• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.3
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• pp.422-432
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• 2001

An analytical characterization is presented on the transient heat transfer by an oscillating flow through a porous slab. Based on a two-equation model, analytic solutions are obtained for both the fluid and solid temperature variations. Two parameters are identified as the Stanton number for the internal heat exchange and the ratio of the thermal capacities between the solid and fluid phases. The heat transfer characteristics are shown to be classified into four regimes according to the two parameters and physical interpretation is presented on the particular heat transfer processes within each regime. In addition, the condition for the local thermal equilibrium between the phases is examined and the relevant criterion is suggested.

• Journal of Microbiology and Biotechnology
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• v.11 no.4
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• pp.649-655
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• 2001

The kinetics of the thermolysin-catalyzed synthesis of N-(benzyloxycarbonyl)-L-phenylalanyl-L-leucine ethyl ester (Z-Phe-LeuOEt) from N-(benzyloxycarbonyl)-L-phyenylalanine (Z-Phe) and L-leucine ethyl ester (LeuOEt) in an ethyl acetate saturated aqueous system in a batch operation were studied. The kinetics for the synthesis of Z-Phe-LeuOEt were expressed using a rate equation for the rapid equilibrium random bireactant mechanism. The four kinetic constants involved in the rate equation were determined numerically by the quasi-Newton method so as to fit the calculated results with the experimental data. Within the pH and temperature range examined, the $K_{cat}$ value for the synthesis of Z-Phe-LeuOEt reached a maximum at pH 7.0 and $45^{\circ}C$, whereas the affinity between Z-Phe and thermolysin reached a maximum at pH 6.0 adn $40^{\circ}C$. The inhibitory effect of Z-Phe on the condensation reaction decreased as the pH and temperature decreased. In contrast, they affinity between LeuOEt and thermolysin remained unchanged within the pH and temperature range examined. Therefore, it was concluded that the protonation state of the carboxyl groups. of Z-Phe was more imprtant than that of the amono groups of LeuOEt for the synthesis of Z-Phe-LeuOEt in the present solvent system. The equilibrium yield at pH 6.0 and $30^{\circ}C$ was 8% higher than that at pH 7.0 and $40^{\circ}C$, although the rate was much slower. This result suggested that the affinity between the enzyme and the substrate rather than the overall rate was a more important factor affecting the equilibrium yield, when the peptide synthesis was carried out in a product-precipitation system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.2
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• pp.906-918
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• 2012

In this study, we compared with results simulated by EOS(Equation of State) using Peng-Robinson model and GERG-2004 model for estimating vapor pressure, latent heat of vaporation, liquid density, and binary isotherm vapor-liquid equilibrium on pure components composing natural gases. We obtained the simulated results that while EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model for estimating liquid density, but rather it is less accurate for estimating binary isotherm vapor-liquid equilibrium. On the other hand, the use of Costald model in EOS using Peng-Robinson model for increasing more accuracy to calculate liquid density is almost same as EOS using GERG-2004 model within the error of 1 % compared with experimental data. Also, we confirmed that on the estimation of binary isotherm vapor-liquid equilibrium, EOS using GERG-2004 model is more accurate than EOS using Peng-Robinson model, but they are almost same.

• Analytical Science and Technology
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• v.24 no.6
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• pp.467-476
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• 2011

Solubility data of carbon dioxide ($CO_2$) in the imidazolium-based ionic liquids with methylsulfate anion are presented at pressures up to about 45 MPa and at temperatures between 303.15 K and 343.15 K. The ionic liquids studied in this work were 1-ethyl-3-methylimidazolium methylsulfate ([emim][$mSO_4$]), 1-butyl-3-methylimidazolium methylsulfate ([bmim][$mSO_4$]). The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the binary mixtures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The equilibrium pressure increased very steeply at high $CO_2$ compositions. The $CO_2$ solubility in ionic liquids increased with increase of the total length of alkyl chains attached to the imidazolium cation of the ionic liquids. The phase equilibrium data for the $CO_2$ + ionic liquid systems have been correlated using the Peng-Robinson equation of state.

• Journal of Korean Association for Spatial Structures
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• v.10 no.2
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• pp.87-94
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• 2010

Form-Finding of tensegrity structures by eigenvalue problem is presented, In ardor to maintain the structures stable, "Form-Finding" should be performed. The types of analytical methods are known to solve this phenomenon: One is to use force density method, and the other is to apply so called, generalized inverse method. In this paper, new form finding methods are presented to obtain the self-equilibrium stress of the tensegrity structures. This method is based on the equilibrium equation of the all of the joint and the governing equation is formulated as eigonvalue problem. In order to verify this approach, numerical example(tensegrity structures) are compared with others calculated by previous methods. The solution by present method is shown identical results. Furthermore, the developed process to find the results is more efficient than previous approaches.

• Journal of the Korea Institute of Military Science and Technology
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• v.11 no.2
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• pp.116-124
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• 2008

Current paper investigates the dynamic behavior and stability of an infrared search and track subjected to external disturbance having gimbal structure with three rotating axes keeping constant angular velocity in the azimuth direction. Euler-Lagrange equation is applied to derive the coupled nonlinear dynamic equation of motion of infrared search and track and the characteristics of dynamic coupling are investigated. Two equilibrium points with small variations from the nonlinear coupling system are derived and the specific condition from which a coupled equation can be three independent equations is derived. Finally, to examine the stability of system, Lyapunov direct method was used and system stability and stability boundaries are investigated.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2929-2934
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• 2007

Prediction methods for cavitation noise are presented. At first, direct numerical simulation of cavitating flow noise has been performed, and acoustic analogy equation based on the cavitation noise modeling is derived. For the direct numerical simulation, a density based homogenous equilibrium model is employed to simulate cavitating two-phase flow and the governing equations are solved with high-order numerical schemes to resolve cavitation noise. The compressible Navier-Stokes equations for mixture fluids are discretized with a sixth-order central compact scheme, and the steep gradient of flow variables and supersonic regions are treated with the selective spatial filtering technique. The direct simulation of cavitating flow noise is performed for a 2D circular cylinder at cavitation number 0.7 and 1. The far-field noise is also predicted with the derived analogy equation. Noise spectrum predicted with the equation is well compared with the result of direct numerical simulation and also agree well with the theory.

• 제어로봇시스템학회:학술대회논문집
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• 2004.08a
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• pp.990-994
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• 2004

This paper presents a method to predict the transient characteristic of the air lubricated slider head in a hard disk drive by using optimization technique. The time dependent modified Reynolds equation based on the molecular slip flow approximation equations was used to describe the fluid flow within the air bearing and the implicit finite difference scheme is applied to calculate the pressure distribution under the slider head. The exhaustive search combined with the Broyden-Fletcher-Goldfarb-Shanno method were employed to obtain optimum design variables which are taper angle, rail width and taper length in order to keep the forces and moments acting on the slider head in dynamic equilibrium. The results show that the optimal head slider of the magnetic head has good stability characteristic that can reach the steady state within 0.5 microsecond.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.12 no.3
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• pp.407-415
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• 1999

There are two kinds of instability phenomena for shell-type structures which are snap-through and bifurcation buckling. These are very sensitive according to the shape characteristics including rise-span ratio and especially shape initial imperfection. In this study, the equilibrium path of shallow sinusoidal arches supported by hinges at both ends is investigated to grasp the instability behavior of shell-type structures with initial imperfection. The Galerkin method is used to get the nonlinear discretized equation of governing differential equation considering geometric nonlinearity of arches and the perturbation method is also used to transform the nonlinear equation to incremental form.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.14 no.2
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• pp.169-174
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• 2001

The electron transport coefficients(the electron drift velocity, W, and the longitudinal and transverse diffusion coefficient, D$_{L}$ and D$_{T}$) in SiH$_4$-Ar mixtures containing 0.5% and 5.0% monosilane were calculated over the E/N range from 0.01 to 300 Td and over the gas pressure range 0.5, 1.0 and 1.5 Torr by the time-of-flight(TOF) method of the Boltzmann equation(BE.) and Monte-Carlo simulation(MCS). The electron energy distribution function in each SiH$_4$-Ar mixtures at E/N=10 Td and L=0.2 cm, which in equilibrium region in the mean electron enregy were compared.red.