• Title/Summary/Keyword: energy matrix

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DGEBA-MDA-SN-Hydroxyl Group System and Composites : 2. Fracture Energy of Fiber Reinforced Composites (DGEBA-MDA-SN-Hydroxyl Group System의 합성 및 복합재료 제조 : 2. 섬유강화 복합재료의 파괴에너지)

  • Lee, Jae-Young;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.737-742
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    • 1994
  • The fracture energy of glass fiber/carbon fiber/epoxy resin hybrid composite system was investigated in the aspect of fracture mechanism. Epoxy resin matrix was DGEBA-MDA-SN-HQ system. On the interface of glass fiber and matrix, post debone friction energy provided a major contribution to the fracture energy, and debonding energy and pull-out energy were of the similar value. In the case of fracture on the interface of carbon fiber and matrix, pull-out energy was the major contributor.

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Effects of Electrode and Matrix in the PAFC Performance (전극 및 메트릭스가 인산형 연료전지의 성능에 미치는 영향)

  • Kim, Dong-Jin;Song, Rak-Hyun;Lee, Byung-Rok;Kim, Chang-Soo;Shin, Dong-Ryul
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1873-1875
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    • 1999
  • The effects of electrode and matrix in the PAFC were investigated using AC-impedance spectroscopy. The performance of PAFC was determined by changing external electronic load. AC impedance measurement was carried out as functions of phosphoric acid impregnation temperature. operating temperature and matrix coating method using various cathodes ; 20%Pt/C, 20%Pt-Ni/C, 20%Pt-Co-Ni/C, 10%Pt-Fe-Co/C, and 20%Pt-Fe-Co/C From the analysis of measured impedance data, the interfacial resistance decreased with increasing operating temperature. and with decreasing impregnation temperature. As compared with the alloy catalysts, Pt catalyst showed a lower interfacial resistance. This consist with the cell performance.

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Effect of Fe Magnetic Nanoparticles in Rubber Matrix

  • Uhm, Young-Rang;Kim, Jae-Woo;Jun, Ji-Heon;Lee, Sol;Rhee, Chang-Kyu;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.173-178
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    • 2010
  • A new kind of magnetic rubber, Fe dispersed ethylene propylene monomer (EPM), was prepared by a conventional technique using a two roll mill. The magnetic fillers of Fe-nanoparicles were coated by low density polyethylene (LDPE). The purpose of surface treatment of nanoparticles by LDPE is to enhance wettability and lubricancy of the fillers in a polymer matrix. The mechanical strength and microstructure of the magnetic rubber were characterized by tensile strength test and scanning electron microscopy (SEM). Results revealed that the Fe nanoparticles were relatively well dispersed in an EPM matrix. It was found that the nano- Fe dispersed magnetic rubber showed higher coercivity and tensile strength than those of micron- Fe dispersed one.

Ni added Si-Al Alloys with Enhanced Li+ Storage Performance for Lithium-Ion Batteries

  • Umirov, Nurzhan;Seo, Deok-Ho;Jung, Kyu-Nam;Kim, Hyang-Yeon;Kim, Sung-Soo
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.82-88
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    • 2019
  • Here, we report on nanocrystalline Si-Al-M (M = Fe, Cu, Ni, Zr) alloys for use as an anode for lithium-ion batteries, which were fabricated via a melt-spinning method. Based on the XRD and TEM analyses, it was found that the Si-Al-M alloys consist of nanocrystalline Si grains surrounded by an amorphous matrix phase. Among the Si-Al-M alloys with different metal composition, Ni-incorporated Si-Al-M alloy electrode retained the high discharge capacity of 2492 mAh/g and exhibited improved cyclability. The superior $Li^+$ storage performance of Si-Al-M alloy with Ni component is mainly responsible for the incorporated Ni, which induces the formation of ductile and conductive inactive matrix with crystalline Al phase, in addition to the grain size reduction of active Si phase.

A Study on a Load Flow calculation for Preserved Jacobian Matrix's elements except diagonal terms (Jacobian 행렬의 비 대각 요소를 보존시킬 수 있는 조류계산에 관한 연구)

  • Moon, Yong-Hyun;Lee, Jong-Gi;Choi, Byoung-Kon;Park, Jeong-Do;Ryu, Hun-Su
    • Proceedings of the KIEE Conference
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    • 1998.11a
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    • pp.311-315
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    • 1998
  • Load Flow calculation methods can usually be divided into Gauss-Seidel method, Newton-Raphson method and decoupled method. Load flow calculation is a basic on-line or off-line process for power system planning, operation, control and state analysis. These days Newton-Raphson method is mainly used since it shows remarkable convergence characteristics. It, however, needs considerable calculation time in construction and calculation of inverse Jacobian matrix. In addition to that, Newton-Raphson method tends to fail to converge when system loading is heavy and system has a large R/X ratio. In this paper, matrix equation is used to make algebraic expression and then to solve load flow equation and to modify above defects. And it preserve certain part of Jacobian matrix to shorten the time of calculation. Application of mentioned algorithm to 14 bus, 39 bus, 118 bus systems led to identical result and the number of iteration got by Newton-Raphson method. The effect of time reduction showed about 28%, 30%, at each case of 39 bus, 118 bus system.

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Polysulfone/nanocomposites mixed matrix ultrafiltration membrane for the recovery of Maillard reaction products

  • Basu, Subhankar;Mukherjee, Sanghamitra;Balakrishnan, Malini;Deepthi, M.V.;Sailaja, R.R.N.
    • Membrane and Water Treatment
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    • v.9 no.2
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    • pp.105-113
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    • 2018
  • Maillard reaction products like melanoidins present in industrial fermentation wastewaters are complex compounds with various functional properties. In this work, novel ultrafiltration (UF) mixed matrix membrane (MMM) composed of polysulfone (PSF) and nanocomposites was prepared through a phase inversion process for the recovery of melanoidins. Nanocomposites were prepared with acid functionalized multiwalled carbon nanotubes (MWCNTs) as the reinforcing filler for chitosan-thermoplastic starch blend. Higher nanocomposites content in the PSF matrix reduced the membrane permeability and melanoidins retention indicating tighter membrane with surface defects. The membrane surface defects could be sealed with dilute polyvinyl alcohol (PVA) solution. The best performing membrane (1% nanocomposites in 18% PSF membrane sealed with 0.25% PVA coating) resulted in uniform melanoidins retention of 98% and permeability of 3.6 L/m2 h bar over a period of 8h. This demonstrates a low fouling PSF membrane for high melanoidins recovery.

A Theoretical Model for Predicting Matrix Crack Density Growth (기지균열의 밀도증가를 예측하기 위한 이론적 모형)

  • 이종원;김진원;김응태;안석민
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.05a
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    • pp.203-206
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    • 2002
  • The present study proposes a theoretical model for predicting the matrix crack density growth of each layer in composite laminates subjected to thermo-mechanical loads. Each layer with matrix cracks is treated as an equivalent continuum of degraded elastic stiffnesses which are functions of the matrix crack density in each slyer. The energy release rate as a function of the degraded elastic stiffnesses is then calculated for each layer as functions of thermo-mechanical loads externally applied to the laminate. The matrix crack densities of each layer in general laminates are predicted as functions of the thermo-mechanical loads applied to a number of laminates. Comparisons of the present study with experimental data in the open literatures are also provided.

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Manufacture of SiC matrix for PAFC (인산형 연료전지용 SiC MATRIX 제조)

  • 김영우;이주성
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.187-193
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    • 1993
  • Porous matrices to contain and support phosphoric acid were prepared with PTFE as binder and SiC whisker or SiC powders of various particle size for phosphoric acid fuel cell(PAFC). Among the matrix characteristics the most important factors in stack performances were thought to be the bubble pressure and electrolyte wettability And then matrix was constructed to have pore size smaller than that of electrode. The bubble pressures and wettabilities of matrices manufactured with various size of SiC and different PTFE contents were investigated and related with the porosities measured by porosimeter, and then the optimum manufacturing condition of matrix for PAFC was determined.

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Boundary element analysis of singular thermal stresses in a unidirectional laminate

  • Lee, Sang Soon;Kim, Beom Shig
    • Structural Engineering and Mechanics
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    • v.5 no.6
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    • pp.705-713
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    • 1997
  • The residual thermal stresses at the interface corner between the elastic fiber and the viscoelastic matrix of a two-dimensional unidirectional laminate due to cooling from cure temperature down to room temperature were studied. The matrix material was assumed to be thermorheologically simple. The time-domain boundary element method was employed to investigate the nature of stresses on the interface. Numerical results show that very large stress gradients are present at the interface corner and this stress singularity might lead to local yielding or fiber-matrix debonding.

Mixed mode I/II fracture criterion to anticipate behavior of the orthotropic materials

  • Farid, Hannaneh Manafi;Fakoor, Mahdi
    • Steel and Composite Structures
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    • v.34 no.5
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    • pp.671-679
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    • 2020
  • The new energy-based criterion, named Reinforcement Strain Energy Density (ReiSED), is proposed to investigate the fracture behavior of the cracked orthotropic materials in which the crack is embedded in the matrix along the fibers. ReiSED is an extension of the well-known minimum strain energy density criterion. The concept of the reinforced isotropic solid as an advantageous model is the basis of the proposed mixed-mode I/II criterion. This model introduces fibers as reinforcements of the isotropic matrix in orthotropic materials. The effects of fibers are qualified by defining reinforcement coefficients at tension and shear modes. These coefficients, called Reduced Stress (ReSt), provide the possibility of encompassing the fiber fraction in a fracture criterion for the first time. Comparing ReiSED fracture limit curve with experimental data proves the high efficiency of this criterion to predict the fracture behavior of orthotropic materials.