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http://dx.doi.org/10.5012/bkcs.2006.27.9.1377

Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile  

Park, Chan Ho (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
Lee, Sang-Kuk (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
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Abstract
The technique of corona-excited supersonic expansion was applied to produce electronically excited but rovibrationally cooled m-tolunitrile. The well-resolved vibronic emission spectrum of the jet-cooled m-tolunitrile in the $S_1\;\rightarrow \;S_0$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. From an analysis of the spectrum observed, it was confirmed that the electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined.
Keywords
Spectroscopy; Vibrational mode; m-Tolunitrile;
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