• 한국세라믹학회지
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• 제26권4호
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• pp.539-549
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• 1989

Polycrystalline TiO2 thin films were deposited on Si and Al2O3 substrates by CVD method. Ethyl titanate, Ti(OC2H5)4, was used as a source material for Ti and O, and Ar was used for carrier gas. In the surface chemical reaction controlled deposition condition, the apparent activation energy of 6.74 Kcal/mole was obtained, and the atomic adsorption on substrate surface was proved to be governed by Rideal-Elley mechanism. In the mass transfer controlled deposition condition, the deposition rate was in a good agreement with the result which was calculated by the simple boundary layer theory. It was also observed that TiO2 thin films show different surface morphology according to the different deposition mechanism, which was fixed by deposition conditions. This phenomenon could be well explained by the surface perturbation theory.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3218-3222
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• 2013

The aminolyses, anilinolysis and pyridinolysis, of bis(2-oxo-3-oxazolidinyl) phosphinic chloride (1) have been kinetically investigated in acetonitrile at 55.0 and $35.0^{\circ}C$, respectively. For the reactions of 1 with substituted anilines and deuterated anilines, a concerted SN2 mechanism is proposed based on the selectivity parameters and activation parameters. The deuterium kinetic isotope effects ($k_H/k_D$) invariably increase from secondary inverse to primary normal as the aniline becomes more basic, rationalized by the transition state variation from a backside to a frontside attack. For the pyridinolysis of 1, the authors propose a stepwise mechanism with a rate-limiting step change from bond breaking for more basic pyridines to bond formation for less basic pyridines based on the selectivity parameters and activation parameters. Biphasic concave upward free energy relationship with X is ascribed to a change in the attacking direction of the nucleophile from a frontside attack with more basic pyridines to a backside attack with less basic pyridines.

• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2260-2264
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• 2012

The kinetics and mechanism of the pyridinolysis ($XC_5H_4N$) of dimethyl isothiocyanophosphate are investigated in acetonitrile at $55.0^{\circ}C$. The Hammett and Br$\ddot{o}$nsted plots for substituent X variations in the nucleophiles exhibit two discrete slopes with a break region between X = 3-Ac and 4-Ac. These are interpreted to indicate a mechanistic change at the break region from a concerted to a stepwise mechanism with a rate-limiting expulsion of the isothiocyanate leaving group from the intermediate. The relatively large ${\beta}x$ values imply much greater fraction of frontside nucleophilic attack TSf than that of backside attack TSb. The steric effects of the two ligands play an important role to determine the pyridinolysis rates of isothiocyanophosphates.

• 에너지공학
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• 제25권1호
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• pp.56-68
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• 2016

최근 원자력 발전소의 안전성을 획기적으로 향상시키기 위한 연구가 활발하게 진행되고 있으며 특히 피동냉각계통의 연구개발이 아주 중요하게 부각되고 있다. 피동냉각계통의 열전달 방식으로는 응축열전달 양식이 주로 채택되고 있다. 이와 같은 맥락에서 부산대학교 Ahn & Yun (Ahn 등, 2014)은 새로운 수평관내부 응축 모델을 제시한 바 있다. 본 연구에서는 먼저 Ahn & Yun 이 제시한 수평관 응축 모델을 MARS 코드에 삽입하고 PASCAL 실험데이터를 이용하여 평가하였다. 이 평가결과를 통해 Ahn & Yun 모델의 코드적용에 있어 문제점을 규명하고 새로운 적용방법론을 적용하여 다양한 실험데이터로 다시 평가함으로써 MARS 코드의 향상된 응축 열전달 해석 능력을 확인하였다.

• Steel and Composite Structures
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• 제31권6호
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• pp.541-558
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• 2019

In Special Concentrically Braced Frames (SCBFs), vertical and horizontal components of the brace force must be resisted by column and beam, respectively but normal force component existing at the gusset plate-to-column and beam interfaces, creates out-of-plane action making distortion in column and beam faces adjacent to the gusset plate. It is a main concern in Hollow Structural Section (HSS) columns and beams where their webs and gusset plate are not in the same plane. In this paper, a new gusset plate passing through the HSS columns and beams, named as through gusset plate, is proposed to study the force transfer mechanism in such gusset plates of SCBFs compared to the case with conventional gusset plates. For this purpose, twelve SCBFs with diagonal brace and HSS columns and twelve SCBFs with chevron brace and HSS columns and beams are considered. For each frame, two cases are considered, one with through gusset plates and the other with conventional ones. Based on numerical results, using through gusset plates prevents distortion and out-of-plane deformation at HSS column and beam faces adjacent to the gusset plate helping the entire column and beam cross-sections to resist respectively vertical and horizontal components of the brace force. Moreover, its application increases energy dissipation, lateral stiffness and strength around 28%, 40% and 32%, respectively, improving connection behavior and raising the resistance of the normal force components at the gusset plate-to-HSS column and beam interfaces to approximately 4 and 3.5 times, respectively. Finally, using such through gusset plates leads to better structural performance particularly for HSS columns and beams with larger width-to-thickness ratio elements.

• 한국태양에너지학회 논문집
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• 제28권6호
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• pp.58-63
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• 2008

It is essential to investigate the structure and the main characteristic of Home USN (Ubiquitous Sensor Network) technologies in built ubiquitous environment while designing bio-sensors. For this study, Thermistor elements and Thermopile black body have been selected to implement ubiquitous technologies for bio-sensors and wireless network such as WiBro has been used to transfer sensing data to the BSN (Bio-Sensor Network) gateway. It is certain that efficiency of ubiquitous space design is improved if main components of each specific sensor network are analyzed precisely in digital way and corresponding communication modules are prepared accordingly. Ubiquitous technology, in conclusion, has to be applied not only with systematical mechanism or electronic setting but in human-centered atmosphere as well, keeping with deep consideration for bio-housing service factors in eco-friendly surrounding.

• 스마트미디어저널
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• 제3권1호
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• pp.28-32
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• 2014

It is practical nowadays to automate data recording in order to prevent loss and tampering of records. There are existing technologies that satisfy this needs and one of them is wireless sensor networks (WSN). Wireless body sensor networks (WBSN) are wireless networks and information-processing systems which are deployed to monitor medical condition of patients. In terms of performance, WBSNs are restricted by energy, and communication between nodes. In this paper, we focused in improving the performance of communication to achieve less energy consumption and to save power. The main idea of this paper is to prioritize nodes that exhibit a sudden change of vital signs that could put the patient at risk. Cluster head is the main focus of this study in order to be effective; its main role is to check the sent data of the patient that exceeds threshold then transfer to the sink node. The proposed scheme implemented added a time-based protocol to sleep/wakeup mechanism for the sensor nodes. We seek to achieve a low energy consumption and significant throughput in this study.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2004년도 춘계학술대회
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• pp.1613-1618
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• 2004

Diffuser is an important fluid-mechanical equipment to convert kinetic energy into pressure energy. Many of the experimental and theoretical researches have been done in a diffuser but the understanding of energy transfer and detailed mechanism of energy dissipation is unclear. In this study, computations were performed using a numerical method with SIMPLE algorithm for conical diffuser with various diffuser angles and diffuser lengths. Also, we investigated the pressure recovery coefficient in conical diffuser by inserting strut. In this paper, we showed that the strut can cause a rising pressure recovery.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 학술대회 논문집 전문대학교육위원
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• pp.172-174
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• 2002

Concerns for wind energy as alternative energy have been highly increased, because of the problems such as the global warming effect, environmental pollution, the exhausting fossil fuel, and so on. Recently, the number of variable-speed wind turbines adopted pitch control apparatus has increased. In this paper, the mechanism between the wind energy and power generating system has been presented to specify the relationship of the energy transfer using the Pitch Control.

• 한국공간구조학회논문집
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• 제13권3호
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• pp.45-55
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• 2013

The core aim of this paper is to empirically scrutinize a strength characteristic and ductility of the beam-column frame of reinforced with steel subjected to the cyclic lateral load. First and foremost, I the author embarks upon making four prototypes vis-$\grave{a}$-vis this research. Through this endeavour, the author has analysed cyclic behavior, fracture shape, ductility and energy dissipation of the normal beam-column frame and a beam-column frame of reinforced with steel. In addition, the survey has revealed the exact stress transfer path and the destructive mechanism in order to how much a beam-column frame of reinforced with steel has resistance to earthquake regarding all types of building, as well as school construction. To get the correct data, the author has compared the normal beam-column frame and three types of the beam-column frame of reinforced with steel following these works, the characteristic of cyclic behavior, destructive mechanism, ductility, and Energy dissipation of normal beam-column frame and a beam-column frame of reinforced with steel have been examined clearly.