• Title/Summary/Keyword: equilibrium equation

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Investigation of vapor-liquid equilibrium of HFC-32/143a and HFC-143a/134a systems (HFC-32/143a와 HFC-143a/134a계의 기-액상평형 실험에 관한 연구)

  • Kim, C.N.;Park, Y.M.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.1
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    • pp.91-99
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    • 1999
  • Vapor-liquid equilibrium apparatus is designed and set up. The equilibrium data of two binary systems, HFC-32/143a and HFC-143a/134a, are measured. Fifteen equilibrium data for HFC-32/143a and HFC-143a/134a systems are measured over the temperature range 263.15~283.15K at 10K interval and the composition range 0.10~0.80, respectively. And vapor-liquid equilibrium data are calculated using equation of state and correlation of activity coefficient and compared with the present data. Equation of state is used CSD and RKS equations and correlation of activity coefficient is used Margules' and Van Ness and Abbott's correlations. Real behavior of HFC-32/143a system has very large deviation with Raoult's rule which is ideal behavior. But real behavior of HFC-143a/134a system is similar to ideal behavior. The calculated data from CSD equation are compared with the data in the open literatures and the calculated data from REFPROP. In the results for REFPROP, the relative deviations of bubble point pressure for HFC-32/143a system are within -2.16~0.84% for CSD equation and within -0.20~1.10% for RKS equation. And the relative deviations of bubble point pressure for HFC-143a/134a system are within -0.45~0.12% and -0.20~2.8% for CSD and RKS equations, respectively.

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BIFURCATION THEORY FOR A CIRCULAR ARCH SUBJECT TO NORMAL PRESSURE

  • Bang, Keumseong;Go, JaeGwi
    • Korean Journal of Mathematics
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    • v.14 no.1
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    • pp.113-123
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    • 2006
  • The arches may buckle in a symmetrical snap-through mode or in an asymmetry bifurcation mode if the load reaches a certain value. Each bifurcation curve develops as pressure increases. The governing equation is derived according to the bending theory. The balance of forces provides a nonlinear equilibrium equation. Bifurcation theory near trivial solution of the equation is developed, and the buckling pressures are investigated for various spring constants and opening angles.

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REMARKS ON CRITERIA FOR THE EXISTENCE OF A POSITIVE EQUILIBRIUM IN REACTION NETWORKS

  • Choo, S.M.
    • Journal of applied mathematics & informatics
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    • v.29 no.3_4
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    • pp.949-953
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    • 2011
  • It is interesting to know the behavior of a network from its structure. One interesting topic is to find a relation between the existence of a positive equilibrium of the reaction network and its structure. One approach to study this topic is using the concept of deficiency. Another is using some conditions on nodes, which can apply to large-size networks compared to deficiency. In this work, we show the relation between deficiency and the conditions.

AN ELEMENTARY PROOF OF THE EXISTENCE OF A POSITIVE EQUILIBRIUM IN REACTION NETWORKS

  • Choo, S.M.
    • Journal of applied mathematics & informatics
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    • v.28 no.5_6
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    • pp.1545-1552
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    • 2010
  • It is interesting to know the behavior of a network from its structure. One interesting topic is to find a relation between the existence of a positive equilibrium of the reaction network and its structure. One approach to study this topic is using the concept of deficiency. In this work, we develop an algorithm and show an elementary proof of the relation based on the algorithm and deficiency.

Biosorption of Rhodamine B onto Waste Activated Sludge: Equilibrium and Kinetic Modelling (폐 활성슬러지를 이용한 Rhodamine B의 생체흡착:흡착평혀여 및 흡착속도 모델링)

  • Lee Chang-Han;Ahn Kab-Hwan
    • Journal of Environmental Science International
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    • v.14 no.9
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    • pp.881-888
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    • 2005
  • The biosorption of dye, Rhodamine B(Rh-B), onto waste activated sludge was investigated. The biosorption capacity and contact time were shown as a simulation of dye adsorption equilibrium and kinetics models. We observed that biosorption of Rh-B occurred rapidly less than 4 hr. These experimental data could be better fitted by a pseudo-second-order rate equation than a pseudo-first-order rate equation. The equilibrium dependence between biosorption capacity and initial concentration of Rh-B was estimated and it was found that the equilibrium data of biosorption were fitted by four kinds of model such as Langmuir, Freundlich, Redlich-Peterson, and Koble-Corrigan model. The average percentage errors, $\varepsilon(\%)$, observed between experimental and predicted values by above each model were $21.19\%,\;9.97\%,\;10.10\%\;and\;11.76\%$, respectively, indicating that Freundlich and Redlich-Peterson model could be fitted more accrately than other models.

Investigation of vapor-liquid equilibrium of HFC125/134a system (HFC125/134a계의 기-액상평형에 관한 연구)

  • 김창년;박영무
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.10 no.2
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    • pp.238-250
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    • 1998
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC125/134a are measured in the range between 268.15 and 283.15K at five compositions. Twenty-five equilibrium data are obtained. To verify consistency of these data, they are tested for thermodynamic consistency. Based upon the present data, the binary interaction parameter for CSD and RKS equation of state is calculated at five isotherms and comparison with the data in the open literatures is made. Results of Nagel and Bier are in very good agreements with those from this study within 0.32∼1.11% for bubble point pressure and -0.66∼0.18% for vapor mole fraction.

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Investigation of vapor-liquid equilibrium of HFC32/134a system (HFC32/134a 계의 기-액상평형에 관한 연구)

  • Kim, C.N.;Park, Y.M.;Lee, B.K.;An, B.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.4
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    • pp.527-535
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    • 1997
  • Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC32/134a are measured in the range between 258.15 and 283.15K at compositions of 0.2, 0.4, 0.6 and 0.8 mole fraction of HFC32. Twenty-two equilibrium data are obtained. Based upon the present data, the binary interaction parameter for Carnahan-Starling-De Santis equation of state is calculated. Temperature range of data is extended to 313.04K using the data in the open literatures. Interaction parameters are determined at nine isotherms.

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Finite element formulations for free field one-dimensional shear wave propagation

  • Sun-Hoon Kim;Kwang-Jin Kim
    • Earthquakes and Structures
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    • v.26 no.2
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    • pp.163-174
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    • 2024
  • Dynamic equilibrium equations for finite element analysis were derived for the free field one-dimensional shear wave propagation through the horizontally layered soil deposits with the elastic half-space. We expressed Rayleigh's viscous damping consisting of mass and stiffness proportional terms. We considered two cases where damping matrices are defined in the total and relative displacement fields. Two forms of equilibrium equations are presented; one in terms of total motions and the other in terms of relative motions. To evaluate the performance of new equilibrium equations, we conducted two sets of site response analyses and directly compared them with the exact closed-form frequency domain solution. Results show that the base shear force as earthquake load represents the simpler form of equilibrium equation to be used for the finite element method. Conventional finite element procedure using base acceleration as earthquake load predicts exact solution reasonably well even in soil deposits with unrealistically high damping.

GLOBAL STABILITY OF A NONLINEAR DIFFERENCE EQUATION

  • Wang, Yanqin
    • Journal of applied mathematics & informatics
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    • v.29 no.3_4
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    • pp.879-889
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    • 2011
  • In this paper, we investigate the local asymptotic stability, the invariant intervals, the global attractivity of the equilibrium points, and the asymptotic behavior of the solutions of the difference equation $x_{n+1}=\frac{a+bx_nx_{n-k}}{A+Bx_n+Cx_{n-k}}$, n = 0, 1,${\ldots}$, where the parameters a, b, A, B, C and the initial conditions $x_{-k}$, ${\ldots}$, $x_{-1}$, $x_0$ are positive real numbers.