• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 1995년도 춘계학술발표회 초록집
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• pp.31-40
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• 1995

The degradation of aqueous chlorinated compounds such as trichloroethylene (TCE), tetrachloroethylene (PCE) and dichloroacetic acid (DCA) to $CO_2$ and HCl was accomplished in the presence of UV light and suspended TiO$_2$ slurries. The decomposition of chlorinated hydrocarbons at 253.7 m irradiation was more effective than that at 360 nm irradiation. Our results show that 253.7 nm irradiation alone can be used for decomposing some chlorinated hydrocarbons such as PCE and TCE.

• 방사성폐기물학회지
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• 제16권2호
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• pp.243-260
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• 2018

사용후핵연료 건식저장 시스템과 관련하여 고온 및 방사선으로 인한 콘크리트 손상과 열화특성에 대해 포괄적으로 문헌분석을 수행하였다. 고온에 의한 장기열화를 방지하기 위한 콘크리트의 임계온도는 일반적으로 $95^{\circ}C$이며, 온도경사는 콘크리트 균열방지를 위해 $60^{\circ}C$ 이하가 되도록 설정하고 있다. 열화정도는 노출온도와 노출시간에 비례하여 증가하는 경향을 나타내며, 압축강도에 비해 인장강도가 고온에 보다 민감한 특성을 보인다. 한편 방사선의 에너지가 $10^{10}MeV{\cdot}cm^{-2}{\cdot}s^{-1}$ 이하일 경우에는 핵반응으로 인한 가열을 무시할 수 있다. 하지만 콘크리트가 $10^{19}n{\cdot}cm^{-2}$ 이상의 중성자에 혹은 $10^{10}$ rad를 초과하는 감마선량에 노출된다면 콘크리트의 역학적 물성이 점차 감소하는 경향을 보이며, 그 손상정도는 콘크리트 구성재료의 특성에 의존적이다. 콘크리트에 대한 방사선 조사시 재료의 역학적 물성변화는 주로 온도상승으로 인한 콘크리트 내부 함수량의 변화 및 재료간의 열적물성 차이로 인한 체적증가와 균열발생으로 발생한다. 따라서 건식저장과 관련된 기술의 조속한 확보 및 인 허가를 위해서는 그 간의 선행연구 결과를 최대한 활용할 필요가 있으며, 본 연구결과는 향후 사용후핵연료 건식저장 콘크리트 캐스크 관련 국내 자체기술 개발에 중요한 기초자료로 활용될 수 있을 것이다.

• Journal of Welding and Joining
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• 제16권6호
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• pp.86-96
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• 1998

This study proposes the analysis method of time series ultrasonic signal using the chaotic feature extraction for degradation extent evaluation. Features extracted from time series data using the chaotic time series signal analyze quantitatively degradation extent. For this purpose, analysis objective in this study is fractal dimension, lyapunov exponent, strange attractor on hyperspace. The lyapunov exponent is a measure of the rate at which nearby trajectories in phase space diverge. Chaotic trajectories have at least one positive lyapunov exponent. The fractal dimension appears as a metric space such as the phase space trajectory of a dynamical system. In experiment, fractal correlation) dimensions, lyapunov exponents, energy variation showed values of 2.217∼2.411, 0.097∼ 0.146, 1.601∼1.476 voltage according to degardation extent. The proposed chaotic feature extraction in this study can enhances precision ate of degradation extent evaluation from degradation extent results of the degraded materials (SA508 CL.3)

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.53-56
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• 2001

The degradation of tetrachloroethene (PCE) and trichloroethene (TCE) by vitamin B$_{12}$, an electron mediator was examined when zero valent metals (ZVMs) were used as built electron donors. Dechlorination of PCE and TCE by iron and zinc in the presence of vitamin B$_{12}$ showed that the zinc and vitamin B$_{12}$ combination greatly enhances the reaction rates for both PCE and TCE, but iron and vitamin B$_{12}$ result in an increase in reactivity only for PCE degradation, not for TCE degradation in comparing with meta]s only. This result indicates vitamin B$_{12}$(I) Is active towards both PCE and TCE degradation while vitamin B$_{12}$(II) is active towards both PCE. Calculated activation energies for the dechlorination of PCE in the presence of Vitamin B$_{12}$ showed that vitamin B$_{12}$ lowered the activation energy about 40-60 kJ/㏖ for the both metals.the both metals.

• Macromolecular Research
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• 제12권5호
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• pp.466-473
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• 2004

We have used FT-IR spectra to explain the effects of hydrogen bonding between chitosan and polycaprolactam (PA6). A dynamic mechanical analysis study suggested that the optimum chitosan and PA6 miscibility under the conditions of this experiment were obtained at a blending ratio of 40:60. We studied the thermal degradation of chitosan blended with PA6 (chitosan/PA6) by thermogravimetric analysis and kinetic analysis (by the Ozawa method). Dry chitosan and PA6 exhibited a single stage of thermal degradation and chitosan/PA6 blends having> 20 wt% PA6 exhibited at least two stages of degradation. In chitosan/PA6 blends, chitosan underwent the first stage of thermal degradation; the second stage proceeded at a temperature lower than that of PA6, because the decomposition product of chitosan accelerated the degradation of PA6. The activation energies of the blends were between 130 and 165 kJ/mol, which are also lower than that of PA6.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.140-143
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• 2000

The primary function of ZnO lightning arrester is to protect transmission and distribution equipment from overvoltages and to absorb electrical energy resulting from lightning or switching surges and form temporary overvoltage. However, ZnO lightning arrester are known to exhibit an increases in resistive current with time, the rate of increase being exacerbated with increasing applied voltage and ambient temperature. So, it is important to the leakage current measurement of ZnO lightning arrester. In addition, since the resistive leakage current caused by deterioration of ZnO lightning arrester mainly caused an increase of the third harmonic component, thereby it is possible the arrester degradation diagnosis by measuring the third harmonic component in the total leakage current. The leakage current and third harmonic component are measured and used to investigate the degradation diagnosis of ZnO element of arrester. Also the SEM photography is used to investigate the change of crystal structure of ZnO element with degradation.

• Steel and Composite Structures
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• 제43권1호
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• pp.55-66
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• 2022

To develop high-efficiency lateral force resistance components for high-rise buildings, a novel energy dissipation shear wall with concrete-filled steel tubular (CFST) column elements was proposed. An energy dissipation shear wall specimen with CFST column elements (GZSW) and an ordinary reinforced concrete shear wall (SW) were constructed, and experimented by low-cycle reversed loading. The mechanical characteristics of these two specimens, including the bearing capacity, ductility, energy dissipation, and stiffness degradation process, were analyzed. The finite-element model of the GZSW was established by ABAQUS. Based on this finite-element model, the effect of the placement of steel-plate energy dissipation connectors on the seismic performance of the shear wall was analyzed, and optimization was performed. The experiment results prove that, the GZSW exhibited a superior seismic performance in terms of bearing capacity, ductility, energy dissipation, and stiffness degradation, in comparison with the SW. The results calculated by the ABAQUS finite-elements model of GZSW corresponded well with the results of experiment, and it proved the rationality of the established finite-elements model. In addition, the optimal placement of the steel-plate energy dissipation connectors was obtained by ABAQUS.

• 한국전산구조공학회논문집
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• 제26권2호
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• pp.131-138
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• 2013

면진장치는 상부구조물의 지진력을 감소시키는데 크게 기여하지만, 고감쇠고무 적층받침에 사용되는 고무재료는 시간이 경과함에 따라 열화되어 상부구조물의 동특성과 기기들의 지진응답에 영향을 줄 수 있다. 따라서 면진장치의 경년열화를 고려한 구조물의 지진응답을 분석하는 연구가 필요하다. 본 연구에서는 기존 문헌을 통하여 분석된 고무의 경년열화 특성을 사용하여 면진장치를 모델링하였다. 면진된 원전의 지진응답을 평가하기 위하여 격납건물과 보조건물을 대상 구조물로 선정하고, 진동수 성분이 다양한 입력지진동을 사용하여 구조물의 고유진동수, 최대지진응답, 층응답스펙트럼을 시간의 경과에 따라 분석하였다. 해석결과에 의하면 면진장치의 경년열화에 의하여 지진응답이 소폭 증가하였으며, 면진장치가 설치된 후 20년까지 지진응답의 증가율이 크게 나타나므로 이 기간에 상세한 검사가 시행되어야 할 것이다.

• Composites Research
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• 제33권5호
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• pp.268-274
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• 2020

이 연구에서는 에폭시 수지에 나노 실리카 입자의 농도가 열화 거동에 미치는 영향에 대해 알아보았다. 약 12 nm 크기의 실리카 입자를 에폭시 수지에 세가지 무게비로 섞은 나노 복합소재를 제작하여 열중량분석(Thermogravimetric Analysis, TGA)을 이용하여 여섯 가지의 서로 다른 승온률 하에서 열화거동 변화를 분석하였다. 등변환법(Isoconversional Method)에 기초한 Friedman, Flynn-Wall-Ozawa, Kissinger 그리고 DAEM(Distributed Activation Energy Method) 방식으로 활성화에너지를 정량적으로 계산하였다. 계산 결과에 의하면 순수 에폭시와 비교했을 때, 실리카 입자가 함유될 경우 활성화에너지가 상승한다는 것을 확인할 수 있었다. 그러나 10%와 18%의 활성화에너지 값이 유사함에 따라 반드시 함유랑에 비례하지는 않는 것으로 나타났다. 또한 각 방법에 의한 계산방식을 분석하여 그 결과를 비교하였다.

• Current Photovoltaic Research
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• 제8권4호
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• pp.114-119
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• 2020

In this study, Mitigation of Potential-induced degradation (PID) for PERC solar cells using SiO2 Structure of ARC layer. The conventional PID test was conducted with a cell-level test based on the IEC-62804 test standard, but a copper PID test device was manufactured to increase the PID detection rate. The accelerated aging test was conducted by maintaining 96 hours with a potential difference of 1000 V at a temperature of 60℃. As a result, the PERC solar cell of SiO2-Free ARC structure decreased 22.11% compared to the initial efficiency, and the PERC solar cell of the Upper-SiO2 ARC structure decreased 30.78% of the initial efficiency and the PID reliability was not good. However, the PERC solar cell with the lower-SiO2 ARC structure reduced only 2.44%, effectively mitigating the degradation of PID. Na+ ions in the cover glass generate PID on the surface of the PERC solar cell. In order to prevent PID, the structure of SiNx and SiO2 thin films of the ARC layer is important. SiO2 thin film must be deposited on bottom of ARC layer and the surface of the PERC solar cell N-type emitter to prevent surface recombination and stacking fault defects of the PERC solar cell and mitigated PID degradation.