• 대한기계학회논문집B
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• 제23권10호
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• pp.1213-1222
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• 1999

A finite element method is developed for calculating the temperature and enthalpy distribution and accordingly the solid, liquid and mushy zone in a three-dimensional body subjected to any heat boundary conditions. The method concurrently consider both temperature and enthalpy for consideration of the latent heat effect, differently from other methods of using a special energy balance equation for solving a mushy zone. The developed brick element has eight nodes with one degree of freedom at each node. The numerical method and procedure are verified using the results of one and two dimensional analytic solutions and by other researchers. It is shown that the present method presents a consistent and stable results in either abrupt or ranged phase change problems. Moreover, the numerical results by the present method are hardly effected by the calculation time steps which otherwise are difficult to determine in most phase change problems. Finally, as a three-dimensional application, a T-shaped body of a phase change is presented and the temperature and enthalpy variation along the time are solved.

• 대한기계학회논문집B
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• 제29권7호
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• pp.814-819
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• 2005

The phase change heat transfer has been applied to the processes of machines as well as of manufacturing. The cycle in a heat exchanger includes the phase change phenomena of coolant for air conditioning, the solidification in casting process makes use of the characteristics of phase change of metal, and the welding also proceeds with melting and solidification. To predict the phase change processes, the experimental and numerical approaches are available. In the case of numerical analysis, the Enthalpy method is most widely applied to the phase change problem, comparing to the other numerical methods, i.e. the Equivalent Specific Heat method and the Temperature Recovery method. It's because that the Enthalpy method is accurate and straightforward. The Enthalpy method does not include any correction step while the correction of final temperature field is inevitable in the Equivalent Specific Heat method and the Temperature Recovery method. When the temperature field is to be used in the calculation, however, there must be converting process from enthalpy to temperature in the calculation scheme of Enthalpy method. In this study, an improved method for the Equivalent Specific Heat method is introduced whose method dose not include the correction steps and takes temperature as an independent variable so that the converting between enthalpy and temperature does not need any more. The improved method is applied to the solidification process of pure metal to see the differences of conventional and improved methods.

• 한국항공우주학회지
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• 제41권9호
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• pp.700-707
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• 2013

0.4 MW 급 분절형 아크 히터를 장착한 전북대학교 플라즈마 풍동의 초음속 유동 특성 실험을 수행하고 그 결과를 분석하였다. 실험에 사용된 분절형 아크 히터와 초음속 노즐은 16.3 g/s 의 질량유량에 대해 전극 당 150 A, 전체 300 A의 입력전류 조건으로 운전되었으며, 운전 결과 350 kW의 입력전력과 약 51.4 %의 열효율이 계측되었다. 이 때, 아크 히터 내 고엔탈피 플라즈마의 내부압력은 약 4 bar 로 측정되었으며, 이를 초음속 노즐을 통해 압력 45 mbar로 유지되는 진공쳄버 내로 팽창시킴으로써, 전체 엔탈피 11 MJ/kg을 가진 초음속 플라즈마 유동을 얻을 수 있었다. 전체 엔탈피 측정과 함께, 생성된 초음속 플라즈마 유동에 대해 원뿔각 $30^{\circ}$를 가진 원뿔 탐침을 삽입하여 경사 충격파와 이루는 각을 측정하였으며, 이 측정값들로부터, 발생된 초음속 플라즈마의 온도와 마하 수는 각각 약 2,950 K 및 약 3.7에 이를 것으로 예상되었다.

• 한국항공우주학회지
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• 제41권7호
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• pp.547-551
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• 2013

아크제트 유동에서 질량평균 및 중심영역 엔탈피 값을 실험적으로 구하였다. 실험에 사용된 아크제트는 150kW 휼스형으로 가스터빈 엔진 분출냉각 기술 연구를 위한 실험조건을 적용하였다. 질량평균 엔탈피 값은 5.5MJ/kg로 음속목유동 방법을 적용하여 구하였다. 중심영역 엔탈피 값은 14.3MJ/kg으로 열전달 방법을 적용하여 구하였다. 실험결과 아크제트 유동에서 중심영역 대비 질량평균 엔탈피 값의 비는 2.6으로 나타났다.

• 한국세라믹학회지
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• 제27권7호
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• pp.943-951
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• 1990

Steady-state sublimation vapour pressures of anhydrous bismuth triiodide have been measured by the continuous gravimetric Kundsen-effusion method from 430.0 to 558.9 K and equilibrium sublimation pressures were obtained from the steady-state data. Condensation coefficients and their temperature dependence have been derived from the effusiion measurement. Condensation coefficients ranged from 0.159 to 0.048(475 to 500K), the activation enthalpy and entropy for condensation have been obtained as -93.38kTmol-1 and -212.70JK-1mol-1. The standard sublimation enthalpy changes derived by both second(modified sigma function) and third(average enthalpy method) law methods were 138.261$\pm$0.023, 138.74$\pm$0.002kJmol-1 respectively. The standard sublimation entropy change derived by modified sigma function was 191.98$\pm$0.047 JK-1mol-1. The reliable standard sublimation enthalpy change based on a correlation of ΔgcrHom(298.15K) and ΔgcrSom(298.15K), a recommended p(T) equation has been obtained for BiI3(cr) ; 1g(p/Pa)=-C/(T/K)＋5.0711g(T/K)-2.838$\times$10-3(T/K)-7.758$\times$103(K/T)2＋1.4519 where p is in Pa, T in Kelvin, ΔgcrHom(298.15K) in kJmol-1 and C=(ΔgcrHom(298.15K)-8.7358)/1.9146$\times$10-2.

• 대한화학회지
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• 제7권4호
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• pp.264-270
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• 1963

前報에서 誘導한 置換基效果 一般關係式은 溶媒組成에 따르는 常數, Y를 potential energy 項에 代置함으로서 solvolysis 反應에 適用할 수가 있다. 新方程式, $\Delta{\Delta}H^\neq=a'Y+b\Delta{\Delta}S^\neq$, 의 適用性은 文獻에 報告된 35個反應에 對한 直線關係를 調査해 봄으로서 檢討하였다. 結果로 平均 相關係數 0.977을 얻었고, 따라서 이 方程式이 solvolysis反應에 一般的으로 適用됨을 밝혔고, 또 Grunwald-Winstein의 式이 지니는 몇몇 難點을 解決할 수가 있음을 알 수 있었다. enthalypy-entopy 直線效果는 外部 enthalpy와 外部 entropy에 限한 것이며, 嚴格히 말해서 外部 enthalpy entropy 直線效果임을 强調하였다.

• 한국주조공학회지
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• 제13권4호
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• pp.323-332
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• 1993

An implicit finite difference formulation with three methods of latent heat treatment, such as equivalent specific heat method, temperature recovery method and enthalpy method, was applied to solidification analysis. The Neumann problem was solved to compare the numerical results with the exact solution. The implicit solutions with the equivalent specific heat method and the temperature recovery method were comparatively consistent with the Neumann exact solution for smaller time steps, but its error increased with increasing time step, especially in predicting the solidification beginning time. Although the computing time to solve energy equation using temperature recovery method was shorter than using enthalpy method, the method of releasing latent heat is not realistic and causes error. The implicit formulation of phase change problem requires enthalpy method to treat the release of latent heat reasonably. We have modified the enthalpy formulation in such a way that the enthalpy gradient term is not needed, and as a result of this modification, the computation stability and the computing time were improved.

• Smart Structures and Systems
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• 제12권5호
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• pp.579-594
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• 2013

A new enthalpy - based procedure for the homogenization of the electromechanical material parameters of composite piezoelectric modules with integrated electrodes is presented. It is based on a finite element (FE) modeling of the latter's representative volume element (RVE). In contrast to most previously published homogenization approaches that are based on averaged quantities, the presented method uses a direct evaluation of the electromechanical enthalpy. Hence, for the linear orthotropic piezoelectric composite behavior full set of elastic, piezoelectric, and dielectric material parameters, 17 load cases (LC) are used where each load case leads directly to one material parameter. This gives the possibility to elaborate a very strict and easy to program processing. In conjunction with the 17 LC, the enthalpy - based homogenization is particularly suitable for laminated composite piezoelectric modules with integrated electrodes. In this case, the electric load has to be given at the electrodes rather than at the RVE FE model boundaries. The proposed procedure is validated through its comparison to literature available results on a classical 1-3 piezoelectric micro fiber (longitudinally polarized) reinforced composite and a $d_{15}$ shear piezoelectric macro-fiber (transversely polarized) composite module.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2001년도 춘계 학술대회논문집
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• pp.176-180
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• 2001

For windshield defrosting, flow analysis of inner room(vehicle) and heat conduction on the windshield surface are undertaken. Simulation for defrosting enthalpy method is usedand verification of heat and fluid flow analysis for room is done in cavity flow. The defrosting process is three dimensional phenomena and phase is changing. The result of defrosting analysis are well presenting the phase change and these results offer basic design data for defrosting phenomena.

• International Journal of Air-Conditioning and Refrigeration
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• 제12권4호
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• pp.214-219
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• 2004

A few commonly used correlation equations of the enthalpy of vaporization are reviewed and a new three-parameter correlation equation is proposed. Performance of the pro­posed equation is examined using the data listed in the ASHRAE table for 22 pure substance refrigerants. The new equation yields an average absolute deviation of $0.14\%$ for 22 refrig­erants, which is better than those of other equations, such as Xiang $(0.18\%),$ Majer-Svoboda­Pick $(0.18\%),$ and Somayajulu equation $(0.23\%)$.