Browse > Article
http://dx.doi.org/10.5012/bkcs.2010.31.12.3600

Reactivity of RhCp* Complexes Containing Labile Ligands toward Potential Linking Ligands Containing Terminal Thiophene or Furan Rings:Preparation and Structures of [Cp*Rh(L1)Cl2], [Cp*Rh(η2-NO3)(L1)](OTf),and {[Rh(L2)] · (OTf)}∞[L1 = 1,2-Bis((thiophen-2-yl)methylene)hydrazine); L2 = 1,2-Bis((furan-2-yl)methylene)hydrazine]  

Lee, Kyung-Eun (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
Lee, Soon-W. (Department of Chemistry (BK21), Sungkyunkwan University, Natural Science Campus)
Publication Information
Bulletin of the Korean Chemical Society / v.31, no.12, 2010 , pp. 3600-3604 More about this Journal
Abstract
Rhodium(III)-$Cp^*$ complexes containing labile ligands, $[Cp^*RhCl_2]_2$, [$Cp^*Rh({\eta}^2-NO_3)$(OTf)], and $[Cp^*Rh(OH_2)_3](OTf)_2$, reacted with potential linking ligands [$L^1$ = (2-thiophene)-CH=N-N=CH-(2-thiophene); $L^2$ = (2-furan)-CH=N-N=CH-(2-furan)] to give two molecular compounds, [$Cp^*Rh(L^1)Cl_2$] (1) and [$Cp^*Rh({\eta}^2-NO_3)(L^1)$]$(OTf){\cdot}CH_2Cl_2$ ($2{\cdot}CH_2Cl_2$), and one 1-dimensioanl coordination polymer, $\{[Rh(L^2)]{\cdot}(OTf)}_{\infty}$ (3). Whereas one imine nitrogen atom within the ligand is coordinated to the Rh metal in compounds 1 and 2, both nitrogen atoms are bound to two neighboring Rh metals in compound 3 to lead to a 1-D chain polymer.
Keywords
Rhodium-$Cp^*$; Bis(thipohene); Bis(furan); 1-D Chain; Rhodium coordination polymer;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
Times Cited By Web Of Science : 0  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759.   DOI   ScienceOn
2 Yamamoto, Y.; Nakamura, H.; Ma, J.-F. J. Organomet. Chem. 2001, 640, 10.
3 Bera, J. K.; Campos-Fernández, C. S.; Rodolphe, C.; Dunbar, K. R. Chem. Commun. 2002, 2536.
4 Angaridis, P.; Berry, J. F.; Cotton, F. A.; Murillo, C. A.; Wang, X. J. Am. Chem. Soc. 2003, 125, 10327.   DOI   ScienceOn
5 Seino, H.; Masumori, T.; Hidai, M.; Mizobe, Y. Organometallics 2003, 23, 3424.
6 Wang, J.-Q.; Ren, C.-X.; Jin, G.-X. Organometallics 2005, 25, 74.   DOI   ScienceOn
7 Lim, M. S.; Baeg, J. Y.; Lee, S. W. J. Organomet. Chem. 2006, 691, 4100.   DOI   ScienceOn
8 Han, W. S.; Lee, S. W. Dalton Trans. 2004, 1656.
9 Han, W. S.; Lee, S. W. Dalton Trans. 2004, 3360.
10 Han, W. S.; Lee, S. W. J. Organomet. Chem. 2003, 678, 102.   DOI   ScienceOn
11 Kang, J. W.; Moseley, K.; Maitlis, P. M. J. Am. Chem. Soc. 1969, 91, 5970.   DOI
12 Han, W. S.; Lee, S. W. Inorg. Chim. Acta 2003, 348, 15.   DOI   ScienceOn
13 Espinet, P.; Bailey, P. M.; Downey, R. F.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1980, 1048.
14 Lee, H. K.; Lee, S. W. Bull. Korean Chem. Soc. 2007, 28, 421.   DOI   ScienceOn
15 Lee, H. K.; Lee, S. W. J. Korean Chem. Soc. 2006, 50, 420.   DOI   ScienceOn
16 Sheldrick, G. M. SADABS, Program for Absorption Correction, University of Gottingen, 1996.
17 Bruker, SHELXTL, Structure Determination Software Programs, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA, 1997.
18 Sun, S.-S.; Lees, A. J. Coord. Chem. Rev. 2002, 230, 171.   DOI   ScienceOn
19 Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853.   DOI   ScienceOn
20 Swiegers, G. F.; Malefetse, T. J. Chem. Rev. 2000, 100, 3483   DOI   ScienceOn
21 Swiegers, G. F.; Malefetse, T. J. Coord. Chem. Rev. 2002, 225, 91.   DOI   ScienceOn
22 Brunner, H.; Janietz, N.; Meier, W.; Wachter, J.; Herdtweck, E.; Herrmann, W. A.; Serhadli, O.; Ziegler, M. L. J. Organomet. Chem. 1988, 347, 237.   DOI   ScienceOn
23 Contakes, S. M.; Klausmeyer, K. K.; Milberg, R. M.; Wilson, S. R.; Rauchfuss, T. B. Organometallics 1998, 17, 3633.   DOI   ScienceOn
24 Klausmeyer, K. K.; Rauchfuss, T. B.; Wilson, S. R. Angew. Chem. Int. Ed. 1998, 37, 1694.   DOI   ScienceOn
25 Klausmeyer, K. K.; Wilson, S. R.; Rauchfuss, T. B. J. Am. Chem. Soc. 1999, 121, 2705.   DOI   ScienceOn
26 Suzuki, H.; Tajima, N.; Tatsumi, K.; Yamamoto, Y. Chem. Commun. 2000, 1081.
27 Maekawa, M.; Sugimoto, K.; Kuroda-Sowa, T.; Suenaga, Y.; Munakata; M. J. Chem. Soc., Dalton Trans. 1999, 4357.