• 대한치과보철학회지
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• 제32권1호
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• pp.23-36
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• 1994

Most investigators recommended that porcelain surface should be roughened with abrasives and/or be etched with acid in repairing the fractured porcelain with composite resin. This study was designed to evaluate the effect of porcelain surface treatments on the bond strength between porcelain and composite resin by measuring the shear bond strength and observing the porcelain surface with SEM. 48 porcelain disc were fabricated with Vintage porcelain and embedded in epoxy resin with the test surface exposed. The specimens were divided four groups at random and the test surfaces of the four groups were prepared as follows : Group 1 : Porcelain surface was roughened with a fine diamond and treated with 32% phosphoric acid gel for 10 seconds. Group 2 : Porcelain surface was roughened with a fine diamond and etched with 8% hydrofluoric acid gel for 5 minutes. Group 3 : Porcelain surface was roughened with a coarse diamond and treated with 32% phosphoric acid gel for 10 seconds. Group 4 : Porcelain surface was roughened with a coarse diamond and etched with 8% hydrofluoric acid gel for 5 minutes. All specimens were washed for 30 seconds. A representative specimen of each group was selected and the porcelain surface was observed with SEM at 1000 magnification. Remaining specimens were silanated, bonded with composite resin, thermocycled, and shear-tested on specially designed zig connected to Instron machine. The results were as follows : 1. The shear bond strength of the group etched with hydrofluoric acid was significantly higher than that of group treated with phosphoric acid(p<0.01). 2. The shear bond strength of the group roughened with a fine diamond was not significantly different from that of the group roughened with a coarse diamond(p>0.01). 3. SEM examination of prepared porcelain surfaces revealed that the surface etched with hydrofluoric acid showed numerous microporosities, undercut, and rougher surface than the surface treated with phosphoric acid. 4. All specimens etched with hydrofluoric acid showed cohesive failure within porcelain, but specimens treated with phosphoric acid mainly showed adhesive failure between porcelain and composite resin.

• Safety and Health at Work
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• 제7권1호
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• pp.63-71
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• 2016

Background: Construction painters have not been studied well in terms of their hazards exposure. The objective of this study was to evaluate the exposure levels of total volatile organic compounds (TVOCs) for painters in the construction industry. Methods: Activity-specific personal air samplings were carried out in three waterproofing activities [polyurethane (PU), asphalt, and cement mortar] and three painting activities (epoxy, oil based, and water based) by using organic-vapor-monitor passive-sampling devices. Gas chromatograph with flame ionization detector could be used for identifying and quantifying individual organic chemicals. The levels of TVOCs, by summing up 15 targeted substances, were expressed in exposure-index (EI) values. Results: As arithmetic means in the order of concentration levels, the EIs of TVOCs in waterproofing works were 10.77, 2.42, 1.78, 1.68, 0.47, 0.07, and none detected (ND) for indoor PU-primer task, outdoor PU-primer task, outdoor PU-resin task, indoor PU-resin task, asphalt-primer task, asphalt-adhesive task, and cement-mortar task, respectively. The highest EI for painting works was 5.61 for indoor epoxyprimer task, followed by indoor epoxy-resin task (2.03), outdoor oil-based-spray-paint task (1.65), outdoor water-based-paint task (0.66), and indoor oil-based-paint task (0.15). Assuming that the operations were carried out continuously for 8 hours without breaks and by using the arithmetic means of EIs for each of the 12 tasks in this study, 58.3% (7 out of 12) exceeded the exposure limit of 100% (EI > 1.0), while 8.3% (1 out of 12) was in 50e100% of exposure limit (0.5 > EI > 1.0), and 4 tasks out of 12 were located in less than 50% of the limit range (EI < 0.5). Conclusion: From this study, we recognized that construction painters are exposed to various solvents, including carcinogens and reproductive toxins, and the levels of TVOC concentration in many of the painting tasks exceeded the exposure limits. Construction workers need to be protected from chemical agents during their painting works by using personal protective devices and/or work practice measures. Additional studies should focus on the exposure assessment of other hazards for construction workers, in order to identify high-risk tasks and to improve hazardous work environments.

• 한국인쇄학회지
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• 제29권2호
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• pp.45-58
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• 2011

Gravure off-set printing recently is used in electronics display market. This method has advantages of mass production and high printing speed. It is also fine pattern can be implemented. We have manufactured low-curable conductive Ag pastes for gravure off-set printing. When printing, the pastes be used different silver powder shape because of the printing characteristics. The pastes were prepared with silver powder by silver powder shape and size, epoxy resin, solvent and homogenized on a standard three-roll mill. And the pastes exhibited a shear-thinning flow at viscosity profile. Moreover the adhesive strength and resistivity of silver film had a good characteristics. With the manufactured paste in this study, touch panel had is manufactured and it had $4{\times}10-5{\Omega}.cm$.

• 박물관보존과학
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• 제7권
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• pp.3-10
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• 2006

경주 은령총에서 출토된 청동제 합은 과거 접합되었다가 파손된 상태로 본체의 경우 전체의 절반 정도만이 남아있어 보존 및 전시를 위해서 보존처리 하였다. 이물질 및 열화된 접착제의 제거 후 재접합 하였는데, 비교적 많은 부분이 남아있는 뚜껑은 복원부위를 쉽게 분리할 수 있는 가역적인 방법으로 처리하였다. 본체의 경우 복원부위가 많기 때문에 유물의 하중을 잘 견딜 수 있도록 에폭시수지를 사용하여 접합하였다. 합을 비파괴 조사한 결과 주조품 이었으며 재질은 Cu-Sn-Pb의 3원계 합금으로 나타났다.

• 한국신뢰성학회지:신뢰성응용연구
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• 제13권3호
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• pp.207-216
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• 2013

This paper, we classified LED failure mechanisms that occur due to the delamination and analyzed each of the mechanism that gives the LED PKGs the effect. Usually, the LED is composed of several materials which are LED chips, gold wire, phosphor, epoxy resin, adhesive, reflector and lead frame. These different materials are usually delaminated in trouble conditions which are huge temperature difference, hot and humid or mechanical shocked. When the components are delaminated, a luminance will be lost and moisture be absorbed easily, a thermal resistance be increased attendantly. In this paper, we experimented to investigate failure mechanism of the thermal resistance and failure mechanism of the decrease of luminance that occur due to the delamination. A thermal shock test was performed to reproduce this phenomena by subjecting samples to a cold-hot cyclling process between $-30^{\circ}C$(15min) and $110^{\circ}C$(15min). The samples were inspected at 200, 600 and 1,000 cycles. We measured feature of LED using the spatial analyzer, optical microscope, thermal resistance, photometer, scanning electron microscope (SEM). As a result, the progression of the crack and the thermal resistance and decrease in luminance are proportional to number of thermal shock.

• Steel and Composite Structures
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• 제44권1호
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• pp.105-117
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• 2022

Impact resistance efficiency of the newly designed sandwich beam with a laterally arched core as bio-inspired by the woodpecker is numerically investigated. The principal components of the beam comprise a dual-core system sandwiched by the top and bottom laminated CFRP skins. Different materials, including hot melt adhesive, high-density polyethylene (HDPE), acrylonitrile butadiene styrene (ABS), epoxy resin (EPON862), aluminum (Al6061), and mild carbon steel (AISI1018), are considered for the side-arched core layer of the beam for impact efficiency assessment. The aluminum honeycomb takes the role of the second core. Contact force, stress, damage formation, and impact energy for beams equipped with different materials are examined. A diversity in performance superiority is noticed in each of these indicators for different core materials. Therefore, for overall performance appraisal, the impact resistance efficiency index, which covers several chief impact performance parameters, of each sandwich beam is computed and compared. The impact resistance efficiency index of the structure equipped with the AISI1018 core is found to be the highest, about 3-10 times greater than other specimens, thus demonstrating its efficacy as the optimal material for the bio-inspired dual-core sandwich beam system.

• 공학기술논문지
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• 제6권2호
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• pp.121-124
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• 2013

This paper proposed a new concept of estimating method for LED(light-emitting diode) delamination with high accuracy. Usually, The LED is composed several materials which are LED chips, gold wire, phosphor, epoxy resin, adhesive, reflector and lead frame. These different materials are usually delaminated in a trouble conditions which are huge temperature difference, hot and humid or mechanical shocked. When the components are delaminated, a luminance will be lost, moisture be absorbed easily and a thermal resistance be increased attendantly. As a conventional method to estimate a delamination of LEDs, a solution immersing method is usually used in a field of LED manufacturing companies or researching institutes. This method has an advantage of simplicity but it is only shown that the existence of delamination or not. In this paper, we have proposed an estimating method for LEDs delamination using the polishing and the electron microscope. New proposed method has shown the result of confirming delamination without destruction and enabled quantitative analysis for LED delamination.

• 한국구조물진단유지관리공학회 논문집
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• 제12권2호
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• pp.67-74
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• 2008

본 연구에서는 탄소섬유접착보강공법의 박리와 연관한 부착특성에 대하여 검토하였다. 그 결과를 요약하면, 온도변화에 따른 변형 특성에서는 바탕 콘크리트의 강도에 관계없이 온도 변화에 따라서 각 재료들의 변형 폭도 커지는 것을 알 수 있었다. 초음파 전파 속도도 온도변화에 따라 작아지는 것으로 나타나 계면에서 박리가 발생하였음을 알 수 있었다. 부착강도는 온도 변화가 클수록 부착강도의 값은 작아지는 것으로 나타났는데, 파괴형태는 계면파괴와 모재파괴 형태로 나타났다. 건습 변화에 따라서는 4사이클까지 각 재료의 변형 및 초음파 전파 속도에서 큰 변화를 나타내지 않아 건습 자체의 반복에는 큰 영향이 없는 것으로 판단된다. 단, 부착강도는 40%정도 저하하는 것으로 나타났지만 비교적 양호한 강도를 나타내었다. 동결융해 시험결과는 온도변화 요인과 유사한 경향으로서 동결융해 작용을 받을 경우 4사이클 이내에 박리가 일어날 수 있는 것으로 분석되었다.

• 한국건축시공학회지
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• 제18권6호
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• pp.569-576
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• 2018

현대사회에서 건축물은 대다수가 RC구조로 건설되어지고 있다. RC구조의 건축물은 시공상의 하자발생, 설계단계에서의 오차발생 등과 같은 인위적인 요인과 지진, 태풍 등의 자연적인 요인에 의해 구조적 불안정성이 발생하고 이를 해결하기 위해 다수의 보수보강공법이 이루어지고 있다. 보강공법 중 FRP 보강공법에서 사용하는 유기계 에폭시 접착제는 고온에 노출되었을 때 부착파괴가 급격하게 발생하게 되며 이는 보강재의 탈락으로 직결된다. 따라서 본 연구에서는 고온에 노출되었을 때 FRP 보강재에 전달되는 열을 감소시켜주며 일정수준 이상의 부착성능을 가진 무기계 내화 모르타르의 개발을 목적으로 실험을 진행하였다. 실험 결과 EVA수지의 포함으로 상온조건에서 높은 부착강도를 나타내었으며, 가열조건에서도 약 $300^{\circ}C$까지 전혀 성능저하를 나타내지 않았다. 또한, 이면온도는 두께가 증가할수록 낮았으며, 가열 2시간 이후에에서는 약 $780^{\circ}C$의 일정한 온도로 수렴되는 것을 확인하였다.

• 대한기계학회논문집A
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• 제23권11호
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• pp.1904-1911
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• 1999

The most effective material in the shape memory alloy(SMA) is the TiNi alloy, because its shape recovery characteristics are very excellent. We molded the composite material with shape memory function. The fiber of it is $Ti_{50}-Ni_{50}$ shape memory alloy and matrix of it is epoxy resin(Araldite B41, Hardner HT903. Ciba Geigy), its adhesive and optical sensitivity are very excellent. It was assured that the composite material could be used as model material of photoelastic experiment for intelligent materials or structures. In this research, the composite material with shape memory function is used as model material of photoelastic experiment. Photoelastic experimental hybrid method is developed in this research, it is assured that it is useful on the obtaining stress intensity factor and the separation of stress components from only isochromatic data. The measuring method of stress intensity factor of intelligent material by photoelastic experiment is introduced. In the mode I state, we can know that stress intensity factors are decreased more than 50% of stress intensity factor of room temperature when temperature of fiber is greater than 4$0^{\circ}C$, prestrain greater than 5% and fiber volume ratio greater than 0.42% and that stress intensity factors are decreased by 100% when fiber volume ratio is greater than 0.84%, prestrain greater than 5% and temperature greater than 60 $^{\circ}C$.