• 제목/요약/키워드: energy storage properties

검색결과 575건 처리시간 0.028초

Investigating InSnZnO as an Active Layer for Non-volatile Memory Devices and Increasing Memory Window by Utilizing Silicon-rich SiOx for Charge Storage Layer

  • Park, Heejun;Nguyen, Cam Phu Thi;Raja, Jayapal;Jang, Kyungsoo;Jung, Junhee;Yi, Junsin
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.324-326
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    • 2016
  • In this study, we have investigated indium tin zinc oxide (ITZO) as an active channel for non-volatile memory (NVM) devices. The electrical and memory characteristics of NVM devices using multi-stack gate insulator SiO2/SiOx/SiOxNy (OOxOy) with Si-rich SiOx for charge storage layer were also reported. The transmittance of ITZO films reached over 85%. Besides, ITZO-based NVM devices showed good electrical properties such as high field effect mobility of 25.8 cm2/V.s, low threshold voltage of 0.75 V, low subthreshold slope of 0.23 V/dec and high on-off current ratio of $1.25{\times}107$. The transmission Fourier Transform Infrared spectroscopy of SiOx charge storage layer with the richest silicon content showed an assignment at peaks around 2000-2300 cm-1. It indicates that many silicon phases and defect sources exist in the matrix of the SiOx films. In addition, the characteristics of NVM device showed a retention exceeding 97% of threshold voltage shift after 104 s and greater than 94% after 10 years with low operating voltage of +11 V at only 1 ms programming duration time. Therefore, the NVM fabricated by high transparent ITZO active layer and OOxOy memory stack has been applied for the flexible memory system.

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단롤주조법에 의한 Ti-Nb-Cr 합금의 제조와 수소화 특성 평가 (Evaluation of Hydrogenation Properties on Ti-Nb-Cr Alloys by Single-Roll Melt Spinning)

  • 김경일;홍태환
    • 대한금속재료학회지
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    • 제47권7호
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    • pp.433-439
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    • 2009
  • Ti and Ti based hydrogen storage alloys have been thought to be the third generation of alloys with a high hydrogen capacity, which makes it difficult to handle because of high reactivity. In order to solve the problem, the activation of a wide range of hysteresis of hydriding/dehydriding and without degradation of hydrogen capacity due to the hydriding/dehydriding cycle have to be improved in order to be aplied. Ti-Cr alloys have a high capacity about 0.8 wt.% in an ambient atmosphere. When the Ti-Cr alloys are added to Nb and Ta elements, they formed a laves phase in the alloy system. The Nb element was expected to make easy diffuse hydrogen in the Ti-Cr storage alloy, which was a catalytic element. In this study, the Ti-Nb-Cr ternary alloy was prepared by melt spinning. As-received specimens were characterized using XRD (X-ray Diffraction), SEM (Scanning Electron Microscopy) with EDX (Energy Dispersive X-ray) and TG/DSC (Thermo Gravimetric Analysis/Differential Scanning Calorimetry). In order to examine hydrogenation behavior, the PCI (Pressure-Composition-Isotherm) was performed at 293, 323, 373 and 423 K.

고성능 에너지 저장 소자를 위한 니켈 구조체에 담지된 니켈 코발트 수산화물의 나노 형상 제어 (Nano-Morphology Design of Nickel Cobalt Hydroxide on Nickel Foam for High-Performance Energy Storage Devices)

  • 신동요;윤종천;하철우
    • 한국재료학회지
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    • 제31권12호
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    • pp.710-718
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    • 2021
  • Recently, due to high theoretical capacitance and excellent ion diffusion rate caused by the 2D layered crystal structure, transition metal hydroxides (TMHs) have generated considerable attention as active materials in supercapacitors (or electrochemical capacitors). However, TMHs should be designed using morphological or structural modification if they are to be used as active materials in supercapacitors, because they have insulation properties that induce low charge transfer rate. This study aims to modify the morphological structure for high cycling stability and fast charge storage kinetics of TMHs through the use of nickel cobalt hydroxide [NiCo(OH)2] decorated on nickel foam. Among the samples used, needle-like NiCo(OH)2 decorated on nickel foam offers a high specific capacitance (1110.9 F/g at current density of 0.5 A/g) with good rate capability (1110.9 - 746.7 F/g at current densities of 0.5 - 10.0 A/g). Moreover, at a high current density (10.0 A/g), a remarkable capacitance (713.8 F/g) and capacitance retention of 95.6% after 5000 cycles are noted. These results are attributed to high charge storage sites of needle-like NiCo(OH)2 and uniformly grown NiCo(OH)2 on nickel foam surface.

Compact CNS shear box를 활용한 모의 절리암석시료의 정적 전단 거동에 관한 연구 (Study of the Static Shear Behaviors of Artificial Jointed Rock Specimens Utilizing a Compact CNS Shear Box)

  • 김한림;민경조;김경규;김영준;윤경재;양주석;배상호;조상호
    • 터널과지하공간
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    • 제33권6호
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    • pp.574-593
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    • 2023
  • 본 연구에서는 절리면 암석 시료에 대한 직접 전단시험을 수행하기 위해 새로 고안된 Compact CNS shear box의 성능과 적용 가능성에 대해 조사하였다. 정적 CNS 절리면 직접 전단시험은 인공적으로 거칠기를 생성한 절리 암석을 대상으로 실시하였으며 절리면 거칠기 계수 및 초기 수직응력 조건을 변화시키면서 수행하였다. 또한, DIC 분석을 통해 변위 데이터 검증 및 파괴 패턴을 관찰하였고 실험으로부터 도출된 전단 특성들을 기존에 연구되었던 전단 거동 예측 모델들과 비교분석하였다. 그 결과 기존의 특정 경험적 전단 거동 예측 모델과 높은 상관관계를 나타내는 것을 확인하였으며 전단 거동 특성이 파괴 패턴과 관련이 있을 가능성에 대해 고찰하였다. 결론적으로, 절리면 전단 특성에 대한 데이터를 제공하는데 있어서 CNS 전단 박스의 적용 가능성과 효과를 입증하였다.

양송이의 관능적 특성에 대한 감마에너지의 영향 (Organoleptic Characteristics of Mushrooms (Agaricus bisporus) As Functions of Post-Irradiation Period)

  • 권중호;변명우;김석원;양재승;차보숙;조한옥
    • 한국식품과학회지
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    • 제22권3호
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    • pp.285-289
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    • 1990
  • 양송이의 신선도 연장을 위한 감마선조사가 버섯의 관능적 특성에 미치는 영향을 채점시험으로 평가해 보았다. $1{\sim}3kGy$의 감마선은 조사 직후 양송이의 견고도를 유의적으로 감소시켰으나(p<0.05), 시료의 외관, 향 및 맛에는 영향을 미치지 않았다. 저장기간 중$(9{\pm}1^{\circ}C,\;80{\pm}7%\;RH)$ 버섯의 관능적 품질평가에서 일간 저장된 시료는 외관(p<0.01), 조직 (p<0.01), 향(p<0.01) 및 맛(p<0.01)에 있어서 처리구간에 고도의 유의차를 나타내어 무처리 대조시료는 저장 후 1주 이내에 별질 되었으나 조사구는 17일 이후에도 식용이 가능한 것으로 평가되었다.

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MgHx-Sc2O3 복합재료의 수소화 특성 (Hydrogenation Properties on MgHx-Sc2O3 Composites by Mechanical Alloying)

  • 김경일;김용성;홍태환
    • 한국수소및신에너지학회논문집
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    • 제21권2호
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    • pp.81-88
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    • 2010
  • Hydrogen energy applications have recognized clean materials and high energy carrier. Accordingly, Hydrogen energy applies for fuel cell by Mg and Mg-based materials. Mg and Mg-based materials are lightweight and low cost materials with high hydrogen storage capacity. However, commercial applications of the Mg hydride are currently hinder by its high absorption/desorption temperature, and very slow reaction kinetics. Therefore one of the most methods to improve kinetics focused on addition transition metal oxide. Addition to transition metal oxide in $MgH_x$ powder produce $MgH_x$-metal oxide composition by mechanical alloy and it analyze XRD, EDS, TG/DSC, SEM, and PCT. This report considers kinetics by transition metal oxide rate and Hydrogen pressure. In this research, we can see behavior of hydriding/dehydriding profiles by addition catalyst (transition metal oxide). Results of PCI make a excellent showing $MgH_x$-5wt.% Sc2O3 at 623K, $MgH_x$-10wt.% $Sc_2O_3$ at 573K.

바나듐 산화환원 흐름전지를 위한 음이온교환막의 관능기에 따른 특성 연구 (A Study on the Effect of Different Functional Groups in Anion Exchange Membranes for Vanadium Redox Flow Batteries)

  • 이재명;이미순;남기석;전재덕;윤영기;최영우
    • 멤브레인
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    • 제27권5호
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    • pp.415-424
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    • 2017
  • 바나듐 산화환원 흐름 전지에 핵심적으로 사용되는 이온교환막은 일반적으로 양이온교환막을 사용하고 있으나 co-ion인 바나듐 이온의 투과에 의한 장기적 성능 저하 문제를 해결하기 어렵다. 따라서 본 연구에서는 바나듐 투과도 및 장기 운전 안정성의 특성을 파악하기 위해 세 가지 다른 관능기를 보유한 음이온교환막을 제조하였다. 기저막으로는 다공성 폴리에틸렌 필름에 benzyl chloride (VBC)과 divinylbenzene (DVB)을 충진 및 가교 중합하여 제조한 후, 세 가지 다른 아민 관능기를 각각 도입하였다. 제조된 음이온교환막들에 대해 바나듐 이온 투과 정도 및 장기 운전 안정성을 관찰한 결과 triethylamine을 관능기로 적용한 음이온교환막에서 높은 에너지효율을 유지하면서도 가장 장기적 운전 안정성을 확보할 수 있었다.

Ni-MH 2차 전지용 Zr계 수소저장합금전극의 특성에 미치는 치환원소(Co, Cr, Fe)의 영향 (The effect of substitution elements(Co, Cr, Fe) on the properties of Zr-based hydrogen storage alloy electrode for Ni-MH secondary battery)

  • 최승준;정소이;서찬열;최전;박충년
    • 한국수소및신에너지학회논문집
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    • 제10권3호
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    • pp.185-189
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    • 1999
  • Effects of alloy modification with the $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy for an electrode use have been investigated. For the alloy composition, a part of Mn was substituted by Co, Cr and Fe. The experimental results showed that Co accelerated activation of alloy, and Fe and Cr improved the discharge capacity. These results agree with P-C-T curves of each alloy. But substituting Fe for Mn showed the decrease of the discharge capacity when discharged at high rate (60mA, about 1C rate). Considering both the discharge capacity and the high rate discharge property, $Zr_{0.6}Ti_{0.4}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy was found to be the best alloy among the alloys subjected to the test.

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보조에너지원으로서의 수퍼커패시터용 나노전극소재로서의 탄소/망간산화물의 전기화학적 특성 (Electrochemical Properties of Manganese Oxide coated onto Carbon Nanotubes for Energy Storage Applications)

  • 안균영;마상복;김광범
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.143-146
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    • 2007
  • Birnessite-type manganese dioxide($MnO_2$) was coated uniformly onto carbon nanotubes (CNTs) through a spontaneous direct redox reaction between CNTs and permanganate ions($MnO_4\;^-$). The initial specific capacitance of the $MnO_2/CNT$ nanocomposite in an organic electrolyte at a large current density of 1 A/g was 250 F/g, which is equivalent to 139 mAh/g based on the total weight of the electrode material including the electroactive material, conducting agent and binder. The specific capacitance of the $MnO_2$ in the $MnO_2/CNT$ nanocomposite was as high as 580 F/g (320 mAh/g), indicating excellent electrochemical utilization of the $MnO_2$. The addition of CNTs as a conducting agent can improve the high rate capability of $MnO_2/CNT$ nanocomposite considerably. An analysis of the in-situ X-ray absorption near-edge structure (XANES) showed an improvement in the structural and electrochemical reversibility of the $MnO_2/CNT$ nanocomposite by heat-treatment.

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펨토초 레이어 기반 유리 내부가공 특성 (Characteristic of the femtosecond laser machining in glass)

  • 유병헌;김영미;조성학;장원석;김재구;황경현;이동주
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.239-240
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    • 2006
  • For longer than picosecond pulses, bulk damage inside defect-free dielectrics involves the heating and multiplication of spurious electrons by the incident laser beam and transfer of this energy to the lattice. The situation is quite different for femtosecond pulses which are shorter than the time scale for electron energy transfer to the lattice. Damage caused by these pulses is produced with smaller statistical uncertainty and is controllable on a microscopic scale. These properties can be exploited to produce laser devices such as arrays of damage dots for all optical memories with high data storage density or arrays of parallel grooves to form transmission gratings. In this work, we observed characteristic of the femtosecond laser machining in BK7 and fused silica.

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