neighboring Rh metals in compound 3 to lead to a 1-D chain polymer.

Fabrication and Characterization of Dye-sensitized Solar Cells based on Anodic Titanium Oxide Nanotube Arrays Sensitized with Heteroleptic Ruthenium Dyes

  • Shen, Chien-Hung;Chang, Yu-Cheng;Wu, Po-Ting;Diau, Eric Wei-Guang
    • Rapid Communication in Photoscience
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    • v.3 no.1
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    • pp.16-19
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    • 2014
  • Anodic self-organized titania nanotube (TNT) arrays have a great potential as efficient electron-transport materials for dye-sensitized solar cells (DSSC). Herewith we report the photovoltaic and kinetic investigations for a series of heteroleptic ruthenium complexes (RD16-RD18) sensitized on TNT films for DSSC applications. We found that the RD16 device had an enhanced short-circuit current density ($J_{SC}/mAcm^{-2}=15.0$) and an efficiency of power conversion (${\eta}=7.2%$) greater than that of a N719 device (${\eta}=7.1%$) due to the increasing light-harvesting and the broadened spectral features with thiophene-based ligands. However, the device made of RD17 (adding one more hexyl chain) showed smaller $J_{SC}(14.1mAcm^{-2})$ and poorer ${\eta}(6.8%)$ compare to those of RD16 due to smaller amount of dye-loading and less efficient electron injection for the RD17 device than for the RD16 device. For the RD18 dye (adding one more thiophene unit and one more hexyl chain), we found that the device showed even lower $J_{SC}(13.2mAcm^{-2}) $ that led to a poorest device performance (${\eta}=6.2%$) for the RD18 device. These results are against to those obtained from the same dyes sensitized on $TiO_2$ nanoparticle films and they can be rationalized according to the electron transport kinetics measured using the methods of charge extraction and transient photovoltage decays.