• 제어로봇시스템학회논문지
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• 제4권3호
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• pp.372-377
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• 1998

This paper deals with the detection, feature extraction and classification of surface defects in cold rolled strips. Inspection systems are one of the most important fields in factory automation. Defects such as slipmark and dullmark can be effectively detected with a Gaussian matched filter because their shapes are similar to Gaussian. It is justified that the proposed WF(Wavelet Frame) method could be regarded as multiscale Gaussian matched filter which can be applied to the inspection of cold rolled strip. After a wavelet frame transform, the entropies and moments are computed for each subband which pass through both local low pass filter and nonlinear operator. With these features as input, a MLP(Multi Layer Perceptron) is used as a classifier. The proposed inspection method was applied to the real images with defects, and hence showed good performance. The role of each extracted feature is analyzed by KLT(Karhunen-Loeve Transform).

• 대한화학회지
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• 제57권1호
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• pp.52-62
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• 2013

The interaction of titanium (IV), yttrium (III), zirconium (IV), palladium (II) and cerium (IV) with deprotonated enrofloxacin leads to the formation of the neutral or cationic mononuclear complexes. The isolated solid complexes have been characterized with physicochemical and spectroscopic techniques and thermogravimeteric analyses. The spectroscopic data indicate that the enrofloxacin ligand is on the deprotonated mode acting as bidentate ligand coordinated to the metal ions through the ketone oxygen and a carboxylato oxygen and the metal ions completed the coordination number with water molecules. The thermal decomposition mechanisms proposed for enrofloxacin and their metal complexes were discussed. The activation energies, $E^*$, enthalpies, ${\Delta}H^*$, entropies, ${\Delta}S^*$ and Gibbs free energies, ${\Delta}G^*$, of the thermal decomposition reactions have been derived from thermogravimetric (TG) and differential thermogravimetric (DTG) curves, using Coats-Redfern (CR) and Horowitz-Metzeger (HM) methods. The antimicrobial activity has been evaluated against six different microorganisms.

• 대한화학회지
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• 제32권4호
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• pp.311-317
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• 1988

임계점 이상의 여러 온도와 압력에서 암모니아내의 나프탈렌의 용해도를 측정함으로써 용해도와 암모니아의 밀도 사이의 관계를 간단한 식으로 나타낼 수 있었다. 이 식을 이용하여 더 높은 압력이나 더 낮은 압력에서의 용해도를 계산할 수가 있으며, 이로부터 용해에 수반되는 에너지 변화와 엔트로피변화를 구하고, 초임계 이산화탄소내의 나프탈렌의 용해도 자료로부터 얻어진 결과와 비교하였다. 또한 나프탈렌과 암모니아 사이의 상호작용 비리알 계수를 결정하여 나프탈렌과 이산화탄소 사이의 경우와 비교 검토하였다.

• 대한화학회지
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• 제35권1호
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• pp.16-23
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• 1991

폴리스틸렌 수지에 트리에틸렌테트라아민을 반응시켜 선형과 집게형의 킬레이트 수지를 합성하였으며, 이들 수지에 지지된 아민은 주로 적외선 스펙트럼으로 확인하였고, 전이금속이 수지에 흡착되는 속도를 측정하였다. 이 결과에서 얻어진 확산계수 및 활성화엔트로피 등이 보고된다. 흡착과정의 속도결정 단계는 입자를 통한 확산과정이다.

• 한국지능시스템학회논문지
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• 제15권5호
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• pp.521-526
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• 2005

모호함의 측도를 위하여 퍼지 엔트로피와 거리측도 그리고 유사측도와의 관계를 이용하여 새로운 퍼지 측도를 제안하였다. 제안된 퍼지 엔트로피는 거리측도를 이용하여 구성된다. 거리측도는 일반적으로 사용되는 해밍 거리를 이용하였다. 또한 집합사이의 유사성을 측정하기 위한 유사측도를 거리 측도를 이용하여 구성하였고, 제안한 퍼지 엔트로피와 유사측도를 증명을 통하여 타당성을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제21권1호
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• pp.105-109
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• 2000

High-performance liquid chromatography is suitable for getting thermodynamic information about solute-solvent interactions. We used a squalane impregnated $C_{18}$ phase as a presumably bulk-like stationary phase to secure a simple partition mechanism for solute retention in reversed phase liquid chromatographic system. We measured retention data of some selected solutes (benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, phenol, benzylalcohol, phenethylalcohol, benzylacetone, acetophenone, benzonitrile, benzylcyanide) at 25, 30, 35, 40, 45, and 50 $^{\circ}C$ in 30/70, 40/60, 50/50, 60/40 and 70/30 (v/v%) acetonitrile/water eluents. The van't Hoff plots were nicely linear, thus we calculated dependable thermodynamic values such as enthalpies and entropies of solute transfer from the mobile phase to the stationary phase based on more than four retention measurements on different days (or weeks). We found that the cavity formation effect was the major factor in solute distribution between the mobile and stationary phases in the system studied here. Our data were com-pared with some relevant literature data.

• Bulletin of the Korean Chemical Society
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• 제3권1호
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• pp.18-23
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• 1982

The molar volumes, the molar heat capacities and the molar entropies of solid argon are calculated from 0 K to the triple point using the vacancies-in-solid model. In the partition function, the central pairwise additive (Mie-Lennard-Jones 12,6) potential is used by introducing numbers, which is obtained by summing powers over all lattice points of a face-centred cubic in terms of the distance between nearest neighbours. A method of iteration is employed to evaluate the potential parameter. The results are compared with experimental values and other theoretical values. The results show a fair agreement with the experimental results.

• Bulletin of the Korean Chemical Society
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• 제17권12호
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• pp.1147-1149
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• 1996

The trans (2a)-cis (2b) isomerization of [Me2Al(μ-NHtBu)]2 (2) has been studied by 1H NMR spectroscopy. The equilibrium has been observed to follow reversible first order kinetics with ΔH0=2.22±0.07 kJmol-1 and ΔS0=2.85±0.07 JK-1mol-1. The activation parameters for the conversion 2a→2b are ΔH1=49.7±2.3 kJmol-1 and ΔS1=-126.3±0.2 JK-1mo1-1 and for the reverse reaction 2b→2a are ΔH-1=47.5±2.3 kJmol-1 and ΔS-1=-129.1±0.5 JK-1mol-1. The isomerization is markedly accelerated in the presence of Lewis bases. A crossover experiment indicates that the isomer interconversion is a unimolecular process. The large negative entropies of activation suggest either the existence of a sterically congested intermediate or the participation of solvent in the isomerization process.

• Current Optics and Photonics
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• 제5권1호
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• pp.16-22
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• 2021

We present the Shannon entropy as an indicator of the spatial resolutions of the morphologies of the resonance mode patterns in an optical resonator. We obtain each optimized number of mesh points, one of minimum size and the other of maximum one. The optimized mesh-point number of minimum size is determined by the identifiable quantum number through a chi-squared test, whereas the saturation of the difference between Shannon entropies corresponds to the other mesh-point number of maximum size. We also show that the optimized minimum mesh-point increases as the (real) wave number increases and approximates the proportionality constant between them.

• Nuclear Engineering and Technology
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• 제10권3호
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• pp.127-136
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• 1978

온도종속 Thomas-Fermi 이론을 적용하여 금속의 일종인 Na에 대한 상태방정식, chemical potential, % ion 화도, 엔트로피, 원자당운동에너지 및 총에너지 등을 포함한 제열학적동을 산출하였다. $\rho$$_{0}$를 Na의 비등점에서의 정상밀도라 할 때 0.1$\rho$$_{0}$ ~ 10$\rho$$_{0}$ 까지의 밀도영역에서, 또한 Na이 기체 또는 액체상태로 존재할 것으로 기대되는 $textsc{k}$T=60.88Ryd.~0.0216Ryd 까지의 온도영역에 대하여 이들 양을 산출하였다. 본 연구에서는 고온 및 고압상태에서의 물리양 산출하는 것을 주목적으로 하고 있으나 Thomas-Fermi 근사가 기대되는 것처럼 그렇게 조잡하지 않음을 보이기 위하여 극저온 및 극저밀도에서의 물리양들도 산출하였다. 특히 고온에서의 상태방정식, 운동에너지, chemical potential 및 엔트로피를 ideal Fermi gas의 이들 양과 비교하였다. 그 결과, 산출한 chemical potential은 서로 잘 일치하나 엔트로피, 원자당운동에너지 및 상태방정식은 $textsc{k}$T=60.88Ryd.의 고온에서도 상당한 차이가 있음을 발견하였다.