• Title/Summary/Keyword: energy storage mechanism

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Physicochemical Behaviors of Oxygen and Sulfur in Li Batteries (리튬 전지에서 산소, 황의 물리화학적 거동)

  • Park, Dong-Won;Kim, Jin Won;Kim, Jongwon;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.23 no.3
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    • pp.247-252
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    • 2012
  • Of late, the development of advanced batteries with high power density and capacity has been indispensible for pushing ahead with much wider applications to electric vehicles and smart IT devices. However, a conventional Li-ion battery contains a limited energy density due to various technological challenges such that other types of Li batteries including Li-S and Li-air have been extensively studied due to their interestingly high energy capacities. Sulfur and oxygen, of which both are cathode materials, showing similar physicochemical characteristics have widely been available which may also contribute to the commercialization of these batteries. In this review, we introduce some perspectives in improving these advanced Li batteries through several approaches such as the provision of porous cathode structures, the optimization of cathode-electrolyte interfaces and the modification of Li anodes.

A study on the activation characteristics of multi-phase Zr-based hydrogen storage alloy for Ni-MH rechargeable battery (Ni-MH 2차전지용 다상의 Zr계 수소저장합금 전극의 활성화 특성에 관한 연구)

  • Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.161-171
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    • 1997
  • $AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

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Modeling and Experimental Response Characterization of the Chevron-type Bi-stable Micromachined Actuator (Chevron형 bi-stable MEMS 구동기의 모델링 및 실험적 응답특성 분석)

  • 황일한;심유석;이종현
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.2
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    • pp.203-209
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    • 2004
  • Compliant bi-stable mechanism allows two stable states within its operation range staying at one of the local minimum states of the potential energy. Energy storage characteristics of the bi-stable mechanism offer two distinct and repeatable stable states, which require no power input to maintain it at each stable state. This paper suggests an equivalent model of the chevron-type bi-stable microactuator using the equivalent spring stiffness in the rectilinear and the rotational directions. From this model the range of spring stiffness where the bi-stable mechanism can be operated is analyzed and compared with the results of the FEA (Finite Element Analysis) using ANSYS for the buckling analysis, both of which show a good agreement. Based on the analysis, a newly designed chevron-type bi-stable MEMS actuator using hinges is suggested for the latch-up operation. It is found that the experimental response characteristics of around 36V for the bi-stable actuation for the 60$mu extrm{m}$ stroke correspond very well to the results of the equivalent model analysis after the change in cross-sectional area by the fabrication process is taken into account. Together with the resonance frequency experiment where 1760Hz is measured, it is shown that the chevron-type bi-stable MEMS actuator using hinges is applicable to the optical switch as an actuator.

Enhancing Electrochemical Performance of Co(OH)2 Anode Materials by Introducing Graphene for Next-Generation Li-ion Batteries

  • Kim, Hyunwoo;Kim, Dong In;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.398-406
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    • 2022
  • To satisfy the growing demand for high-performance batteries, diverse novel anode materials with high specific capacities have been developed to replace commercial graphite. Among them, cobalt hydroxides have received considerable attention as promising anode materials for lithium-ion batteries as they exhibit a high reversible capacity owing to the additional reaction of LiOH, followed by conversion reaction. In this study, we introduced graphene in the fabrication of Co(OH)2-based anode materials to further improve electrochemical performance. The resultant Co(OH)2/graphene composite exhibited a larger reversible capacity of ~1090 mAh g-1, compared with ~705 mAh g-1 for bare Co(OH)2. Synchrotron-based analyses were conducted to explore the beneficial effects of graphene on the composite material. The experimental results demonstrate that introducing graphene into Co(OH)2 facilitates both the conversion and reaction of the LiOH phase and provides additional lithium storage sites. In addition to insights into how the electrochemical performance of composite materials can be improved, this study also provides an effective strategy for designing composite materials.

Reliability Evaluation of Accelerated Carbonation Results According to Carbon Dioxide Concentration (이산화탄소 농도에 따른 촉진 탄산화 결과의 신뢰도 평가)

  • Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.04a
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    • pp.166-167
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    • 2022
  • The International Energy Agency(IEA) recommends that intergovernmental agreements reduce CO2 emissions by 2050 to about 50% in 2005 in its report. To realize these demands, it is suggested to actively utilize energy efficiency improvement technology, renewable energy, nuclear power, carbon dioxide capture & storage technology (CCS). In the field of building materials and cement, mineral carbonization technology is widely used. Inorganic by-products applicable to greenhouse gas storage include waste concrete, slag, coal ash, and gypsum. If the Mineral Carbonation Act is used, it is expected that about 12 million tons of greenhouse gases can be immobilized every year. Greenhouse gas immobilization using cement hydrate can be immobilized by injecting carbon dioxide into the hydrated products C-S-H, and Ca(OH)2. In the case of immobilization through concrete carbonization, a carbon dioxide promotion test is used, which is often different from the actual carbon dioxide carbonization reaction. If the external carbon dioxide concentration is abnormally higher than the reality, it is thought that it will be different from the actual reaction. In this study, the carbonation phenomenon according to the concentration and identification of the carbon dioxide reaction mechanism of cement hydrate was to be considered.

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An Energy Efficient Query Processing Mechanism using Cache Filtering in Cluster-based Wireless Sensor Networks (클러스터 기반 WSN에서 캐시 필터링을 이용한 에너지 효율적인 질의처리 기법)

  • Lee, Kwang-Won;Hwang, Yoon-Cheol;Oh, Ryum-Duck
    • Journal of the Korea Society of Computer and Information
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    • v.15 no.8
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    • pp.149-156
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    • 2010
  • As following the development of the USN technology, sensor node used in sensor network has capability of quick data process and storage to support efficient network configuration is enabled. In addition, tree-based structure was transformed to cluster in the construction of sensor network. However, query processing based on existing tree structure could be inefficient under the cluster-based network. In this paper, we suggest energy efficient query processing mechanism using filtering through data attribute classification in cluster-based sensor network. The suggestion mechanism use advantage of cluster-based network so reduce energy of query processing and designed more intelligent query dissemination. And, we prove excellence of energy efficient side with MATLab.

Self Charging Sulfanilic Acid Azocromotrop/Reduced Graphene Oxide Decorated Nickel Oxide/Iron Oxide Solar Supercapacitor for Energy Storage Application

  • Saha, Sanjit;Jana, Milan;Samanta, Pranab;Murmu, Naresh Chandra;Lee, Joong Hee;Kuila, Tapas
    • Composites Research
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    • v.29 no.4
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    • pp.179-185
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    • 2016
  • A self-charging supercapacitor is constructed through simple integration of the energy storage and photo exited materials at the photo electrode. The large band gap of $NiO/Fe_3O_4$ heterostructure generates photo electron at the photo electrode and store the charges through redox mechanism at the counter electrode. Sulfanilic acid azocromotrop/reduced graphene oxide layer at the photo electrode trapped the photo generated hole and store the charge by forming double layer. The solar supercapacitor device is charged within 400 s up to 0.5 V and exhibited a high specific capacitance of ~908 F/g against 1.5 A/g load. The solar illuminated supercapacitor shows a high energy and power density of 33.4 Wh/kg and 385 W/kg along with a very low relaxation time of ~15 ms ensuring the utility of the self charging device in the various field of energy storage and optoelectronic application.

An Proxy Trajectory Based Storage in Sensor Networks (센서네트워크에서의 프록시 트라젝토리 기반 데이터 저장 기법)

  • Lim, Hwa-Jung;Lee, Heon-Guil
    • The KIPS Transactions:PartC
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    • v.15C no.6
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    • pp.513-522
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    • 2008
  • Efficient data dissemination is one of the important subjects for sensor networks. High accessibility of the sensed data can be kept by deploying the data centric storage approach in which data is stored over the nodes in the sensor network itself rather than external storages or systems. The advantage of this approach is its direct accessibility in a real-time without the severe burden on delay and power dissipation on the data path to the external storages or systems. However, if the queries from many users are concentrated to the few nodes with data, then the response time could be increased and it could lead to the reduction of network life time by rapid energy dissipation caused by concentrated network load. In this paper, we propose a adaptive data centric storage scheme based on proxy trajectory (APT) mechanism. We highlight the data centric storage mechanism by taking account of supporting large number of users, and make it feasible to provide high-performance accessibility when a non-uniform traffic pattern is offered. Storing data around the localized users by considering spatial data-access locality, the proxy trajectory of APT provides fast response for the users. The trajectory, furthermore, may help the mobile users to roams freely within the area they dwell.

G-RAID: A Green RAID Mechanism for enhancing Energy-Efficiency in Massive Storage System (G-RAID: 대용량 저장장치에서 에너지 효율향상을 위한 그린 RAID 기법)

  • Kim, Young-Hwan;Suck, Jin-Sun;Park, Chang-Won;Hong, Ji-Man
    • Journal of the Korea Society of Computer and Information
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    • v.16 no.6
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    • pp.21-30
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    • 2011
  • In the global IT market, a lot of issues for responding to various environmental regulations emerged. In case of the data centers, it is consuming huge amounts of energy to maintain. So there have been various technical attempts as Consolidation, Virtualization, Optimization to efficiently manage energy and data storage to fix the problems. In this paper, we propose a new RAID(Redundant Array of Independent Disks) mechanism which is differing the intensity of power consumption and works to provide data protection and disaster recovery(backup, mirroring etc.) to stratify multiple volumes. G-RAID minimize the power consumption and the lower of I/O performance by selecting the volume depending on the frequency of data access while classifying the power consumption between volumes in storage system. Also, it is possible that a filesystem and block map information of G-RAID is processed by basic unit which is group located in a row for the blocks to work efficiently and can minimize the performance degradation of block mapping load by the access frequency in each groups. As a result, we obtained to elevate a little bit of response time caused by block relocation work, but showed the decrease of power consumption by 38%.

DESIGN OF LSDS FOR ISOTOPIC FISSILE ASSAY IN SPENT FUEL

  • Lee, Yongdeok;Park, Chang Je;Kim, Ho-Dong;Song, Kee Chan
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.921-928
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    • 2013
  • A future nuclear energy system is being developed at Korea Atomic Energy Research Institute (KAERI), the system involves a Sodium Fast Reactor (SFR) linked with the pyro-process. The pyro-process produces a source material to fabricate a SFR fuel rod. Therefore, an isotopic fissile content assay is very important for fuel rod safety and SFR economics. A new technology for an analysis of isotopic fissile content has been proposed using a lead slowing down spectrometer (LSDS). The new technology has several features for a fissile analysis from spent fuel: direct isotopic fissile assay, no background interference, and no requirement from burnup history information. Several calculations were done on the designed spectrometer geometry: detection sensitivity, neutron energy spectrum analysis, neutron fission characteristics, self shielding analysis, and neutron production mechanism. The spectrum was well organized even at low neutron energy and the threshold fission chamber was a proper choice to get prompt fast fission neutrons. The characteristic fission signature was obtained in slowing down neutron energy from each fissile isotope. Another application of LSDS is for an optimum design of the spent fuel storage, maximization of the burnup credit and provision of the burnup code correction factor. Additionally, an isotopic fissile content assay will contribute to an increase in transparency and credibility for the utilization of spent fuel nuclear material, as internationally demanded.