• Title/Summary/Keyword: emission spectrum

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Blue Electroluminescent Properties and Dependent of Dye Mixed ratio of ZnS:Cu (ZnS:Cu의 청색 발광 특성과 염료 혼합비 의존성)

  • 이종찬;박대희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.528-531
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    • 2000
  • ZnS:Cu phosphor used on powder electroluminescent device has a green emission in low frequency and a blue emission in high frequency. In this paper, to obtain the powder electroluminescent device of the blue emission in low frequency, the emission properties with mixed the ratio between phosphor and dye was investigated. The mixed ratio of the dye was from 0 to 5 weight percent. To inquire into the blue emission, the emission spectrum, the CIE coordinate system and the brightness were measured.

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Spectroscopic Analysis of Partially Folded State of Ubiquitin (유비퀴틴 단백질의 부분적으로 폴딩된 구조에 대한 분광학적 분석)

  • Park, Soon-Ho
    • Applied Biological Chemistry
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    • v.46 no.4
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    • pp.305-310
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    • 2003
  • Hydrophobic core variant of ubiquitin appeared to have partially folded structure at pH around 2. The intrinsic tryptophan fluorescence emission maximum of this ubiquitin variant at pH 2 showed slight blue shift compare to that of unfolded state, suggesting that some residual tertiary structures remain in this solvent condition. At the same solvent condition, this ubiquitin variant binds with hydrophobic dye, 8-anilinonaphthalene-1-sulfonic acid(AMS), which is known to bind to exposed hydrophobic surface. Furthermore, far-UV circular dichroic spectrum of this ubiquitin variant in the diminished pH was remarkably different from the far-UV CD spectrum of the native state or unfolded state. Based on the molar ellipticity at 220 nm, this ubiquitin variant at pH 2 appeared to have significant amount of secondary structures. All these observations suggest that this ubiquitin variant in the diminished solvent pH has loosely folded hydrophobic core with some secondary structures, which are key features of molten globule conformation. Since molten globule has long been considered as a protein folding intermediate, it is considered that this hydrophobic core variant ubiquitin will serve as a valuable model to study protein folding process.

SPHERICAL WIND ACCRETION ONTO SUPERMASSIVE BLACK HOLE (우리은하 중심의 초거대 질량 블랙홀에 대한 구형 항성풍 부착)

  • Im, Su-Yeon;Park, Myeong-Gu
    • Publications of The Korean Astronomical Society
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    • v.10 no.1
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    • pp.79-90
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    • 1995
  • The unique compact radio source, Sgr $A^*$, at the Galactic center show many observational signs that it is powered by supermassive black hole. Recent observations also imply that it is surrounded by winds from nearby IR sources. So we explore the model in which multiwavelength spectrum from Sgr $A^*$ is due to the spherical accretion of these winds onto the central supermassive black hole. Improving upon the previous work, we allowed the possibility that ions and electrons have different temperatures, included the Compton effects and pair processes. Electrons radiate via cyclosynchrotron and bresstrahlung with comptoniztion. We find that ion approaches the virial temperature ${\sim}10^{13}K$ while electron temperature saturates at ${\sim}10^{10}K$. However, decoupling between ion and electron does not greatly affect the shape of the emission spectrum. When the mass of the black hole is ${\sim}10^6M_{\odot}$, radio, IR, X-ray, $\gamma$-ray band spectrum is reasonably explained by the model. Yet Compton effect which is neglected in previous works produces significant emission in IR band, which is marginally compatible with observations. Pair production is negligible and annihilation lines cannot be observed.

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A Study on the Combustion Characteristics with Hydrogen Contents of SNG Fuel in Low-Swirl Combustor (저선회 연소기에서 합성천연가스(SNG) 연료의 수소함량에 따른 연소 특성 연구)

  • JEONG, HWANGHUI;KANG, KIJOONG;LEE, KEEMAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.2
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    • pp.181-189
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    • 2017
  • This paper describes experimental results on combustion characteristics with hydrogen contents of synthetic natural gas (SNG) in low swirl combustor. To investigate the effect of hydrogen contents for premixed SNG flame, stability map, CH chemiluminescence images, flame spectrum analysis and emission performances were measured. In the results, as the hydrogen content was increased, the lean flammable limit was expanded and the flame length was decreased. The hydrogen contents affected the flame liftoff height, and it has different tendency according to the equivalence ratio and flame shape. The change of height and length of flame according to hydrogen contents is caused by the fast burning velocity of hydrogen, which can be confirmed by GRI 3.0 reaction mechanism in PREMIX code. The intensity of $OH^*$, $CH^*$ and $C_2^*$ was confirmed by spectrum analysis of flame. As a result, the $CH^*$ intensity was not significantly different according to hydrogen content. The increase of hydrogen contents influenced positively CO and NOx emission performances.

A Study on the Detection of Acoustic Signal Produced by Partial Discharges in Insulation Oil and its Positioning (부분방전에 의한 음향신호의 검출과 위치추정에 관한 연구)

  • Kil, Gyung-Suk;Park, Dae-Won;Kim, Il-Kwon;Choi, Su-Yeon;Park, Chan-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.10
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    • pp.907-911
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    • 2007
  • This paper dealt with the frequency spectrum analysis of acoustic signal produced by partial discharge (PD) in insulation oil and the positioning of PD occurrence to apply in diagnosis of oil insulated transformers. Three types of electrode system ; the needle-plane, the plane-plane, and the wire-wire structure were assembled to simulate partial discharges in oil insulated transformers. A low-noise amplifier and a decoupling circuit were designed to detect acoustic signal with high sensitivity The frequency spectrum of the acoustic signal were 50 kHz ${\sim}$ 260 kHz in the needle-plane, 50 kHz ${\sim}$ 250 kHz in the plane-plane, and 45 kHz${\sim}$195 kHz in the wire-wire electrode system. Their peak frequencies were 145 kHz, 130 kHz and 114 kHz, respectively The position of PD occurrence was calculated by the time difference of arrival (TOA) using three acoustic emission (AE) sensors, and we could find the position within the error of 1 % in the experimental apparatus.

Measurement of Evoked Otoacoustic Emission Latency Using Linear prediction Coding Spectrum (선형예측부호화 스펙트럼을 이용한 유발이음향 방사파 잠시의 측정)

  • An, Jung-Il;Choi, Jin-Young;Cho, Jin-Ho;Lee, Kuhn-Il
    • Proceedings of the KOSOMBE Conference
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    • v.1991 no.05
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    • pp.47-50
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    • 1991
  • An automatized latency calculation method of evoked otoacoustic emission is proposed. Averaged e-OAE signal is measured from normal adult and it is processed by IBM-AT computer for latency calculation. After partition of stimulated and emitted signal on the time axis by converted linear prediction coding spectrum, latency is calculated by cross correlation method. The output is also compared with those of conventional autocorrelation and pure cross correlation methods. The result show that proposed method has better performance than those of conventional ones.

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Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion

  • Park, Chan-Ho;Lee, Gi-Woo;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.881-885
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    • 2006
  • We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.

Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile

  • Park, Chan Ho;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1377-1380
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    • 2006
  • The technique of corona-excited supersonic expansion was applied to produce electronically excited but rovibrationally cooled m-tolunitrile. The well-resolved vibronic emission spectrum of the jet-cooled m-tolunitrile in the $S_1\;\rightarrow \;S_0$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. From an analysis of the spectrum observed, it was confirmed that the electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined.

Formation of Difluorobenzyl Radicals from 2,3,4-Trifluorotoluene in Corona Excitation

  • Yoon, Young-Wook;Lee, Gi-Woo;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.1993-1996
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    • 2011
  • The vibronically well-resolved emission spectrum was recorded from the corona discharge of precursor 2,3,4-trifluorotoluene in a corona excited supersonic expansion with a pinhole-type glass nozzle using a long-path monochromator in the visible region. From the analysis of the observed spectrum, we found the evidence of the presence of the difluorobenzyl radicals in the corona discharge of the precursor. A possible mechanism is proposed for the formation of difluorobenzyl radicals in the gas phase on the basis of the observed emission intensity of the difluorobenzyl radicals produced.

Synthesis of $\beta$-$Ga_{2}O_{3}$Fiber-Wool from GaN Powder and its Characteristics (GaN분말을 이용한 $Ga_{2}O_{3}$fiber-wool의 합성과 특성)

  • 조성룡;여운용;이종원;박인용;김선태
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.848-850
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    • 2001
  • In this work, we investigated on the white-colored ribbon fiber synthesized from GaN powder. We convinced the formation of monoclinic phase $\beta$-Ga$_2$O$_3$from the X-ray diffraction pattern on ribbon fiber. The 10 K PL spectrum consisted with the strong emission band caused by self-activated optical center at 3.464 eV with the full-width at half maximum of 48 meV and the impurity related emission bands. Through this work, the optical properties and the electrical conductivity of $\beta$-Ga$_2$O$_3$, it will be useful for the fabrication of optoelctronic devices operating in visible spectrum region.

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