• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.30 no.9
• /
• pp.583-588
• /
• 2017

Thermal batteries are used in military power sources that require robustness and long storage life for applications in missiles and torpedoes. $FeS_2$ powder is currently used as a cathode material because of its high specific energy density, environmental non-toxicity, and low cost. $MS_2$ (M = Fe, Ni, Co) cathodes have been explored as novel candidates for thermal batteries in many studies; however, the discharge characteristics (1, 2, 3 plateau) of single cells in thermal batteries with different cathodes have not been elucidated in detail. In this study, we independently analyzed the discharge voltage and calculated the total polarizations of single cells using $MS_2$ cathodes. Based on the results of this study, we propose $NiS_2$ as a potential cathode material for use in thermal batteries.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.26 no.8
• /
• pp.1709-1718
• /
• 2002

It is well recognized that improving capacity of positive grid in battery is one of key factors for controlling the expected long lift-time of Battery Energy Storage System(B.E.S.S). Thus it is really important to characterized material properties of positive grid which are mainly affected by fabrication process. In this study, two kinds of positive grids, which were fabricated by gravity casting and die-casting technique were used. Micro-structural observation and tensile test were conducted to investigate the effect of fabrication process of positive grid. Ultrasonic measurement based on pulse-echo method and ultrasonic C-scan technique also performed to correlate ultrasonic velocity with porosity ratio in positive grid. It was found that the porosity ratio of grid fabricated by gravity casting technique increased significantly compared to the grid fabricated by die-casting technique. It was also shown that ulrasonic technique is effective to evaluate the porosity ratio in positive grid.

• KEPCO Journal on Electric Power and Energy
• /
• v.5 no.4
• /
• pp.337-341
• /
• 2019

In this study, the effects of two materials, active alumina and CaO based inorganic binder, which cause the side reaction on the K₂CO₃-based solid CO₂ sorbents was investigated. K₂CO₃-based solid sorbents called KAM series was prepared by spray drying method and then measured its physical properties and CO₂ sorption capacity. Among the KAM series sorbents, KAM(0.5) maintained high CO₂ sorption capacity of 7.6 wt% after 3 cycle of sorption/regeneration reaction and showed very low attrition loss as low as 3.1 % which was measured by ASTM D5757-95.

• Transactions on Electrical and Electronic Materials
• /
• v.17 no.5
• /
• pp.239-251
• /
• 2016

The potential of nanocomposites have been drawing the intention of the researchers from energy storage to electrical insulation applications. Nanocomposites are known to improve dielectric properties, such as the increase in dielectric breakdown strength, suppressing the partial discharge (PD) as well as space charge, and prolonging the treeing, etc. In this review, different theories have been established to explain the reactions at the interaction zone of polymer matrix and nanofiller; the characterization methods of nanocomposites are also presented. Furthermore, the remarkable findings in the fields of epoxy, cross-linked polyethylene (XLPE), polypropylene and polyvinyl chloride (PVC) nanocomposites are reviewed. In this study, it was observed that there is lack of comparison between results of lab scale specimens and actual field aged cables. Also, non-standardization of the preparation methods and processing parameters lead to changes in the polymer structure and its surface degradation. However, on the positive side, recent attempt of 250 kV XLPE nanocomposite HVDC cables in service may deliver a promising performance in the coming years. Moreover, materials such as self-healing polymer nanocomposites may emerge as substitutes to traditional insulations.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.406-409
• /
• 2009

In this work, the magnetite ($Fe_3O_4$)/multi-walled carbon nanotubes (MWNTs) composites for lithium secondary battery were prepared. Nano-$Fe_3O_4$ was deposited by chemical coprecipitation of $Fe^{2+}$ and $Fe^{3+}$ in the presence of MWNTs in alkaline solutions. Transmission electron spectroscopy (TEM) and X-ray diffraction (XRD) analyses indicated that nano-$Fe_3O_4$ particles had a good crystallinity of cubic specimens and many tiny particles attached on the surfaces of the MWNTs. The electrochemical properties of $Fe_3O_4$/MWNTs composites as anodes in lithium-secondary batteries were evaluated by cyclic voltammetry and galvanostatic charge/discharge techniques. The as-prepared $Fe_3O_4$/MWNTs composites showed an initial lithium storage capacity of 1120 mAh/g and a reversible capacity of 394 mAh/g after 100 cycles, demonstrating better performance than that of the commercial graphite anode materials.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.6
• /
• pp.1799-1805
• /
• 2014

In this article, we described about the preparation and electrochemical properties of a flexible energy storage system based on a plastic polyethylene terephthalate (PET) substrate. The PET treated with UV/ozone was fabricated with multilayer films composed of 30 polyaniline (PANi)/graphene oxide (GO) bilayers using layer-by-layer assembly of positively charged PANi and negatively charged GO. The conversion of GO to the reduced graphene oxide (RGO) in the multilayer film was achieved using hydroiodic acid vapor at $100^{\circ}C$, whereby PANi structure remained nearly unchanged except a little reduction of doping state. Cyclic voltammetry and charge/discharge curves of 30 PANi/RGO bilayers on PET substrate (shorten to PANi-$RGO_{30}$/PET) exhibited an excellent volumetric capacitance, good cycling stability, and rapid charge/discharge rates despite no use of any metal current collectors. The specific capacitance from charge/discharge curve of the PANi-$RGO_{30}$/PET electrode was found to be $529F/cm^3$ at a current density of $3A/cm^3$, which is one of the best values yet achieved among carbon-based materials including conducting polymers. Furthermore, the intrinsic electrical resistance of the PANi-$RGO_{30}$/PET electrodes varied within 20% range during 200 bending cycles at a fixed bend radius of 2.2 mm, indicating the increase in their flexibility by a factor of 225 compared with the ITO/PET electrode.

• Ceramist
• /
• v.22 no.3
• /
• pp.316-327
• /
• 2019

Carbon nitride has drawn broad interdisciplinary attention in diverse fields such as catalyst, energy storage, gas adsorption, biomedical sensing and even imaging. Intensive studies on carbon dioxide (CO₂) capture using carbon nitride materials with various nanostructures have been reported since it is needed to actively remove CO₂ from the atmosphere against climate change. This is mainly due to its tunable structural features, excellent physicochemical properties, and basic surface functionalities based on the presence of a large number of -NH or -NH₂ groups so that the nanostructured carbon nitrides are considered as suitable materials for CO₂ capture for future utilization as well. In this review, we summarize and highlight the recent progress in synthesis strategies of carbon nitride nanomaterials. Their superior CO₂ adsorption capabilities are also discussed with the structural and textural features. An outlook on possible further advances in carbon nitride is also included.

• Journal of Information Display
• /
• v.10 no.3
• /
• pp.117-120
• /
• 2009

A new crystallization method for amorphous silicon, called selective area heating (SAH), was proposed. The purpose of SAH is to improve the reliability of amorphous silicon films with extremely low thermal budgets to the glass substrate. The crystallization time shortened from that of the conventional solid-phase crystallization method. An isolated thin heater for SAH was fabricated on a quartz substrate with a Pt layer. To investigate the crystalline properties, Raman scattering spectra were used. The crystalline transverse optic phonon peak was at about 519 $cm^{-1}$, which shows that the films were crystallized. The effect of the crystallization time on the varying thickness of the $SiO_2$ films was investigated. The crystallization area in the 400nm-thick $SiO_2$ film was larger than those of the $SiO_2$ films with other thicknesses after SAH at 16 W for 2 min. The results show that a $SiO_2$ capping layer acts as storage layer for thermal energy. SAH is thus suggested as a new crystallization method for large-area electronic device applications.

• Food Science and Biotechnology
• /
• v.15 no.6
• /
• pp.871-876
• /
• 2006

Rheological behavior of commercial hot pepper-soybean paste (HPSP) was evaluated in small amplitude oscillatory and steady shear tests. Storage modulus (G'), loss modulus (G"), and complex viscosity (${\eta}^*$) as a function of angular frequency (${\omega}$), and shear stress (${\sigma}$) as a function of shear rate (${\gamma}$) data were obtained for 5 commercial HPSP samples. HPSP samples at $25^{\circ}C$ exhibited a non-Newtonian, shear-thinning flow behavior with high yield stresses and their flow behaviors were described by power law, Casson, and Herschel-Bulkley models. Time-dependent flow properties were also described by the Weltman, Hahn, and Figoni & Shoemaker models. Apparent viscosity over the temperature range of $5-35^{\circ}C$ obeyed the Arrhenius temperature relationship with activation energies (Ea) ranging 18.3-20.1 kJ/mol. Magnitudes of G' and G" increased with an increase in ${\omega}$, while ${\eta}^*$ decreased. G' values were higher than G" over the most of the frequency range (0.63-63 rad/sec), showing that they were frequency dependent. Steady shear viscosity and complex viscosity of the commercial HPSP did not fit the Cox-Merz rule.

• Advances in materials Research
• /
• v.1 no.4
• /
• pp.245-268
• /
• 2012

Results of isothermal torsional oscillation tests are reported on melts of linear low density polyethylene and isotactic polypropylene. Prior to rheological tests, specimens were annealed at various temperatures ranging from $T_a$ = 180 to $310^{\circ}C$ for various amounts of time (from 30 to 120 min). Thermal treatment induced degradation of the melts and caused pronounced decreases in their molecular weights. With reference to the concept of transient networks, constitutive equations are developed for the viscoelastic response of polymer melts. A melt is treated as an equivalent network of strands bridged by junctions (entanglements and physical cross-links). The time-dependent response of the network is modelled as separation of active strands from and merging of dangling strands with temporary nodes. The stress-strain relations involve three adjustable parameters (the instantaneous shear modulus, the average activation energy for detachment of active strands, and the standard deviation of activation energies) that are determined by matching the dependencies of storage and loss moduli on frequency of oscillations. Good agreement is demonstrated between the experimental data and the results of numerical simulation. The study focuses on the effect of molecular weight of polymer melts on the material constants in the constitutive equations.