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http://dx.doi.org/10.5012/bkcs.2006.27.6.881

Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion  

Park, Chan-Ho (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
Lee, Gi-Woo (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
Lee, Sang-Kuk (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
Publication Information
Bulletin of the Korean Chemical Society / v.27, no.6, 2006 , pp. 881-885 More about this Journal
Abstract
We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.
Keywords
Spectroscopy; Vibrational mode; o-Tolunitrile;
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