• 제목/요약/키워드: energy partition

검색결과 122건 처리시간 0.023초

Mechanisms of Cu(II) Sorption at Several Mineral/Water Interfaces: An EPR Study

  • Cho, Young-Hwan;Hyun, Sung-Pil;Pilsoo Hahn
    • 한국자기공명학회:학술대회논문집
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    • 한국자기공명학회 2002년도 International Symposium on Magnetic Resonance
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    • pp.72-72
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    • 2002
  • In most traditional sorption study in environmental conditions, experimental sorption data have been measured and interpreted by empirical ways such as partition coefficient and sorption isotherms. A mechanistic understanding of heavy metal interactions with various minerals (metal oxides, clay minerals) in aqueous medium is required to describe the behavior of radioactive metal ions in the environment. Various spectroscopic methods provide direct or indirect information on sorption mechanisms involved. We applied EPR (Electron Paramagnetic Resonance) spectroscopy to investigate the nature of metal ion sorption at water/mineral interfaces using Cu(II) as a spin probe. The major sorbed species and their motional state was identified by their EPR spectra. They showed distinct signals due to their strength of binding, local structure and motional state. The EPR results together with macroscopic sorption data show that sorption involved at least three different mechanisms depending on chemical environments (1).

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A split kinetic energy solution scheme applied to various delta potentials in quantum mechanical systems

  • Chen, Yu-Hsin;Chao, Sheng D.
    • Coupled systems mechanics
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    • 제6권1호
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    • pp.17-28
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    • 2017
  • In this work, we extend the previously developed split kinetic energy (dubbed KEP) method by Mineo and Chao (2012) by modifying the mass parameter to include the negative mass. We first show how to separate the total system into the subsystems with 3 attractive delta potentials by using the KEP method. For repulsive delta potentials, we introduce "negative" mass terms. Two cases are demonstrated using the "negative" mass terms for repulsive delta potential problems in quantum mechanics. Our work shows that the KEP solution scheme can be used to obtain not only the exact energies but also the exact wavefunctions very precisely.

유니트 캐빈 목업(mock-up)의 차음성능평가 (Evaluation of Sound Insulation Performance of a Unit Cabin Mock-up)

  • 김현실;김상렬;김봉기;김재승;이성현
    • 대한조선학회논문집
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    • 제48권1호
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    • pp.49-55
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    • 2011
  • Sound insulation performance of a unit cabin mock-up is studied, where two identical rooms simulating cruise ship cabin are installed. STL (Sound Transmission Loss) measurement in the mock-up shows that STL of the partition between rooms is degraded by imperfect door ceiling and gap between wall and floor. It is also observed that gap around lighting and electrical outlet slightly affect the STL in high frequency ranges, since lighting and electrical outlet are supported by mineral wool in the back side due to fire-resistance requirement. Even after all possible gaps are sealed, STL of the partition is found to be lower than that measured in the laboratory by 9 dB. Measurement of SBN (Structure-Borne Noise) reveals that flanking transmission of SBN along the steel deck floor can severely deteriorate STL of the partition. Statistical energy analysis (SEA) of the mock-up confirms importance of the floor SBN control, in which increasing damping is essential to ensure high STL.

이산 Wavelet 변환을 이용한 3차원 등방성 난류속도장의응집구조 추출 (Coherent Structure Extraction from 3-Dimensional Isotropic Turbulence Velocity Field Using Discrete Wavelet Transform)

  • 이상환;정재윤
    • 대한기계학회논문집B
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    • 제28권9호
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    • pp.1032-1041
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    • 2004
  • In this study we decompose the 3-dimensional velocity field of isotropic turbulent flow into the coherent and the incoherent structure using the discrete wavelet. It is shown that the coherent structure, 3% wavelet modes, has 98% energy and 88% enstrophy and its statistical characteristics are almost same as the original turbulence structure. And it is confirmed that the role of the coherent structure is that it produces the turbulent kinetic energy at the inertia range then transfers energy to the dissipation range. The incoherent structure, with residual wavelet modes, is uncorrelated and has the Gaussian probability density function but it dissipates the kinetic energy in dissipation range. On the procedure, we propose a new but easy way to get the threshold by applying the energy partition percentage concept about coherent structure. The vorticity field extracted from the wavelet-decomposed velocity field has the same structure as the result of the precedent studies which decomposed vorticity field directly using wavelet. Therefore it has been shown that velocity and vorticity field are on the interactive condition.

고체 표면 위의 기체 흡착에 관한 이론적 연구 (Theoretical Approach to Physical Adsorption of Gases on Solid Surfaces)

  • 장세현;박형석
    • 대한화학회지
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    • 제14권1호
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    • pp.97-107
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    • 1970
  • 액체 구조의 천이상태 이론을 써서 고체 표면에 기체가 흡착된 계에 대한 상태합을 유도하였다. 이 상태합을 써서 아르곤, 질소, 벤젠 등이 여러 가지 흡착제에 흡착되었을 때의 흡착등온 곡선을 계산하였으며, 이 계산 값들은 측정치와의 좋은 일치를 보여 준다. 그리고 벤젠이 흑연 표면에 흡착되었을 때의 표면압, 물엔트로피, 물에너지, 몰흡착열 들을 계산하였다. 몰엔트로피는 표면이 단분자층으로 완전히 덮였을 때 최소값을 갖는다. 아울러 흡착에 관여된 여러 가지 물리적인 성질들의 계산 방법을 설명하였다.

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Solvent Effect on $Rb^+$ to $K^+$ Iron Mutation: Monte Carlo Simulation Study

  • 김학성
    • Bulletin of the Korean Chemical Society
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    • 제21권5호
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    • pp.503-509
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    • 2000
  • The solvent effects on the relative free energies of solvation and the difference in partition coefficients (log P) for $Rb^+$ to $K^+$ mutation in several solvents have been investigated using Monte Carlo simulation (MCS) of statistical perturbation theory(SPT). In comparing the relative free energies for interconversion of one ion pair, $Rb^+$ to $K^+$, in $H_2O$(TIP4P) in this study with the relative free energies of the computer simulations and the experimental, we found that the figure in this study with the relative free energies of the computert simulations and the experimental, we found that the figure in this study is $-5.00\pm0.11$ kcal/mol and those of the computer simulations are $-5.40\pm1.9$, -5.5, and -5.4 kcal/mol. The experimental is -5.1 kcal/mol. There is good agreement among various studies, taking into account both methods used to obtain the hydration free energies and standard deviations. There is also good agreement between the calculated structural properties of this study and the simulations, ab initio and the experimental results. We have explained the deviation of the relationship between the free energy difference and the Onsager dielectric function of solvents by the electron pair donor properties of the solvents. For the $Rb^+$ and $K^+$ ion pair, the Onsager dielectric function of solvents (or solvent permittivity), donor number of solvent and the differences in solvation dominate the differences in the relative free energies of solvation and partition coefficients.

Multi-Objective Pareto Optimization of Parallel Synthesis of Embedded Computer Systems

  • Drabowski, Mieczyslaw
    • International Journal of Computer Science & Network Security
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    • 제21권3호
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    • pp.304-310
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    • 2021
  • The paper presents problems of optimization of the synthesis of embedded systems, in particular Pareto optimization. The model of such a system for its design for high-level of abstract is based on the classic approach known from the theory of task scheduling, but it is significantly extended, among others, by the characteristics of tasks and resources as well as additional criteria of optimal system in scope structure and operation. The metaheuristic algorithm operating according to this model introduces a new approach to system synthesis, in which parallelism of task scheduling and resources partition is applied. An algorithm based on a genetic approach with simulated annealing and Boltzmann tournaments, avoids local minima and generates optimized solutions. Such a synthesis is based on the implementation of task scheduling, resources identification and partition, allocation of tasks and resources and ultimately on the optimization of the designed system in accordance with the optimization criteria regarding cost of implementation, execution speed of processes and energy consumption by the system during operation. This paper presents examples and results for multi-criteria optimization, based on calculations for specifying non-dominated solutions and indicating a subset of Pareto solutions in the space of all solutions.

크리프-피로상호작용하의 파단수명에 관한 연구 (Study on Fracture Life Under Mutual Interaction of Creep and Fatigue)

  • 조용이;김희송
    • 한국정밀공학회지
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    • 제10권3호
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    • pp.97-106
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    • 1993
  • This is the study on fracture life under the interaction of creep and fatigue. It is difficult to explain the interaction of the creep and fatigue with indication of frequency but the dependency of the time should be considered. The formulation of material varieties causing by interaction of creep and fatigue is required in the accumulative damage method. The strain range partition method requires some of modification corresponding to the changes in temperature and load. All of other method also comprehended with above mentioned problems. Generally, in this field, the variety of stress-strain and suitable parameter is required and connective study between the macro and micro results seems to be insufficient. The linear damage rule is acquiring the support generally but it requires modification in the hgigh temperature instruments. The variety of stress effecting on crack and variety of stress on the metallurgical side are considered to be problems in the future days.

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Prolong life-span of WSN using clustering method via swarm intelligence and dynamical threshold control scheme

  • Bao, Kaiyang;Ma, Xiaoyuan;Wei, Jianming
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제10권6호
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    • pp.2504-2526
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    • 2016
  • Wireless sensors are always deployed in brutal environments, but as we know, the nodes are powered only by non-replaceable batteries with limited energy. Sending, receiving and transporting information require the supply of energy. The essential problem of wireless sensor network (WSN) is to save energy consumption and prolong network lifetime. This paper presents a new communication protocol for WSN called Dynamical Threshold Control Algorithm with three-parameter Particle Swarm Optimization and Ant Colony Optimization based on residual energy (DPA). We first use the state of WSN to partition the region adaptively. Moreover, a three-parameter of particle swarm optimization (PSO) algorithm is proposed and a new fitness function is obtained. The optimal path among the CHs and Base Station (BS) is obtained by the ant colony optimization (ACO) algorithm based on residual energy. Dynamical threshold control algorithm (DTCA) is introduced when we re-select the CHs. Compared to the results obtained by using APSO, ANT and I-LEACH protocols, our DPA protocol tremendously prolongs the lifecycle of network. We observe 48.3%, 43.0%, and 24.9% more percentages of rounds respectively performed by DPA over APSO, ANT and I-LEACH.

콘택트렌즈용 하이드로젤 계면에너지에 따른 단백질 흡착현상의 이해 (Understanding of Protein Adsorption to Contact Lens Hydrogels with Varying Surface Energy)

  • 전소하;노혜란
    • 폴리머
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    • 제36권3호
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    • pp.338-343
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    • 2012
  • 콘텍트렌즈용 하이드로젤의 계면 특성의 이해를 위해 단백질 흡착 현상을 열역학을 바탕으로 연구하였다. 다른 습윤성을 갖는 $1{\times}1mm^2$ 크기의 하이드로젤을 알부민(bovine serum albumin, BSA)용액에 1시간 동안 침지시킨 후 남아있는 BSA 용액의 농도를 Bradford assay로 정량하였다. 모든 하이드로젤로의 단백질 흡착량은 단백질 농도가 증가함에 따라 계면 흡착량이 증가하며 Langmuir 곡선의 형태를 보였다. 또한 계면과 용액내의 단백질 농도비($P$), 계산된 흡착 Gibbs free energy는 하이드로젤 재료의 친수성도가 증가함에 따라 증가하였다. 표면에너지와 단백질 흡착량 상관관계를 이해하여 콘택트렌즈 재질로의 단백질 흡착현상의 물리화학적 해석이 가능함을 알 수 있었다.