• Title/Summary/Keyword: enrichment

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Wet Deposition of Heavy Metals during Farming Season in Taean, Korea (태안지역 강우의 중금속 함량 평가)

  • Jung, Goo-Bok;Kim, Min-Kyeong;Lee, Jong-Sik;Kim, Won-Il;Kim, Gun-Yeob;Ko, Byong-Gu;Kang, Kee-Kyung;Kwon, Soon-Ik
    • Korean Journal of Environmental Agriculture
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    • v.30 no.2
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    • pp.153-159
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    • 2011
  • BACKGROUND: This experiment was conducted to investigate the distribution and burden characteristics of heavy metal in the rainwater sampled at Taean area, in the middle part of Korea, from April 2002 to October 2003. METHODS AND RESULTS: The relationship between concentration of heavy metal and other chemical properties in the rainwaters was also evaluated. Chemical properties in the rainwater were various differences with raining periods and years. It appeared that a weighted average pH values of rainwater was ranged from 5.0 to 5.1. Heavy metal concentrations in the rainwater were ranked as Pb > Zn > Cu > Ni > As > Cr > Cd. As compared with heavy metal concentrations of rainwater in 2002, Cu, Pb, and Zn were higher than other elements in 2003. There were positive correlation between major ionic components, such as ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$, ${SO_4}^{2-}$ and ${NO_3}^-$, and As, Cd, Zn, Cr, and Ni concentrations in rainwater. For heavy metal distribution of rainwater, the order of average enrichment factor was Cd > Pb > As > Cu > Zn > Ni > Cr, and these were relatively higher than the natural components such as Fe, Mg and Ca. The monthly enrichment factor were relatively high, from August to October at Taean. The monthly amount of heavy metal precipitation was high in the rainy season from July to August because of great influence of rainfall. CONCLUSION(s): The results of this study suggest that the heavy metals(Cd, Pb, As, Cu, and Zn) of rainwater is strongly influenced by anthropogenic sources rather than natural sources.

Investigation of PWR Spent Fuels for the Design of a Deep Geological Repository (심층처분시스템 설계를 위한 경수로 사용후핵연료 현황 분석)

  • Cho, Dong-Keun;Kim, Jungwoo;Kim, In-Young;Lee, Jong-Youl
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.3
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    • pp.339-346
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    • 2019
  • Based on the $8^{th}$ Basic Plan for Electric Power Demand and Supply, an estimation has been made for inventories and characteristics of spent fuel (SF) to be generated from existing and planned nuclear power plants. The characteristics under consideration in this study are dimensions, fuel array, $^{235}U$ enrichment, discharge burnup, and cooling time for each fuel assembly. These are essentially needed for designing a disposal facility for SFs. It appears that the anticipated quantity by the end of 2082 is about 62,500 assemblies for PWR SFs. The inventories of Westinghouse-type and Korean-type SFs were revealed to be 60% and 40%, respectively as of the end of 2018. The proportion of SFs with initial $^{235}U$ enrichment below 4.5 weight percent (wt%) was shown to be approximately 90% in total as of the end of 2018. As of 2077, more than 97% of SFs generated from Westinghouse-type nuclear reactors were shown to have cooling time of over 50 years. As of 2125, more than 98% of SFs generated from Korean-type nuclear reactors were shown to have cooling time of over 45 years. Based on these results, for the efficient design of a disposal system, it is reasonable to adopt two types of reference spent fuel. SF of KSFA with $^{235}U$ enrichment of 4.5 wt%, discharge burnup of 55 GWd/tU, and cooling time of 50 years was determined as reference fuel for Westinghouse-type SFs; SF of PLUS7 with $^{235}U$ enrichment of 4.5 wt%, discharge burnup of 55 GWd/tU, and cooling time of 45 years was determined as reference fuel for Korean-type SFs.

Degradation of Anthracene by a Pseudomonas strain, NGK1

  • Shinde Manohar;Kim, Chi-Kyung;Tim
    • Journal of Microbiology
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    • v.37 no.2
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    • pp.73-79
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    • 1999
  • Pseudomonas sp. NGK1, isolated by naphthalene enrichment culture technique, is capable of degrading anthracene as a sole source of carbon and energy. The organism degraded anthracene through the intermediate formation of 1,2-dihydroxyanthracene, 2-hydroxy-3-naphthoic acid, salicylate, and catechol. The intermediates were isolated and characterized by TLC, spectrophotometry, and HPLC analysis. The cell free extract of anthracene-grown cells showed activities of anthracene dioxygenase, 2-hydroxy-3-naphthylaldehyde dehydrogenae, 2-hydroxy-3-naphthoate hydroxylase, salicylate hydroxylase and catechol 2,3-dioxygenase. The formed catechol as a metabolite is degraded through meta-cleavage with the formation of ${\alpha}$-hydroxymuconic semi-aldehyde.

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Optimal Resolution of L-Carnitine from Racemic DL-Carnitine by Enterobacter sp. Assimilating D-Carnitine

  • Hwang, Ki-Chul;Bang, Won-Gi
    • Journal of Microbiology and Biotechnology
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    • v.7 no.5
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    • pp.318-322
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    • 1997
  • In order to isolate a microorganism having preferential degradation of D-carnitine from DL-carnitine, a bacterium assimilating D-carnitine as a sole carbon and energy source was isolated from soil by enrichment culture and partially identified as Enterobacter sp. Also, a mutant having lessened L-carnitine decomposition rates was selected with nitrosoguanidine mutagenesis, which led to decrease the specific activities of carnitine dehydrogenase (7.6-fold) and ${\beta}$-hydroxybutyrate dehydrogenase (9.5-fold) as compared to the wild strain. Meanwhile, optimal culture conditions for optical resolution of DL-carnitine were investigated. Under optimal conditions, 3.53 g/l L-carnitine was obtained from 20 g/l DL-carnitine, which corresponded to 35.3% L-carnitine yield and 97.9% optical purity.

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Characterization of a New Acidophilic Acetobacter sp. Strain HA Isolated from Korean Traditional Fermented Vinegar

  • CHUN, HONG-SUNG;SUNG-JUN KIM
    • Journal of Microbiology and Biotechnology
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    • v.3 no.2
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    • pp.108-114
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    • 1993
  • A new strain of acidophilic, acetogenic bacterium, Acetobacter sp. strain HA was isolated by selective enrichment from the traditionally fermented rice wine vinegar in Korea. It was a gram-negative, non-motile short rod and oxidized acetate and lactate. The optimal temperature and pH for growth were $28^{\circ}C$ and 4.0, respectively. The strain HA differed from other Acetobacter species by growing well on methanol, xylitol, inositol, dulcitol, D-xylose, L-arabinose, and D-mannose as sole sources of carbon and energy. The isolated strain HA did not produce $\gamma$-pyrones from glucose and did not produce ketone bodies from glycerol. The quinone system used in this study was an ubiquinone-9 isoprene unit. The guanine-plus-cytosine content of the DNA was 50.7 mol%, and the major cellular fatty acids were $C_{18:1} and C_{16:0}$.

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Single Drop Microextraction for Analysis of Mustard Gas(HD) (수포작용제(HD) 분석을 위한 단일방울 미세농축법 연구)

  • Park, Yang-Ki;Kim, Sung-Ki;Son, Byung-Hoon;Park, Myeong-Ju
    • Journal of the Korea Institute of Military Science and Technology
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    • v.11 no.2
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    • pp.95-100
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    • 2008
  • A fast, simple, inexpensive, and reproducible sample preparation for extraction and analysis of HD in water was studied using single-drop microextraction(SDME) and GC-MS. Operation parameters, such as extraction solvent, extraction time were optimized. The optimized conditions were $1\{mu}L$ trichloroethylene and 10 min extraction time. In these conditions, about 42 times higher enrichment factor(EF) was obtained. The detection limit of HD was $1\{mu}g/L$, and the precision expressed as relative standard deviation was about 9.0%.

Physical Properties and Permeation Characteristics of Polysulfone group(PS/PES/PPS) membrane for Gas Permeation (비대칭 Polysulfone계(PS/PES/PPS)막 제조시 물리적 인자의 영향 및 기체투과 특성)

  • Park, Young-Hae
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.1
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    • pp.77-85
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    • 2001
  • This paper was to investigate the preparation of polysulfone(PS), polyethersulfone(PES) and polyphenylsulfone(PPS) membrane. The thermal property of PPS was higher than that of others. From the result of SEM, the concentration of polymer was found to have a significant effect on the structure of membrane, and the structure of membrane made of PES is found to have regular micell form of asymmetry. Permeability and selectivity for oxygen and nitrogen gas in the air were analyzed by GC. Permeabilities of the membrane made of PES for oxygen and nitrogen in air, 1.5 and $0.7(x10^9[cm^3(STP)cm/cm^2seccmHg]) $, respectively was higher than that of others. and Selectivity of the membrane made of PPS for oxygen to nitrogen gas in air was 2.9.

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Effects of Employees' Job Characteristics, Commitment, and Self-Leadership on Organizational Citizenship Behavior

  • Eom, Keun;Yang, Hoe-Chang
    • Journal of Distribution Science
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    • v.12 no.7
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    • pp.13-21
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    • 2014
  • Purpose - This study reveals antecedent factors to help develop expressway rest areas in which employees were exposed to inferior environments, using Hackman and Oldham's Job Characteristics Theory. Research design, data, and methodology - The survey was conducted on 148 expressway rest area employees in Gyeonggi-do. After excluding questionnaires with invalid responses, 141 questionnaires were analyzed. Results - The sub-factors of job characteristics had a positive influence on the organizational commitment of employees, and organizational commitment had a positive influence on organizational citizenship behavior (OCB). Further, the results of mediation effects showed that organizational commitment and self-leadership were partially mediated. Finally, the results of the moderation effect of self-leadership showed that self-leadership was thought to be vital to let members endeavor to promote the competitiveness of expressway rest areas. Conclusions - The expressway rest area company needed to design jobs to let employees be self-motivated, productive, positive, responsible, and aspirational; job redesign, including job enrichment and job enlargement can be considerably helpful for affirmative influence.

Development of finite 'crack' element (균열 유한 요소의 개발)

  • 조영삼;전석기;임세영
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2004.04a
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    • pp.381-388
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    • 2004
  • We propose a 2D 'crack' element for the simulation of propagating crack with minimal remeshing. A regular finite element containing the crack tip is replaced with this novel crack element, while the elements which the crack has passed are split into two transition elements. Singular elements can easily be implemented into this crack element to represent the crack-tip singularity without enrichment. Both crack element and transition element proposed in our formulation are mapped from corresponding master elements which are commonly built using the moving least-square (MLS) approximation only in the natural coordinate. In numerical examples, the accuracy of stress intensity factor K/sub I/ is demonstrated and the crack propagation in a plate is simulated.

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Structure and chemical composition of $CsB_{3}O_{5}$ (CBO) optical surface

  • V.V. Atuchin;V.G. Kesler;L.D. Pokrovsky;N. Yu. Maklakova;M. Yoshimura;N. Ushiyama;T. Matsui;K. Kamimura;Y. Mori;T. Sasaki
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.1
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    • pp.19-23
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    • 2003
  • Polished surface of $CsB_{3}O_{5}$ (CBO) has been observed by reflection high energy electron diffraction (RHEED) and X-ray photoelectron spectroscopy (XPS). For comparison, electronic properties of CBO powder have been studied by XPS. It has been found that the crystal surface is covered by thick amorphous layer with chemical composition closely related to that of CBO. Great enrichment of top surface by cesium, ~30 % in reference to the bulk of the modified layer, has been displayed by depth profiling.