• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.1
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• pp.83-90
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• 2017

The corrosion behavior of a rebar in concrete according to the amount of NaCl and $LiNO_2$ was observed by using Electrochemical Impedance Spectroscopy. The corrosion was accelerated in a short time by using dry/wet cycles method, which is one of the corrosion acceleration methods, and though the value of measured impedance, equivalent circuit can be introduced. It was confirmed that the passive film of a embedded rebar in concrete with NaCl was broken quickly, and when $0.6M\;LiNO_2$ was added, the velocity of ongoing corrosion was declined considerably compared to the amount of NaCl. However, when $1.2M\;LiNO_2$ was added, it was confirmed that the passive film was not broken and its performance remained, compared to the amount of NaCl.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.41 no.2
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• pp.59-64
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• 2004

In this paper, a Cold PHEMT equivalent circuit was proposed, and it is applied to extract extrinsic resistances. By using the proposed Cold PHEMT equivalent circuit, the variation of impedance with frequency and bias were mainly emphasized. Especially, the convergence of impedance with frequency and the change in impedance with bias were carefully analyzed, which may be used for fast extraction of extrinsic resistances. The proposed extraction method demonstrated improving of small signal model accuracy than conventional extraction method.

• Journal of Electrochemical Science and Technology
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• v.13 no.4
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• pp.462-471
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• 2022

In this study, the electrochemical impedance characteristics of CO₂/H₂O co-reduction to produce CO/H₂ syngas were investigated in a low-temperature single cell. The effect of the operating conditions on the single-cell performance was evaluated at different feed concentrations and cell voltages, and the corresponding electrochemical impedance spectroscopy (EIS) data were collected and analyzed. The Nyquist plots exhibited two semicircles with separated characteristic frequencies of approximately 1 kHz and tens of Hz. The high-frequency semicircles, which depend only on the catholyte concentration, could be correlated to the charge transfer processes in competitive CO₂ reduction and hydrogen evolution reactions at the cathodes. The EIS characteristics of the CO₂/H₂O co-reduction single cell could be explained by the equivalent circuit suggested in this study. In this circuit, the cathodic mass transfer and anodic charge transfer processes are collectively represented by a parallel combination of resistance and a constant phase element to show low-frequency semicircles. Through nonlinear fitting using the equivalent circuit, the parameters for each electrochemical element, such as polarization resistances for high- and low-frequency processes, could be quantified as functions of feed concentration and cell voltage.

• Proceedings of the KIEE Conference
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• 1992.07a
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• pp.149-152
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• 1992

A simple and practial equivalent technique has been presented in this study. Arbitrary number of bus system can be aggregated to the equivalent one-bus system, equivalents are totel real, and reactive bus powers and T/L losses viewing form boundary buses. Variables to be determined are line impedance between boundary buses and the equivalent bus, voltage and angle of that bus. IEEE 14 bus system is used to demonstrate the proposed method. even in contingency cases very good results have been obtained

• KIEE International Transactions on Power Engineering
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• v.12A no.1
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• pp.6-14
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• 2002

In this paper, an EMM(Equivalent Mechanical Model) Is developed to explain the voltage collapse mechanism by reflecting the effects of reactive powers. The proposed EMM exactly represents the voltage instability mechanism described by the system equations. By the use of the EMM model, the voltage collapse mechanism has been illustrated by showing the exactness of the results. The stable region has been investigated with a reactive-power-controlled two-bus system, which shows that special alerts are required when the system operates with leading power factor. It is also discussed a system transform technique to eliminate the resistance component of the Thevenin equivalent impedance for practical applications. Finally, the results adopting the proposed method fur sample systems which were transformed are listed

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.18 no.4
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• pp.181-187
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• 2004

With the proliferation of nonlinear loads, high neutral harmonic currents in three-phase four-wire distribution system have been observed. It has been known that the ground impedance has an effect on the neutral currents of a system which operates with harmonics present. On-site measurements of harmonic currents and voltages according to the fall-of-potential method under case study system were made and the ground impedance modeling using the pattern search method for the harmonic analysis was developed The ground impedance model obtained by the proposed method was compared with the frequency characteristics by field tests and has shown appropriate results, and would be applicable to evaluate the harmonic and transient response characteristics of the ground system.

• Advanced Composite Materials
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• v.16 no.1
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• pp.1-10
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• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.49 no.2
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• pp.39-49
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• 2012

An impedance bandwidth enhancement method of an aperture coupled microstrip patch antenna (ACMPA) using a shunt stub is investigated. The conventional ACMPA with a H-shaped coupling aperture is designed and the electrical parameters for the equivalent circuit of the designed conventional ACMPA are extracted. A method for the enhancement of the impedance bandwidth of the ACMPA using a tuning stub connected in shunt with the feed line is presented. The -10 dB return loss impedance bandwidth of the ACMPA with a shunt stub is increased up to about 14 %. The maximum impedance bandwidth of the corresponding ACMPA without a shunt stub is 5.4 %. The increase of the impedance bandwidth of the ACMPA with a shunt stub compared to that of the corresponding ACMPA without a shunt stub is about 160 %.

• Journal of the Korean Ceramic Society
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• v.42 no.12 s.283
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• pp.793-799
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• 2005

A composite cathode of LSCF$(La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3)\;and\;GDC\; (Gd_2O_3-doped\;CeO_2:Ce_{0.9}Gd_{0.1}O_{1.95_})$ was characterized in terms of an electrode response, using a point contact in an Yttria-Stabilized Zirconia (YSZ) electrolyte incorporated into AC two-point impedance spectroscopy. The point-contacted configuration amplifies the responses occurring near the YSZ/cathode interface through the aligned point contact on the planar LSCF/GDC electrode. The point contact interface increases the bulk resistance allowing the estimation of the point contact geometry and resolving the electrode-related responses. The resultant impedance spectra are analyzed through an equivalent circuit model constructed by resistors and constant phase elements. The bulk responses can be resolved from the electrode-related portions in terms of spreading resistance. The electrode-related polarizations are measured in terms of temperature and oxygen partial pressure. The modified impedance spectroscopy is discussed in terms of methodology and analytical aspects, toward resolving the electrode-polarization issues in solid oxide fuel cells.

• Bulletin of the Korean Chemical Society
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• v.28 no.9
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• pp.1523-1530
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• 2007

The first reduction peak of the cyclic voltammogram (CV) for sulfur reduction in dimethyl sulfoxide has been studied using time resolved Fourier transform electrochemical impedance spectroscopic (FTEIS) analysis of small potential step chronoamperometric currents. The FTEIS analysis results reveal that the impedance signals obtained during short potential steps can be resolved into electron transfer reactions of two different time constants in a high frequency region. The FTEIS method provides snap shots of impedance profiles during an earlier phase of the reaction, leading to time resolved EIS measurements. Our results obtained by the FTEIS analysis are consistent with a series of electron transfer and chemical equilibrium steps of a complex reaction, making up an ECE (electrochemical-chemical-electrochemical) mechanism postulated from the results of computer simulation.