• 한국식품영양과학회지
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• 제14권1호
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• pp.88-94
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• 1985

Food irradiation is increasingly recognized as the sole viable alternative to traditional method of food preservation in terms of reducing the overall quantity of spoiled food, reducing energy used in food storage, and reducing reliance on chemicals known to be hazardous but currently required for disinfestation. Irradiation with ionizing radiation can be applied in the fields of sprout inhibition, disinfestation of insects, sterilization, delay of ripening, and improvement of organoleptic properties in food. In order to back up the commercialization of food irradiation in Korea, this review not only dealt with the international background for food irradiation and wholesomeness of irradiated food, but also evaluated economic feasibility of irradiated food, irradiation facilities, and domestic status of food irradiation studies.

• 반도체디스플레이기술학회지
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• 제13권3호
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• pp.13-19
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• 2014

Phosphoric acid was used as etching agent instead of conventional peroxide - based chemicals for forming pattern of ultra definition display. Etchant was synthesized by mixing etching agent, oxidation agent, buffer solution, and additive into solvent, deionized water. Thicknesses of copper, main metal of ultra definition display, for etching, were 10,000 and $30,000{{\AA}}$. Etch stop of good low skew for proper pattern formation has been occurred at the content ratio of phosphoric acid 60 - 64%, nitric acid 4 - 5%, additive(potassium acetate) 1 - 3%. Buffer solution(acetic acid) decreased the metal contact angle $63.07^{\circ}$ to $42.49^{\circ}$ for benefiting pattern formation. Content variations on four components (phosphoric acid, nitric acid, acetic acid, potassium acetic acid) of the etchant with storage time were within 3 wt% after 24 hrs of etching work.

• 한국식품과학회지
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• 제16권1호
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• pp.71-77
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• 1984

염장(鹽藏)미역의 품질을 chlorophyll a의 함량음 지표로하여 검토하기 위하여, 생미역을 25초간 blanching 하고, 2분간 원심탈수한 후 식염을 첨가, 48시간 방치하고, 다시 원심탈수한 다음 8%의 식염을 뿌리고 polyethylene film으로 밀봉하여 정온저장하였을 때의 결과를 요약하면 다음과 같다. $70{\sim}100^{\circ}C$의 온도 범위에서 chlorophyll a 잔존량이 가장 많은 blanching온도는 $85^{\circ}C$였다. Blanching온도의 변화에 따른 총유기산(總有機酸) 및 총휘발산(總揮發酸)의 함량차이는 그리 크지 않았다. Blanching 후에 색소안정용액에 20분간 침지(浸漬)하는 것보다는 색소안정제용액중에서 blanching하는 것이 색소안정효과가 컸다. $1%{\;}Ca(CH_3CO_2)_2,{\;}1%Ca(OH)_2,{\;}1%MgCO_3,{\;}0.5%Ca(CH_3CO_2)_2+0.5%MgCO_2$ 갈대잿물 중에서 $0.5%Ca(CH_3CO_2)_2+0.5%MgCO_3$액과 갈대잿물이 색소안정 효과가 컸다. 그러나 대조구에 비교하여 큰 효과는 없다. 48시간 동안의 가염탈수과정에서 chlorophyll a 잔존량이 가장 많았던 염첨가량은 중량비로 30%일 때였다. 총유기산(總有機酸) 및 총휘발산(總揮發酸)의 양은 염첨가량(鹽添加量)과는 무관하였다. $40^{\circ}C$에 저장한 염장(鹽藏)미역은 77일후에도 색택, 풍미, 조직에 별다른 변화가 없었다. 그러나 저장온도가 높을수록 변화가 심하였다. 정온저장한 염장(鹽藏)미역의 chlorophyll a의 파괴는 일차반응으로 해석되었고, 10, 20, 30, $40^{\circ}C$에서의 반응(反應)속도상수는 각각 0.1289, 0.1028, 0.0770, 0.0550이었다. $Q_{10}$은 1.33, 활성화 energy는 5.01Kcal/g mole이었다.

• 접착 및 계면
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• 제15권3호
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• pp.100-108
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• 2014

본 연구에서는 비스페놀 A 에폭시 수지/경화제(YD-128/DDM) 조성물의 비율을 조절하여 $170^{\circ}C$의 경화온도에서 접착성능 최적화 조성비를 얻기 위한 실험을 진행하였다. DSC, TGA, DMA, TMA 열분석 장비를 사용하여 YD-128/DDM 혼합물의 당량비 변화가 경화물의 열적 특성에 미치는 영향에 대하여 조사하였으며, 조성물의 경화시간은 YD-128/DDM (1 : 1.1) 조성물을 동적 DSC를 이용하여 측정된 시간당 누적 발열량을 총 발열량으로 나누어 계산한 전환율을 토대로 결정하였다. TGA를 이용한 분해 활성화 에너지 분석에서는 경화물의 DDM 당량비가 증가할수록 열안정성과 열분해 활성화 에너지가 높게 나타났고, DMA와 TMA를 이용한 경화물의 열적 특성 조사 결과에서는 당량비 1 : 1에서 다른 당량비 조건에 비해 우수한 탄성률 및 열팽창성이 관찰되었다. 또한 각기 다른 당량비의 조성물을 $170^{\circ}C$에서 경화하여 중첩 전단 강도를 측정하였다.

• Korean Chemical Engineering Research
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• 제48권2호
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• pp.129-139
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• 2010

석탄으로부터 수소, 일산화탄소 등의 가스 연료를 생산하기 위하여 개발된 석탄 가스화 공정은 이산화탄소 저장, 환경 유해 물질 저감 등의 우수성으로 인하여 최근 세계 각국에서 앞다투어 개발에 나서고 있다. $75{\mu}m$ 이하의 미분탄을 이용하는 분류층 가스화 공정은 용량의 대형화가 쉽고, 에너지 전환 효율이 우수하여 석탄가스화복합발전(IGCC) 등에 널리 이용되고 있다. 특히 석탄슬러리를 원료로 사용하는 습식 분류층 가스화 공정은 기술적으로 성숙되어 가장 많이 보급되고 있다. 본 논문에서는 습식 분류층 가스화 공정을 이루는 석탄전처리, 버너, 가스화기, 슬래그용융, 가스화 운전 특성과 설계 및 해석을 위한 수치모사 등의 요소기술 개발 현황을 고찰하였다. 습식 석탄가스화는 IGCC 플랜트에서 뿐만 아니라 합성석유, SNG, 화학원료 제조용으로 활용될 수 있으며 융합 공정, 연료 다변화 등에 대응하기 위하여 요소기술별 추가적인 기술개발이 이루어져야 할 것으로 판단된다.

• 한국전기전자재료학회논문지
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• 제24권5호
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• pp.404-409
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• 2011

An amorphous $Ge_2Sb_2Te_5$ thin film is one of the most commonly used materials for phase-change data storage. In this study, $Au_x(Ge_2Sb_2Te_5)_{1-x}$ thin film amorphous-to-crystalline phase-change rate were evaluated in using 658 nm laser beam. The focused laser beam with a diameter <10 ${\mu}m$ was illuminated in the power (P) and pulse duration (t) ranges of 1-17 mW and 10-460 ns, respectively, with subsequent detection of the responsive signals reflected from the film surface. We also evaluated the material characteristics, such as optical absorption and energy gap, crystalline phases, and sheet resistance of as-deposited and annealed films. The result of experiments showed that the thermal stability of the $Ge_2Sb_2Te_5$ film is largely improved by adding Au.

• Journal of Electrochemical Science and Technology
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• 제13권1호
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• pp.148-158
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• 2022

The electrochemical CO₂ reduction (ECR) to produce value-added fuels and chemicals using clean energy sources (like solar and wind) is a promising technology to neutralize the carbon cycle and reproduce the fuels. Presently, the ECR has been the most attractive route to produce carbon-building blocks that have growing global production and high market demand. The electrochemical CO₂ reduction could be extensively implemented if it produces valuable products at those costs which are financially competitive with the present market prices. Herein, the electrochemical conversion of CO₂ obtained from flue gases of a power plant to produce diesel and formic acid using a consistent techno-economic approach is presented. The first scenario analyzed the production of diesel fuel which was formed through Fischer-Tropsch processing of CO (obtained through electroreduction of CO₂) and hydrogen, while in the second scenario, direct electrochemical CO₂ reduction to formic acid was considered. As per the base case assumptions extracted from the previous outstanding research studies, both processes weren't competitive with the existing fuel prices, indicating that high electrochemical (EC) cell capital cost was the main limiting component. The diesel fuel production was predicted as the best route for the cost-effective production of fuels under conceivable optimistic case assumptions, and the formic acid was found to be costly in terms of stored energy contents and has a facile production mechanism at those costs which are financially competitive with its bulk market price. In both processes, the liquid product cost was greatly affected by the parameters affecting the EC cell capital expenses, such as cost concerning the electrode area, faradaic efficiency, and current density.

• 분석과학
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• 제22권4호
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• pp.285-292
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• 2009

장기 저장된 탄약은 화공품의 노화에 따른 절심현상(연소 중단)으로 인해 불발 등의 악작용이 발생하게 된다. 탄약에 주로 사용되는 화공품은 초기 에너지를 부여하는 뇌관 화약과 뇌관 화약의 에너지를 받아 지연제를 점화시켜주는 점화제, 일정 시간 동안 연소를 지연시켜주는 지연제 등을 사용한다. 이러한 형태의 탄약에는 뇌관화약, 점화제, 지연제의 순으로 충전되는데 충전된 순서대로 에너지가 전달되어 기능을 발휘하게 된다. 탄약의 절심 현상은 점화제의 연소중단, 점화제로부터 지연제로의 불충분한 에너지 전달, 지연제의 연소 중단 등에 의해 발생하는데, 이러한 현상이 나타나는 요인으로는 각 구성 성분의 낮은 순도,부적절한 혼합비, 입자성 성분의 입자 크기 및 분포, 바인더의 종류, 각 구성 성분의 혼합방법, 장기저장시 흡입된 수분에 의한 구성성분의 가수분해 및 고온에 의한 구성 성분의 화학적 변화 등이 의심된다. 본 연구의 목적은 Zr-Ni계 지연관 결합체를 장기 보관했을 때 점화제 및 지연제에서 나타나는 연소중단현상의 원인을 규명하는 것이다. 이를 위해 본 연구에서는 현장에서 일어나는 절심현상과 일치하는 시험법을 개발하였고, 장-흐름 분획법(field-flow fractionation, FFF)을 이용하여 입자성 성분의 입자 크기와 분포를 조사하였으며, 장기보관에 의한 점화제와 지연제의 화학적인 변화 메커니즘을 조사하기 위하여 열분석(differential scanning calorimetry) 및 XRD, XPS (X-ray diffractometry, X-ray photoelectron Spectroscopy)분석을 수행하였다. XPS 와 XRD data 에 의하면, 점화제의 경우 산소의 1s 결합에너지 위치에서 M-O,M-OH 피크들이 관찰되었다. 이는 산화에 의한 새로운 생성물이 생성되었음을 의미한다. 즉 점화제의 산화에 의해 방출 열량이 감소하여 절심(연소 중단) 현상이 야기된다는 사실을 확인할 수 있었다.

• Asia pacific journal of information systems
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• 제20권3호
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• pp.191-204
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• 2010

Recently, the CO2 emission and energy consumption have become critical global issues to decide the future of nations. Especially, the spread of IT products and the increased use of internet and web applications result in the energy consumption and CO2 emission of IT industry though information technologies drive global economic growth. EU, the United States, Japan and other developed countries are using IT related environmental regulations such as WEEE(Waste Electrical and Electronic Equipment), RoHS(Restriction of the use of Certain Hazardous Substance), REACH(Registration, Evaluation, Authorization and Restriction of CHemicals) and EuP(Energy using Product), and have established systematic green business/IT strategies to enhance the competitiveness of IT industry. For example, the Japan government proposed the "Green IT initiative" for being compatible with economic growth and environmental protection. Not only energy saving technologies but energy saving systems have been developed for accomplishing sustainable development. Korea's CO2 emission and energy consumption continuously have grown at comparatively high rates. They are related to its industrial structure depending on high energy-consuming industries such as iron and steel Industry, automotive industry, shipbuilding industry, semiconductor industry, and so on. In particular, export proportion of IT manufacturing is quite high in Korea. For example, the global market share of the semiconductor such as DRAM was about 80% in 2008. Accordingly, Korea needs to establish a systematic strategy to respond to the global environmental regulations and to maintain competitiveness in the IT industry. However, green competitiveness of Korea ranked 11th among 15 major countries and R&D budget for green technology is not large enough to develop energy-saving technologies for infrastructure and value chain of low-carbon society though that grows at high rates. Moreover, there are no concrete action plans in Korea. This research aims to deduce the priorities of the Korean green business/IT strategies to use multi attribute weighted average method. We selected a panel of 19 experts who work at the green business related firms such as HP, IBM, Fujitsu and so on, and selected six assessment indices such as the urgency of the technology development, the technology gap between Korea and the developed countries, the effect of import substitution, the spillover effect of technology, the market growth, and the export potential of the package or stand-alone products by existing literature review. We submitted questionnaires at approximately weekly intervals to them for priorities of the green business/IT strategies. The strategies broadly classify as follows. The first strategy which consists of the green business/IT policy and standardization, process and performance management and IT industry and legislative alignment relates to government's role in the green economy. The second strategy relates to IT to support environment sustainability such as the travel and ways of working management, printer output and recycling, intelligent building, printer rationalization and collaboration and connectivity. The last strategy relates to green IT systems, services and usage such as the data center consolidation and energy management, hardware recycle decommission, server and storage virtualization, device power management, and service supplier management. All the questionnaires were assessed via a five-point Likert scale ranging from "very little" to "very large." Our findings show that the IT to support environment sustainability is prior to the other strategies. In detail, the green business /IT policy and standardization is the most important in the government's role. The strategies of intelligent building and the travel and ways of working management are prior to the others for supporting environment sustainability. Finally, the strategies for the data center consolidation and energy management and server and storage virtualization have the huge influence for green IT systems, services and usage This research results the following implications. The amount of energy consumption and CO2 emissions of IT equipment including electrical business equipment will need to be clearly indicated in order to manage the effect of green business/IT strategy. And it is necessary to develop tools that measure the performance of green business/IT by each step. Additionally, intelligent building could grow up in energy-saving, growth of low carbon and related industries together. It is necessary to expand the affect of virtualization though adjusting and controlling the relationship between the management teams.

• 분석과학
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• 제28권5호
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• pp.341-346
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• 2015

In order to understand the counter anionic effects in a non-aqueous vanadium redox flow battery (VRFB), we synthesized four types of electrolyte salts (1-ethyltriethamine tertafluoroborate, [E-TEDA]⁺[BF₄]⁻, 1-ethyltriethamine hexafluorophosphate, [E-TEDA]⁺[PF₆]⁻, 1-butyltriethylamine tertafluoroborate, [B-TEDA]⁺[BF₄]⁻, and 1-buthyltriethamine hexafluorophosphate [B-TEDA]⁺[PF₆]⁻) by counter anion exchange reaction after the SN₂ reaction. We confirmed the successful synthesis of the electrolyte salts [E-TEDA]⁺[Br]⁻ and [B-TEDA]⁺[Br]⁻ via ¹H-NMR spectroscopy and GC-mass analysis before the counter anion exchange reaction. The electric potential of the vanadium acetylacetonate, V(acac)₃, as an energy storage chemical was shown to be 2.2 V in the acetonitrile solvent with each of the [E-TEDA]⁺[BF₄]⁻, [E-TEDA]⁺[PF₆]⁻, [B-TEDA]⁺[BF₄]⁻, and [B-TEDA]⁺[PF₆]⁻ electrolyte salts. In a non-aqueous VRFB with a commercial Neosepta AFN membrane, the maximum voltages reached 1.0 V and 1.5 V under a fixed current value of 0.1 mA in acetonitrile with the [E-TEDA]⁺[BF₄]⁻ and [E-TEDA]⁺[PF₆]⁻ electrolyte salts, respectively. The maximum voltage was 0.8 V and 1.1 V under a fixed current value of 0.1 mA in acetonitrile with the [B-TEDA]⁺[BF₄]⁻ and [B-TEDA]⁺[PF₆]⁻ electrolyte salts, respectively. From these results, we concluded that in the non-aqueous VRFB more of the [PF₆]⁻ counter anion than the [BF₄]⁻ counter anion was transported onto the commercial Neosepta AFN anion exchange membrane.