• Bulletin of the Korean Chemical Society
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• v.33 no.9
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• pp.2937-2942
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• 2012

We have theoretically investigated the magnetic properties of N-confused porphyrin (NCP), tetraphenyl-N-confused porphyrin (TPNCP) and their substituted derivatives with O, S and Se heteroatoms (2ONCP, 2STPNCP, 2SeNCP, 2OTPNCP, etc.) by using DFT method. In the minimum energy structures of the 2OTPNCP, the two couples opposite phenyl substitutes are staggered. In the case of TPNCP, 2STPNCP and 2SeTPNCP, two phenyls being respectively close to or opposite to N-confused pyrrole are found to be pointed the same direction, whilst others are in the opposite direction. Based on the equilibrium structures, the $^1H$ chemical shifts and nucleus-independent chemical shifts (NICS) are calculated in this paper. The ${\pi}$ current density being induced by the tridimensional perpendicular magnetic field transmits the inner section of the pyrrole segments for NCP and TPNCP. As for their substituted derivatives with O, S and Se atoms, the current path passes through the outer section of the two heterorings. The NICS values at the ring critical points of the heterorings are much lower (in absolute value) than those of which is at the center of an isolated pyrrole molecule. The $^1H$ NMR for ${\beta}H$ atoms of the heterorings decreases from O, S to with Se.

• Journal of Korean Society of Transportation
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• v.17 no.4
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• pp.71-84
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• 1999

The purpose of this study is to construct a dynamic traffic analysis model using the existing traffic flow theory in order to develope a dynamic traffic assignment technique. In this study the dynamic traffic analysis model was constructed using Daganzo's CELL TRANSMISSION THEORY which was considered more suitable to dynamic traffic assignment than the other traffic flow theories. We developed newly the diverging split module, the cost update module and the link cost function and defined the maximum waiting time decision function that Daganzo haven't defined certainly at his Papers. The output that resulted from the simulation of the dynamic traffic analysis model with test network I and II was shown at some tables and figures, and the analysis of the bottleneck and the HOV lane theory showed realistic outputs. Especially, the result of traffic assignment using the model doesn't show equilibrium status every time slice but showed that the average travel cost of every path maintains similarly in every time slice. It is considered that this model can be used at the highway operation and the analysis of traffic characteristics at a diverging section and the analysis of the HOV lane effect.

• Proceedings of the KWS Conference
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• 2002.10a
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• pp.176-180
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• 2002

During the last two decades the laser beam has progressed from a sophisticated laboratory apparatus to an adaptable and viable industrial tool. Especially, in its welding mode, the laser offers high travel speed, low distortion, and narrow fusion and heat-affected zones (HAZ). The principal obstacle to selection of a laser processing method in production is its relatively high equipment cost and the natural unwillingness of production supervision to try something new until it is thoroughly proven. The major objective of this work is focused on the combined features of gas tungsten arc and a low-power cold laser beam. Although high-power laser beams have been combined with the plasma from a gas tungsten arc (GTA) torch for use in welding as early as 1980, recent work at the Ohio State University has employed a low power laser beam to initiate, direct, and concentrate a gas tungsten arcs. In this work, the laser beam from a 7 watts carbon monoxide laser was combined with electrical discharges from a short-pulsed capacitive discharge GTA welding power supply. When the low power CO laser beam passes through a special composition shielding gas, the CO molecules in the gas absorbs the radiation, and ionizes through a process known as non-equilibrium, vibration-vibration pumping. The resulting laser-induced plasma (LIP) was positioned between various configurations of electrodes. The high-voltage impulse applied to the electrodes forced rapid electrical breakdown between the electrodes. Electrical discharges between tungsten electrodes and aluminum sheet specimens followed the ionized path provided by LIP. The result was well focused melted spots.

• The Korean Journal of Applied Statistics
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• v.18 no.1
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• pp.147-158
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• 2005

Most of the statistical models that real data can be applicable are static in nature, and thus it is not possible to analyze the effect of variations in the real world over time. Usual specification of the models does not produce the length and the time path of the effect even if the effect of an exogenous variation continues for periods of time. In this study, deriving the dynamic inherence from the static structure of the linear model for better utilization, we attempt to apply actual data to compare and analyze the long-run effect of variations in the market variables between the related markets by formulating a simultaneous equation system. Accordingly, it is proved to be possible to obtain efficient analytical results and to derive various useful implications.

• International Journal of Concrete Structures and Materials
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• v.11 no.1
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• pp.135-149
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• 2017

The prediction of the actual ultimate capacity of confined concrete columns requires partial confinement utilization under eccentric loading. This is attributed to the reduction in compression zone compared to columns under pure axial compression. Modern codes and standards are introducing the need to perform extreme event analysis under static loads. There has been a number of studies that focused on the analysis and testing of concentric columns. On the other hand, the augmentation of compressive strength due to partial confinement has not been treated before. The higher eccentricity causes smaller confined concrete region in compression yielding smaller increase in strength of concrete. Accordingly, the ultimate eccentric confined strength is gradually reduced from the fully confined value $f_{cc}$ (at zero eccentricity) to the unconfined value $f^{\prime}_c$ (at infinite eccentricity) as a function of the ratio of compression area to total area of each eccentricity. This approach is used to implement an adaptive Mander model for analyzing eccentrically loaded columns. Generalization of the 3D moment of area approach is implemented based on proportional loading, fiber model and the secant stiffness approach, in an incremental-iterative numerical procedure to achieve the equilibrium path of $P-{\varepsilon}$ and $M-{\varphi}$ response up to failure. This numerical analysis is adapted to assess the confining effect in rectangular columns confined with conventional lateral steel. This analysis is validated against experimental data found in the literature showing good correlation to the partial confinement model while rendering the full confinement treatment unsafe.

• Journal of Korean Association for Spatial Structures
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• v.12 no.2
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• pp.89-98
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• 2012

This study investigates the optimum structural design of space truss considering global buckling, and is to obtain the minimal weight of the structure. The mathematical programming method is used for optimization of each member by member force. Besides, dynamic programming method is adapted for consideration in snap-through buckling. The mathematical modeling for optimum design of truss members consists of objective function of total weight and constrain equations of allowable tensile (or compressive) stress and slenderness. The tangential stiffness matrix is examined to find the critical point on equilibrium path, and a ratio of the buckling load to design load is reflected in iteration procedures of dynamic programming method to adjust the stiffness of space truss. The star dome is examined to verify the proposed optimum design processor. The numerical results of the model are conversed well and satisfied all constrains. This processor is a relatively simple method to carry out optimum design with consideration in global buckling, and is viable in practice with respect to structural design.

• Steel and Composite Structures
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• v.10 no.3
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• pp.207-222
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• 2010

Fire incident in buildings is common, so the fire safety design of the framed structure is imperative, especially for the unprotected or partly protected bare steel frames. However, software for structural fire analysis is not widely available. As a result, the performance-based structural fire design is urged on the basis of using user-friendly and conventional nonlinear computer analysis programs so that engineers do not need to acquire new structural analysis software for structural fire analysis and design. The tool is desired to have the capacity of simulating the different fire scenarios and associated detrimental effects efficiently, which includes second-order P-D and P-d effects and material yielding. Also the nonlinear behaviour of large-scale structure becomes complicated when under fire, and thus its simulation relies on an efficient and effective numerical analysis to cope with intricate nonlinear effects due to fire. To this end, the present fire study utilizes a second-order elastic/plastic analysis software NIDA to predict structural behaviour of bare steel framed structures at elevated temperatures. This fire study considers thermal expansion and material degradation due to heating. Degradation of material strength with increasing temperature is included by a set of temperature-stress-strain curves according to BS5950 Part 8 mainly, which implicitly allows for creep deformation. This finite element stiffness formulation of beam-column elements is derived from the fifth-order PEP element which facilitates the computer modeling by one member per element. The Newton-Raphson method is used in the nonlinear solution procedure in order to trace the nonlinear equilibrium path at specified elevated temperatures. Several numerical and experimental verifications of framed structures are presented and compared against solutions in literature. The proposed method permits engineers to adopt the performance-based structural fire analysis and design using typical second-order nonlinear structural analysis software.

• Journal of the Korea institute for structural maintenance and inspection
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• v.21 no.3
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• pp.102-113
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• 2017

A new index for the buckling strength of non-structured plates is proposed. The external work or the deformation energy caused by the external loads or the boundary displacement controled by a load parameter is calculated along an equilibrium path of the member under consideration. If the second variation of the energy with respect to the parameter loses its positiveness, it defined as the limit of the stability. In contrast to the current method given in codes where the stability limit is evaluated by using only representative internal forces, the evaluation of the stability limit is always consistent even with the change of the distribution of the internal forces on the boundary. If the elasticity is concerned, the result from this proposed approach becomes identical to that from the classical methods.

• Tunnel and Underground Space
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• v.18 no.4
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• pp.289-299
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• 2008

Based on the case study on the causes for the failure of cutting slope composed of weathered rock and soil, the factors influencing the design of a cutting slope have been examined, This type of rock and soil is widely distributed on the region whose parent rock is granite. To analyze the stability of the cutting slope, the following series of progress has been conducted: (1) ground characterization by geological survey and ground investigation, (2) the safety factor examination by limit equilibrium analysis and numerical analysis and (3) the comparison and analysis of rainfall and failure history. As a result, the main factors to cause the failure is determined to be the decrease of shear strength in the upper parts whose ground condition is weakened during localized heavy rain. Moreover, the analysis indicates the failure is also closely related to the groundwater inflow path. On the base of this investigation, a reinforcement method is proposed to ensure the stability of the cutting slope.

• International Area Studies Review
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• v.16 no.1
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• pp.3-27
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• 2012

This paper adopts recently developed panel unit root test that is cross-sectionally robust. Cointegration test is also used to find whether regional house prices are in line with gross regional domestic production (GRDP) in the long run in Korea during 1989-2009. Based on the panel VECM and the panel ARDL models, we examine causal relationships among the variables and estimate the long-run elasticity. We find evidence of cointegration and bidirectional causal relationships between regional house prices and GRDP. The results of long-run estimates, using both fixed effect and ARDL models, show that house prices positively and significantly influence on the GRDP and vice versa. Together with these results, the findings of ARDL-ECM imply that there exists a long-run equilibrium relationship between house prices and regional economic variables even if there is a possibility of short-run deviation from its long-run path.